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    • 62. 发明授权
    • Void-free copper filling of recessed features for semiconductor devices
    • 半导体器件凹陷特征的无孔铜填充
    • US07884012B2
    • 2011-02-08
    • US11864566
    • 2007-09-28
    • Kenji SuzukiTadahiro IshizakaMiho JomenJonathan Rullan
    • Kenji SuzukiTadahiro IshizakaMiho JomenJonathan Rullan
    • H01L21/4763
    • H01L21/76843H01L21/28518H01L21/2855H01L21/28556H01L21/76844H01L21/76862H01L21/76864H01L21/76868H01L21/76873H01L21/76874H01L21/76883
    • A method is provided for void-free copper (Cu) filling of recessed features in a semiconductor device. The method includes providing a patterned substrate containing a recessed feature, depositing a barrier film on the patterned substrate, including in the recessed feature, depositing a Ru metal film on the barrier film, and depositing a discontinuous Cu seed layer on the Ru metal film, where the Cu seed layer partially covers the Ru metal film in the recessed feature. The method further includes exposing the substrate to an oxidation source gas that oxidizes the Cu seed layer and the portion of the Ru metal film not covered by the Cu seed layer, heat-treating the oxidized Cu seed layer and the oxidized Ru metal film under high vacuum conditions or in the presence of an inert gas to activate the oxidized Ru metal film for Cu plating, and filling the recessed feature with bulk Cu metal. The exposure to the oxidation source gas can be an air exposure commonly encountered in semiconductor device manufacturing prior to Cu plating.
    • 提供了一种用于半导体器件中凹陷特征的无空隙铜(Cu)填充的方法。 该方法包括提供含有凹陷特征的图案化衬底,在图案化衬底上沉积阻挡膜,包括在凹陷特征中,在阻挡膜上沉积Ru金属膜,以及在Ru金属膜上沉积不连续的Cu籽晶层, 其中Cu籽晶层部分地覆盖凹陷特征中的Ru金属膜。 该方法还包括将衬底暴露于氧化Cu籽晶层的氧化源气体和未被Cu籽晶层覆盖的Ru金属膜的部分,在高温下热处理氧化的Cu种子层和氧化的Ru金属膜 真空条件下或在惰性气体存在下活化用于Cu电镀的氧化的Ru金属膜,并用块状Cu金属填充凹陷特征。 暴露于氧化源气体可以是在镀铜之前在半导体器件制造中通常遇到的空气暴露。
    • 63. 发明授权
    • Method for forming cobalt nitride cap layers
    • 形成氮化钴盖层的方法
    • US07846841B2
    • 2010-12-07
    • US12242900
    • 2008-09-30
    • Tadahiro IshizakaShigeru MizunoMiho Jomen
    • Tadahiro IshizakaShigeru MizunoMiho Jomen
    • H01L21/44
    • H01L21/76814H01L21/02063H01L21/02074H01L21/76846H01L21/76849H01L21/76883H01L23/53238H01L2924/0002H01L2924/3011H01L2924/00
    • A method is provided for integrating cobalt nitride cap layers into manufacturing of semiconductor devices to improve electromigration and stress migration in copper (Cu) metal. One embodiment includes providing a patterned substrate containing a recessed feature formed in a low-k material and a first metallization layer at the bottom of the feature, forming a cobalt nitride cap layer on the first metallization layer, depositing a barrier layer in the recessed feature, including on the low-k dielectric material and on the first cobalt metal cap layer, and filling the recessed feature with Cu metal. Another embodiment includes providing a patterned substrate having a substantially planar surface with Cu paths and low-k dielectric regions, and selectively forming a cobalt nitride cap layer on the Cu paths relative to the low-k dielectric regions.
