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61. 发明申请

US20100243567A1 Polymer Membranes Derived from Aromatic Polyimide Membranes 有权
标题翻译：衍生自芳族聚酰亚胺膜的聚合物膜
公开(公告)号：US20100243567A1
公开(公告)日：2010-09-30
申请号：US12412653
申请日：2009-03-27
申请人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
发明人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
IPC分类号： B01D53/22 , B01D71/64 , B01D61/00 , C08L77/06 , C08F2/48
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译：本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜衍生而来。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。

62. 发明申请

US20100137124A1 High Performance Cross-Linked Polybenzoxazole and Polybenzothiazole Polymer Membranes 有权
公开(公告)号：US20100137124A1
公开(公告)日：2010-06-03
申请号：US12412629
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01J20/28 , C08G69/48 , C08J3/28
CPC分类号： C08G75/32 , B01D67/0093 , B01D71/62 , B01D2323/30 , B01D2323/345 , B01J20/26 , B01J20/262 , B01J20/267 , C08G73/1042 , C08G73/22
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., —OH or —SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

63. 发明申请

US20100133192A1 Polymer Membranes Prepared from Aromatic Polyimide Membranes by Thermal Treating and UV Crosslinking 有权
标题翻译：通过热处理和UV交联从芳族聚酰亚胺膜制备的聚合物膜
公开(公告)号：US20100133192A1
公开(公告)日：2010-06-03
申请号：US12412649
申请日：2009-03-27
申请人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D53/22 , B01D39/16 , B01D61/02 , C08G73/10
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译：本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。

64. 发明申请

US20100133187A1 Polybenzoxazole Polymer-Based Mixed Matrix Membranes 有权
标题翻译：聚苯并恶唑聚合物基混合基质膜
公开(公告)号：US20100133187A1
公开(公告)日：2010-06-03
申请号：US12412647
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D61/36 , B01D53/22 , B01D71/06
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/028 , B01D71/62 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/06 , H01M8/1048 , H01M2300/0082 , Y02C10/10 , Y02C20/20
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

65. 发明申请

US20100133171A1 Polybenzoxazole Polymer-Based Mixed Matrix Membranes 审中-公开
标题翻译：聚苯并恶唑聚合物基混合基质膜
公开(公告)号：US20100133171A1
公开(公告)日：2010-06-03
申请号：US12412643
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D39/16
CPC分类号： B01D71/82 , B01D67/0079 , B01D69/148
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 300° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在300℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

66. 发明申请

US20090277837A1 Fluoropolymer Coated Membranes 审中-公开
标题翻译：含氟聚合物涂膜
公开(公告)号：US20090277837A1
公开(公告)日：2009-11-12
申请号：US12115726
申请日：2008-05-06
申请人： Chunqing Liu , Man-Wing Tang
发明人： Chunqing Liu , Man-Wing Tang
IPC分类号： B01D71/32 , B05D3/00 , B01D53/22 , B01D61/00 , B01D67/00
CPC分类号： B01D61/025 , B01D61/362 , B01D67/0011 , B01D67/0079 , B01D67/0088 , B01D69/10 , B01D69/12 , B01D69/141 , B01D71/028 , B01D71/10 , B01D71/32 , B01D2325/022 , B01D2325/24 , C10K1/20 , Y02A20/131
摘要： The present invention discloses fluoropolymer coated membranes and methods for making and using these membranes. The fluoropolymer coated membranes described in the current invention are prepared by coating a porous asymmetric membrane layer with a thin layer of fluoropolymer coating. The porous asymmetric membrane layer comprises an asymmetric cellulosic membrane, an asymmetric polymer membrane, or an asymmetric molecular sieve/polymer mixed matrix membrane with a low selectivity and high permeance. The fluoropolymer coating improves the selectivity of the porous asymmetric membrane layer and maintains the membrane performance with time. The fluoropolymer coated membranes are suitable for a variety of liquid, gas, and vapor separations such as desalination of water by reverse osmosis, non-aqueous liquid separation such as deep desulfurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations.
摘要翻译：本发明公开了含氟聚合物涂层膜以及制造和使用这些膜的方法。在本发明中描述的含氟聚合物涂布的膜通过涂覆具有薄层氟聚合物涂层的多孔不对称膜层来制备。多孔非对称膜层包含不对称纤维素膜，不对称聚合物膜或具有低选择性和高渗透性的不对称分子筛/聚合物混合基质膜。含氟聚合物涂层改善了多孔不对称膜层的选择性并随时间保持膜的性能。含氟聚合物涂层膜适用于各种液体，气体和蒸气分离，如通过反渗透脱水，非水液体分离，如汽油和柴油燃料的深度脱硫，乙醇/水分离，渗透蒸发脱水 /有机混合物，CO 2 / CH 4，CO 2 / N 2，H 2 / CH 4，O 2 / N 2，烯烃/石蜡，异/正链烷烃分离和其它轻质气体混合物分离。

