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    • 67. 发明授权
    • Porous composite structures for lithium-ion battery separators
    • 用于锂离子电池隔板的多孔复合结构
    • US09412986B2
    • 2016-08-09
    • US13955025
    • 2013-07-31
    • GM GLOBAL TECHNOLOGY OPERATIONS LLC
    • Xiaosong Huang
    • H01M2/16H01M2/14H01M10/0525
    • H01M2/1626H01M2/145H01M2/1653H01M2/1666H01M10/0525Y02E60/122Y02P70/54Y02T10/7011
    • Micro-fibrillated cellulose nanofibers (or other suitable fibrillated organic polymer nanofibers) are dispersed with ceramic particles (such as alumina or silica powder) in water suspension and formed into a suitable porous mat shape by wet-laying the suspension on a suitable mesh structure. After removal of the mat from the mesh and drying, the suitably proportioned cellulose nanofibers/ceramic powder composite may be coated with a thin porous polymer layer to further fix the particles between the fibers and strengthen the resulting composite membrane for use as a separator layer between the electrode layers of an electrochemical cell. The strength and temperature resistance of the composite separator layer make it particularly useful in lithium-ion batteries for vehicle traction motors.
    • 将微原纤化纤维素纳米纤维(或其它合适的原纤化有机聚合物纳米纤维)与陶瓷颗粒(例如氧化铝或二氧化硅粉末)分散在水悬浮液中,并通过将悬浮液湿式铺设在合适的网状结构上,形成合适的多孔垫形状。 在从网中除去垫子并干燥之后,适当比例的纤维素纳米纤维/陶瓷粉末复合材料可以涂覆有薄的多孔聚合物层,以进一步将颗粒固定在纤维之间并加强所得的复合膜,以用作隔离层 电化学电池的电极层。 复合隔离层的强度和耐温性使其特别适用于车辆牵引电动机的锂离子电池。
    • 68. 发明授权
    • Cross-linked multilayer porous polymer membrane battery separators
    • 交联多层聚合物膜电池隔膜
    • US09331323B2
    • 2016-05-03
    • US13971900
    • 2013-08-21
    • GM GLOBAL TECHNOLOGY OPERATIONS LLC
    • Xiaosong Huang
    • H01M2/16H01M2/14H01M10/0525
    • H01M2/1686H01M2/145H01M2/1653H01M10/0525
    • A cross-linkable polyolefin composition (polyethylene, polypropylene or an ethylene-propylene copolymer) is coextruded with ultrahigh molecular weight polyethylene to form two-layer separator membranes, or three-layer separator membranes, for lithium-ion battery cells. In three-layer separator membranes, the cross-linkable polyolefin is formed as the outer faces of the separator for placement against facing surfaces of cell electrodes. The polymer materials initially contain plasticizer oil, which is removed from the extruded membranes, and the extruded membranes are also stretched to obtain a suitable open pore structure in the layered membranes to provide for suitable infiltration with a liquid electrolyte. The cross-linked polyolefin layer provides strength at elevated temperatures and the lower-melting, ultrahigh molecular weight polyethylene layer provides the separator membrane with a thermal shutdown capability.
    • 将可交联聚烯烃组合物(聚乙烯,聚丙烯或乙烯 - 丙烯共聚物)与超高分子量聚乙烯共挤出以形成用于锂离子电池单元的两层隔膜或三层隔膜。 在三层隔膜中,形成可交联聚烯烃作为隔板的外表面以放置在电池电极的相对表面上。 聚合物材料最初含有增塑剂油,其从挤出的膜中除去,并且挤出的膜也被拉伸以在层状膜中获得合适的开孔结构,以提供与液体电解质合适的渗透。 交联聚烯烃层在升高的温度下提供强度,较低熔点的超高分子量聚乙烯层为隔膜提供了热关断能力。