    • 提供了一种用于将氮化钴盖层整合到半导体器件的制造中以改善铜(Cu)金属中的电迁移和应力迁移的方法。 一个实施例包括提供包含形成在低k材料中的凹陷特征的图案化衬底和在特征底部的第一金属化层,在第一金属化层上形成氮化钴覆盖层,在凹陷特征中沉积阻挡层 包括在低k电介质材料和第一钴金属帽层上,并用Cu金属填充凹陷特征。 另一个实施例包括提供具有Cu路径和低k电介质区域的基本平坦表面的图案化衬底,以及相对于低k电介质区域在Cu路径上选择性地形成氮化钴覆盖层。
    • 68. 发明申请
    • VOID-FREE COPPER FILLING OF RECESSED FEATURES FOR SEMICONDUCTOR DEVICES
    • 无阻塞铜填充半导体器件的特征
    • US20090087981A1
    • 2009-04-02
    • US11864566
    • 2007-09-28
    • Kenji SuzukiTadahiro IshizakaMiho JomenJonathan Rullan
    • Kenji SuzukiTadahiro IshizakaMiho JomenJonathan Rullan
    • H01L21/4763
    • H01L21/76843H01L21/28518H01L21/2855H01L21/28556H01L21/76844H01L21/76862H01L21/76864H01L21/76868H01L21/76873H01L21/76874H01L21/76883
    • A method is provided for void-free copper (Cu) filling of recessed features in a semiconductor device. The method includes providing a patterned substrate containing a recessed feature, depositing a barrier film on the patterned substrate, including in the recessed feature, depositing a Ru metal film on the barrier film, and depositing a discontinuous Cu seed layer on the Ru metal film, where the Cu seed layer partially covers the Ru metal film in the recessed feature. The method further includes exposing the substrate to an oxidation source gas that oxidizes the Cu seed layer and the portion of the Ru metal film not covered by the Cu seed layer, heat-treating the oxidized Cu seed layer and the oxidized Ru metal film under high vacuum conditions or in the presence of an inert gas to activate the oxidized Ru metal film for Cu plating, and filling the recessed feature with bulk Cu metal. The exposure to the oxidation source gas can be an air exposure commonly encountered in semiconductor device manufacturing prior to Cu plating.
    • 提供了一种用于半导体器件中凹陷特征的无空隙铜(Cu)填充的方法。 该方法包括提供含有凹陷特征的图案化衬底,在图案化衬底上沉积阻挡膜,包括在凹陷特征中,在阻挡膜上沉积Ru金属膜,以及在Ru金属膜上沉积不连续的Cu籽晶层, 其中Cu籽晶层部分地覆盖凹陷特征中的Ru金属膜。 该方法还包括将衬底暴露于氧化Cu籽晶层的氧化源气体和未被Cu籽晶层覆盖的Ru金属膜的部分,在高温下热处理氧化的Cu种子层和氧化的Ru金属膜 真空条件下或在惰性气体存在下活化用于Cu电镀的氧化的Ru金属膜,并用块状Cu金属填充凹陷特征。 暴露于氧化源气体可以是在镀铜之前在半导体器件制造中通常遇到的空气暴露。
    • 70. 发明申请
    • Method of plasma enhanced atomic layer deposition of TaC and TaCN films having good adhesion to copper
    • 等离子体增强了对铜具有良好附着力的TaC和TaCN膜的原子层沉积方法
    • US20070218670A1
    • 2007-09-20
    • US11378271
    • 2006-03-20
    • Tadahiro Ishizaka
    • Tadahiro Ishizaka
    • H01L21/44
    • H01L21/76843C23C16/32C23C16/36C23C16/4554C23C16/5096H01L21/28562
    • A method for processing a substrate for forming TaC and TaCN films having good adhesion to Cu. The method includes disposing the substrate in a process chamber of a plasma enhanced atomic layer deposition (PEALD) system configured to perform a PEALD process, and depositing a TaC or TaCN film on the substrate using the PEALD process. The PEALD process includes (a) exposing the substrate to a first process material containing tantalum, (b) exposing the substrate to a second process material containing a plasma excited reducing agent, (c) repeating steps (a) (b) a predetermined number of times, (d) exposing the substrate to plasma excited Argon, and (e) repeating steps (c) and (d) until the TaC or TaCN film has a desired thickness. Preferably, purging of the process chamber is performed after one or more of the exposing steps.
    • 一种处理用于形成对Cu具有良好粘附性的TaC和TaCN膜的基板的方法。 该方法包括将衬底设置在配置为执行PEALD工艺的等离子体增强原子层沉积(PEALD)系统的处理室中,以及使用PEALD工艺在衬底上沉积TaC或TaCN膜。 PEALD工艺包括(a)将衬底暴露于含有钽的第一工艺材料,(b)将衬底暴露于含有等离子体激发还原剂的第二工艺材料,(c)重复步骤(a)(b)预定数量 的时间,(d)将衬底暴露于等离子体激发的氩,和(e)重复步骤(c)和(d),直到TaC或TaCN膜具有所需的厚度。 优选地,在一个或多个曝光步骤之后执行处理室的清洗。