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    • 65. 发明授权
    • Cyanato group containing phenolic resins, phenolic triazines derived
therefrom
    • 含有酚醛树脂的氰基组合物,由其衍生的酚类三嗪
    • US4831086A
    • 1989-05-16
    • US104700
    • 1987-10-05
    • Sajal DasDusan C. Prevorsek
    • Sajal DasDusan C. Prevorsek
    • C08G8/28C08G8/00C08G73/00C08G73/06C08G73/10C08L79/08
    • C08G8/00C08G73/0655
    • The present invention is a cyanato group containing phenolic resin of the formula: ##STR1## wherein n is 0 or an integer of one or more, and R is the same or different and is selected from the group consisting of hydrogen and methyl radicals. The advancement over the art is that the resin of the present invention is stable and has a long shelf life. This is indicated by the gel time of greater than 1 minute, preferably greater than 2 minutes, more preferably greater than 10 minutes, and most preferably greater than 20 minutes at 155.degree. C. Alternately, the improved phenolic triazine resin of the present invention can be characterized as having a thermal stability indicated by thermal decomposition temperature of at least 400.degree. C. and preferably of at least 450.degree. C. as measured by Thermal Gravimetric Analysis (TGA).
    • 本发明是含有下式的含氰基的酚醛树脂,其结构式如下:其中n为0或一个或多个整数,R为相同或不同的并且选自氢和甲基。 本领域的进步是本发明的树脂是稳定的并且具有长的保质期。 这通过在155℃下大于1分钟,优选大于2分钟,更优选大于10分钟,最优选大于20分钟的凝胶时间表示。或者,本发明的改进的酚醛三嗪树脂可以 其特征在于通过热重分析(TGA)测定的热分解温度为至少400℃,优选为至少450℃的热稳定性。