67. 发明申请

US20090152763A1 Molecular Sieve/Polymer Asymmetric Flat Sheet Mixed Matrix Membranes 有权
标题翻译：分子筛/聚合物不对称平板混合基质膜
公开(公告)号：US20090152763A1
公开(公告)日：2009-06-18
申请号：US11954454
申请日：2007-12-12
申请人： Chunqing Liu , Stephen T. Wilson , David A. Lesch
发明人： Chunqing Liu , Stephen T. Wilson , David A. Lesch
IPC分类号： B29D7/01
CPC分类号： B01D69/148 , B01D67/0079 , B01D69/06 , B01D71/028 , B01D2325/022
摘要： The present invention discloses an approach for making mixed matrix membranes (MMMS) and methods for using these membranes. These MMMs contain a continuous polymer matrix and dispersed microporous molecular sieve particles. This invention also pertains to control of the thickness of the thin dense selective mixed matrix membrane layer that is equal to or greater than the particle size of the largest molecular sieve particles for making large scale asymmetric MMMs. In particular, the invention is directed to making asymmetric flat sheet MMM by a phase inversion technique. The MMMs of the present invention exhibit at least 20% increase in selectivity compared to the polymer membranes prepared from their corresponding continuous polymer matrices. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.
摘要翻译：本发明公开了一种制备混合基质膜（MMMS）的方法和使用这些膜的方法。这些MMM含有连续的聚合物基质和分散的微孔分子筛颗粒。本发明还涉及等于或大于用于制造大规模不对称MMM的最大分子筛颗粒的粒度的薄致密选择性混合基质膜层的厚度的控制。特别地，本发明涉及通过相位反转技术制造不对称平板MMM。与由其相应的连续聚合物基质制备的聚合物膜相比，本发明的MMM显示出至少20％的选择性增加。本发明的MMM适用于各种液体，气体和蒸气分离。

68. 发明申请

US20090152755A1 Molecular Sieve/Polymer Hollow Fiber Mixed Matrix Membranes 审中-公开
标题翻译：分子筛/聚合物中空纤维混合基质膜
公开(公告)号：US20090152755A1
公开(公告)日：2009-06-18
申请号：US11954463
申请日：2007-12-12
申请人： Chunqing Liu , Stephen T. Wilson , David A. Lesch
发明人： Chunqing Liu , Stephen T. Wilson , David A. Lesch
IPC分类号： D04H3/16
CPC分类号： B01D69/148 , B01D67/0079 , B01D69/08 , B01D69/087 , B01D71/028
摘要： The present invention discloses a method for making mixed matrix membranes (MMMs) and methods for using these membranes. These MMMs contain a continuous polymer matrix and dispersed microporous molecular sieve particles. This invention also pertains to control the thickness of the thin dense selective mixed matrix layer equal to or greater than the particle size of the largest molecular sieve particles for making large scale asymmetric MMMs. In particular, the invention is directed to make asymmetric hollow fiber MMM by a phase inversion technique. The MMMs of the present invention exhibit at least 20% increase in selectivity compared to the polymer membranes prepared from their corresponding continuous polymer matrices. The MMMs of the present invention are suitable for a variety of liquid, gas, and vapor separations.
摘要翻译：本发明公开了一种制备混合基质膜（MMM）的方法和使用这些膜的方法。这些MMM含有连续的聚合物基质和分散的微孔分子筛颗粒。本发明还涉及控制等于或大于用于制造大规模非对称MMM的最大分子筛颗粒的粒度的薄致密选择性混合基质层的厚度。特别地，本发明涉及通过相位反转技术制造不对称中空纤维MMM。与由其相应的连续聚合物基质制备的聚合物膜相比，本发明的MMM显示出至少20％的选择性增加。本发明的MMM适用于各种液体，气体和蒸气分离。

