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61. 发明授权

US06372916B1 Method for producing triazolinethione derivatives 有权
公开(公告)号：US06372916B1
公开(公告)日：2002-04-16
申请号：US09750589
申请日：2000-12-28
申请人： Reinhard Lantzsch , Manfred Jautelat , Achim Hupperts , David Erdman
发明人： Reinhard Lantzsch , Manfred Jautelat , Achim Hupperts , David Erdman
IPC分类号： C07D24912
摘要： According to a novel process, it is possible to prepare triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description by a) reacting hydrazine derivatives of the formula with carbonyl compounds of the formula in which R3 and R4 are each as defined in the description with potassium thiocyanate, sodium thiocyanate or ammonium thiocyanate, if appropriate in the presence of a diluent and if appropriate in the presence of an acid, and b) reacting the resulting triazolidinethione derivatives of the formula with formic acid, if appropriate in the presence of a catalyst and if appropriate in the presence of a diluent. The triazolidinethione derivatives of the formula (V) are novel.

62. 发明授权

US06359142B1 Sulfonyl oxazolones and their use for combating undesirable microorganisms 失效
标题翻译：磺酰基恶唑酮及其用于防治不良微生物的用途
公开(公告)号：US06359142B1
公开(公告)日：2002-03-19
申请号：US09787054
申请日：2001-03-13
申请人： Lutz Assmann , Manfred Jautelat , Ulrike Wachendorff-Neumann , Klaus Stenzel
发明人： Lutz Assmann , Manfred Jautelat , Ulrike Wachendorff-Neumann , Klaus Stenzel
IPC分类号： C07D26338
CPC分类号： C07D413/12 , A01N43/76 , A01N43/80 , C07D263/38
摘要： Novel sulphonyloxazolones of the formula in which R1 represents alkyl or represents optionally substituted heterocyclyl or represents a radical of the formula in which R3 represents halogen, alkyl or phenyl, R4 represents hydrogen or alkyl and R5 represents alkyl or optionally substituted phenyl, and R2 represents alkyl, a process for preparing these substances and their use for controlling undesirable microorganisms. Novel intermediates of the formula and a process for their preparation.
摘要翻译：烷基或苯基，R4代表氢或烷基，R5代表烷基或任意取代的苯基，R 2代表烷基，其中R 2代表烷基，其中R1代表烷基，这些物质及其用于控制不良微生物的用途。新型中间体及其制备方法。

63. 发明授权

US06353114B2 Method for producing triazolinethione derivatives 有权
标题翻译：三唑啉酮衍生物的制备方法
公开(公告)号：US06353114B2
公开(公告)日：2002-03-05
申请号：US09748932
申请日：2000-12-27
申请人： Manfred Jautelat , David Erdman
发明人： Manfred Jautelat , David Erdman
IPC分类号： C07D24912
CPC分类号： C07D249/12
摘要： According to a novel process, triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description, can be prepared by a) reacting hydrazine derivatives of the formula with formaldehyde and thiocyanate of the formula X—SCN (III), in which X represents sodium, potassium or ammonium, in the presence of a diluent and if appropriate in the presence of an acid, and b) reacting the resulting triazolidinethiones of the formula either &agr;) with oxidizing agents, if appropriate in the presence of a catalyst and in the presence of a diluent, or &bgr;) with formic acid. The triazolidinethiones of the formula (IV) are novel.
摘要翻译：根据新的方法，R1和R2各自如说明书中所定义的式的三唑啉酮衍生物可以通过以下方法制备：a）使下式的肼衍生物与下式的甲醛和硫氰酸酯反应其中X代表钠，钾或铵，在存在稀释剂的情况下，如果合适的话，在酸的存在下，和b）使所得到的式α的三唑烷硫酮与氧化剂反应，如果合适的话，在催化剂的存在下，在稀释剂的存在下，将其与式（IV）的三唑烷硫代乙烯是新颖的。

64. 发明授权

US06303837B1 Process for synthesizing &agr;-substituted ring systems 失效
标题翻译：合成α-取代环系的方法
公开(公告)号：US06303837B1
公开(公告)日：2001-10-16
申请号：US09387020
申请日：1999-08-31
申请人： Christoph Gürtler , Manfred Jautelat
发明人： Christoph Gürtler , Manfred Jautelat
IPC分类号： C07C3518
CPC分类号： C07C41/18 , C07C29/00 , C07C67/293 , C07C2601/16 , Y02P20/544 , C07C69/013 , C07C43/188 , C07C35/18
摘要： Using the process according to the invention, it is possible to provide, with few reaction steps, a novel route to &agr;-substituted ring systems, which optionally have further substituents.
摘要翻译：使用根据本发明的方法，可以在少量反应步骤中提供一种新的α-取代的环系的途径，其任选具有其它取代基。