69. 发明申请

US20090131242A1 Method of Making Polymer Functionalized Molecular Sieve/Polymer Mixed Matrix Membranes 审中-公开
标题翻译：制备聚合物官能化分子筛/聚合物混合基质膜的方法
公开(公告)号：US20090131242A1
公开(公告)日：2009-05-21
申请号：US11940539
申请日：2007-11-15
申请人： Chunqing Liu , Stephen T. Wilson , David A. Lesch , Douglas B. Galloway
发明人： Chunqing Liu , Stephen T. Wilson , David A. Lesch , Douglas B. Galloway
IPC分类号： B01J20/28
CPC分类号： B01J20/28004 , B01D53/228 , B01D61/362 , B01D67/0088 , B01D67/0093 , B01D69/148 , B01D71/028 , B01D71/64 , B01D71/68 , B01D2256/24 , B01D2257/504 , B01J20/18 , B01J20/26 , B01J20/28026 , Y02C10/10
摘要： The present invention discloses a method of making polymer functionalized molecular sieve/polymer mixed matrix membranes (MMMs) with either no macrovoids or voids of less than several Angstroms at the interface of the polymer matrix and the molecular sieves by incorporating polyethersulfone (PES) or cellulose triacetate (CTA) functionalized molecular sieves into a continuous polyimide or cellulose acetate polymer matrix. The MMMs, particularly PES functionalized AlPO-14/polyimide MMMs and CTA functionalized AlPO-14/CA MMMs have good flexibility and high mechanical strength, and exhibit significantly enhanced selectivity and/or permeability over the polymer membranes made from the corresponding continuous polymer matrices for carbon dioxide/methane (CO2/CH4), hydrogen/methane (H2/CH4), and propylene/propane separations. The MMMs are suitable for a variety of liquid, gas, and vapor separations such as deep desulphurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations.
摘要翻译：本发明公开了一种通过加入聚醚砜（PES）或纤维素，在聚合物基体和分子筛的界面处制备聚合物官能化分子筛/聚合物混合基质膜（MMM）的方法，该聚合物官能化分子筛/聚合物混合基质膜（MMMs）在聚合物基体和分子筛的界面处没有大于或等于几埃的大孔或空隙三乙酸酯（CTA）官能化分子筛成为连续聚酰亚胺或乙酸纤维素聚合物基质。 MMMs，特别是PES功能化的AlPO-14 /聚酰亚胺MMM和CTA官能化的AlPO-14 / CA MMM具有良好的柔韧性和高的机械强度，并且显示出从由相应的连续聚合物基体制成的聚合物膜显着增强的选择性和/或渗透性二氧化碳/甲烷（CO2 / CH4），氢/甲烷（H2 / CH4）和丙烯/丙烷分离。 MMM适用于各种液体，气体和蒸气分离，如汽油和柴油的深度脱硫，乙醇/水分离，水/有机混合物的渗透蒸发脱水，CO2 / CH4，CO2 / N2，H2 / CH4， O2 / N2，烯烃/石蜡，异/正链烷烃分离和其他轻质气体混合物分离。

70. 发明申请

US20090031897A1 Cross-Linkable and Cross-Linked Mixed Matrix Membranes and Methods of Making the Same 有权
标题翻译：可交联和交联的混合基质膜及其制备方法
公开(公告)号：US20090031897A1
公开(公告)日：2009-02-05
申请号：US12193897
申请日：2008-08-19
申请人： Chunqing Liu , Jeffrey J. Chiou , Stephen T. Wilson
发明人： Chunqing Liu , Jeffrey J. Chiou , Stephen T. Wilson
IPC分类号： B01D53/22 , B29C35/08
CPC分类号： B01D53/228 , B01D67/0004 , B01D67/009 , B01D69/02 , B01D69/141 , B01D71/64 , B01D2323/30 , B01D2323/345 , Y02C10/10 , Y02C20/20 , Y10S55/05
摘要： The present invention is for novel high performance cross-linkable and cross-linked mixed matrix membranes and the use of such membranes for separations such as for CO2/CH4, H2/CH4 and propylene/propane separations. More specifically, the invention involves the preparation of cross-linkable and cross-linked mixed matrix membranes (MMMs). The cross-linkable MMMs were prepared by incorporating microporous molecular sieves or soluble high surface area microporous polymers (PIMs) as dispersed microporous fillers into a continuous cross-linkable polymer matrix. The cross-linked MMMs were prepared by UV-cross-linking the cross-linkable MMMs containing cross-linkable polymer matrix such as BP-55 polyimide. Pure gas permeation test results demonstrated that both types of MMMs exhibited higher performance for CO2/CH4 and H2/CH4 separations than those of the corresponding cross-linkable and cross-linked pure polymer matrices.
摘要翻译：本发明是用于新型高性能可交联和交联的混合基质膜，以及这种膜用于分离的用途，例如用于CO 2 / CH 4，H 2 / CH 4和丙烯/丙烷分离。更具体地，本发明涉及可交联和交联的混合基质膜（MMM）的制备。通过将微孔分子筛或可溶性高表面积微孔聚合物（PIM）作为分散的微孔填料掺入连续可交联的聚合物基质中来制备可交联的MMM。交联的MMM通过UV-交联含有可交联聚合物基质如BP-55聚酰亚胺的可交联MMM制备。纯气体渗透测试结果表明，两种类型的MMM对于CO 2 / CH 4和H 2 / CH 4分离显示出比相应的可交联和交联纯聚合物基质更高的性能。

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