65. 发明授权

US06262276B1 Method for producing triazolinthion derivatives 有权
标题翻译：三唑衍生物的制备方法
公开(公告)号：US06262276B1
公开(公告)日：2001-07-17
申请号：US09509927
申请日：2000-04-03
申请人： Manfred Jautelat , Achim Hupperts , Reinhard Lantzsch
发明人： Manfred Jautelat , Achim Hupperts , Reinhard Lantzsch
IPC分类号： C07D24912
CPC分类号： C07D249/12 , C07C337/06
摘要： According to a novel process, it is possible to prepare triazolinethione derivatives of the formula in which R1 and R2 are each as defined in the description by a) reacting hydrazine derivatives of the formula or their acid addition salts with an inorganic or organic acid with thiocyanate of the formula Y—SCN (III) in which Y represents sodium, potassium or ammonium in the presence of a diluent and, if appropriate, in the presence of a catalyst and b) reacting the resulting thiosemicarbazide derivatives of the formula with formic acid, if appropriate in the presence of a catalyst and if appropriate in the presence of a diluent. The thiosemicarbazide derivatives of the formula (IV) are novel. Method for producing triazolinthion derivatives
摘要翻译：根据一个新方法，可以制备甲醛的三唑啉酮衍生物，其中R 1和R 2各自如描述中所定义.a）使式或其酸加成盐的肼衍生物与无机或有机酸与式I的硫氰酸酯反应钠，钾或铵，在适当的情况下，在催化剂存在下，和b）如果合适的话，在催化剂的存在下，如果合适的话，使所得的甲酸甲酯的氨基磺酰胺衍生物式（IV）的硫代氨基脲衍生物是新颖的。三唑衍生物的制备方法

66. 发明授权

US6166059A Thiocyano- triazolyl derivatives and their use as microbicides 有权
标题翻译：硫氰基 - 三唑基衍生物及其作为杀微生物剂的用途
公开(公告)号：US6166059A
公开(公告)日：2000-12-26
申请号：US180862
申请日：1998-11-17
申请人： Manfred Jautelat , Stefan Dutzmann , Klaus Stenzel , Gerd Hanssler
发明人： Manfred Jautelat , Stefan Dutzmann , Klaus Stenzel , Gerd Hanssler
IPC分类号： A01N43/653 , A01N53/00 , A01N55/00 , C07D249/12 , C07D401/06 , C07D405/06 , C07F7/08
CPC分类号： C07D405/06 , A01N43/653 , A01N53/00 , A01N55/00 , C07D249/12 , C07F7/0812
摘要： The present invention provides novel thiocyanato-triazolyl derivatives, and the acid addition salts and metal salt complexes thereof; a process for their preparation; and a method for their use as microbicides.
摘要翻译： PCT No.PCT / EP97 / 02373 371日期：1998年11月17日 102（e）日期1998年11月17日PCT提交1997年5月9日PCT公布。第WO97 / 44331号公报日期1997年11月27日本发明提供新型硫氰酸 - 三唑基衍生物及其酸加成盐和金属盐络合物; 其准备过程; 以及用作杀微生物剂的方法。

67. 发明授权

US5859039A Microbicidal triazolyl derivatives 失效
标题翻译：杀菌三唑衍生物
公开(公告)号：US5859039A
公开(公告)日：1999-01-12
申请号：US878916
申请日：1997-06-19
申请人： Manfred Jautelat , Ralf Tiemann , Stefan Dutzmann , Gerd Hanssler , Klaus Stenzel
发明人： Manfred Jautelat , Ralf Tiemann , Stefan Dutzmann , Gerd Hanssler , Klaus Stenzel
IPC分类号： A01N43/653 , A01N43/74 , A61K31/41 , C07D20060101 , C07D249/08 , C07D249/12 , C07D401/06 , C07D403/06 , C07D405/06 , C07D409/06 , C07D413/06 , C07D417/06
CPC分类号： A01N43/653 , C07D249/12
摘要： Triazolyl derivatives of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and represent optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted aralkyl, optionally substituted aralkenyl, optionally substituted aroxyalkyl, optionally substituted aryl or optionally substituted heteroaryl andX represents the groups --SH, --SR.sup.3, --SO--R.sup.3, --SO.sub.2 --R.sup.3 or --SO.sub.3 H, in whichR.sup.3 represents alkyl which is optionally substituted by fluorine and/or chlorine, alkenyl which is optionally substituted by fluorine and/or chlorine, optionally substituted aralkyl or optionally substituted aryl,and their acid addition salts and metal salt complexes,a plurality of processes for the preparation of the new substances, and their use as microbicides in plant protection and materials protection.
摘要翻译：式（I）的三唑基衍生物，其中R 1和R 2相同或不同并且表示任选取代的烷基，任选取代的烯基，任选取代的环烷基，任选取代的芳烷基，任选取代的芳烯基，任选取代的芳基烷基，任选取代的芳基或任选取代的杂芳基，X表示基团-SH，-SR 3，-SO-R 3，-SO 2 -R 3或-SO 3 H，其中R 3表示任选被氟和/或氯取代的烷基，任选被氟取代的烯基和/或氯，任选取代的芳烷基或任选取代的芳基，以及它们的酸加成盐和金属盐络合物，多种制备新物质的方法，以及它们在植物保护和材料保护中作为杀微生物剂的用途。

68. 发明授权

US5760067A Halogen alkenyl azolyl microbicides 失效
标题翻译：卤素烯基唑基杀微生物剂
公开(公告)号：US5760067A
公开(公告)日：1998-06-02
申请号：US676304
申请日：1996-07-18
申请人： Manfred Jautelat , Stefan Dutzmann , Heinz-Wilhelm Dehne
发明人： Manfred Jautelat , Stefan Dutzmann , Heinz-Wilhelm Dehne
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Novel halogenoalkenyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted aryl or represents optionally substituted heteroaryl, R.sup.2 represents alkyl, halogenoalkyl, 1-hydroxyalkyl, 2-hydroxyalkyl, 1-hydroxyhalogenalkyl, 1-alkenyl or 2-alkenyl, X.sup.1 represents fluorine, chlorine, bromine or iodine, X.sup.2 represents fluorine, chlorine, bromine or iodine, and Y represents nitrogen or a CH group, and addition products thereof with acids or metal salts are very active as microbicides in plant protection and in the protection of materials.
摘要翻译：式（I）的新型卤代烯基 - 唑基衍生物，其中R 1表示任选取代的烷基，任选取代的烯基，任选取代的环烷基，任选取代的芳基或表示任选取代的杂芳基，R 2表示烷基，卤代烷基，1-羟基烷基， 1-羟基烷基，1-烯基或2-链烯基，X 1表示氟，氯，溴或碘，X 2表示氟，氯，溴或碘，Y表示氮或CH基，其加成酸与酸或金属盐在植物保护和材料保护中作为杀微生物剂非常活跃。

69. 发明授权

US5262434A Halogenoalkyl-azolyl derivatives 失效
标题翻译：卤代烷基 - 唑基衍生物
公开(公告)号：US5262434A
公开(公告)日：1993-11-16
申请号：US929849
申请日：1992-08-14
申请人： Manfred Jautelat , Jurgen Scherkenbeck , Klaus Stroech , Stefan Dutzmann , Heinz Dehne , Gerd Haenssler , Karl-Heinz Kuck
发明人： Manfred Jautelat , Jurgen Scherkenbeck , Klaus Stroech , Stefan Dutzmann , Heinz Dehne , Gerd Haenssler , Karl-Heinz Kuck
IPC分类号： A01N43/50 , A01N43/653 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New halogenoalkyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted phenyl,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen,n represents 0 or 1 andY represents nitrogen or a CH groupand their acid addition salts and metal salt complexes, are outstandingly effective as microbicides in plant protection and in the preservation of materials.
摘要翻译：式（I）的新卤代烷基 - 唑基衍生物，其中R 1表示任选取代的苯基，R 2表示氢，烷基，烯基，酰基或芳烷基，X 1表示卤素，X 2表示卤素，n表示0或1，Y表示氮或CH基团及其酸加成盐和金属盐络合物在植物保护和材料保存方面非常有效。

70. 发明授权

US5175169A Halogenovinyl-azole derivatives 失效
标题翻译：卤代乙烯基 - 唑衍生物
公开(公告)号：US5175169A
公开(公告)日：1992-12-29
申请号：US761087
申请日：1991-09-17
申请人： Manfred Jautelat , Dieter Berg , Stefan Dutzmann , Wilhelm Brandes , Gerd Hanssler , Astrid Mauler , Wilfried Paulus , Monika Frie
发明人： Manfred Jautelat , Dieter Berg , Stefan Dutzmann , Wilhelm Brandes , Gerd Hanssler , Astrid Mauler , Wilfried Paulus , Monika Frie
IPC分类号： A01N43/50 , A01N43/653 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New halogenovinyl-azole derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl or optionally substituted aryl, or represents optionally substituted heteroaryl,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkylX.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogenY represents nitrogen or a CH group,and acid addition salts and metal salt complexes thereofare very effective for combating microbes in plant protection and in the preservation of materials.
摘要翻译：式（I）的新的卤代乙烯基 - 唑衍生物，其中R 1表示任选取代的烷基，任选取代的烯基，任选取代的环烷基或任选取代的芳基，或表示任选取代的杂芳基，R 2表示氢，烷基，烯基，酰基或芳烷基X1表示卤素，X2表示卤素，X3表示氢或卤素，Y表示氮或CH基，其酸加成盐和金属盐络合物对于防治植物保护和保存材料中的微生物非常有效。

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