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61. 发明申请

US20050129601A1 Emissions treatment system with NSR and SCR catalysts 有权
标题翻译：具有NSR和SCR催化剂的排放处理系统
公开(公告)号：US20050129601A1
公开(公告)日：2005-06-16
申请号：US10975428
申请日：2004-10-29
申请人： Yuejin Li , Michel Deeba , Joseph Dettling , Joseph Patchett , Stanley Roth
发明人： Yuejin Li , Michel Deeba , Joseph Dettling , Joseph Patchett , Stanley Roth
IPC分类号： B01D53/94 , F01N3/035 , F01N3/08 , F01N3/20 , F01N13/00 , B01J8/00 , C01B21/00 , F01N3/00
CPC分类号： F01N3/035 , B01D53/9418 , B01D53/9422 , B01D53/9459 , B01D2255/202 , B01D2255/204 , B01D2255/2063 , B01D2255/2068 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9022 , B01D2255/908 , B01D2255/91 , B01D2255/9155 , B01D2258/012 , F01N3/0814 , F01N3/0842 , F01N3/2073 , F01N13/009 , F01N13/0093 , F01N2570/04 , F01N2570/16 , F01N2610/02 , F01N2610/03 , Y02T10/24
摘要： Provided is an emissions treatment system for an exhaust stream, having a NOx storage reduction (NSR) catalyst with a NOx sorbent at a concentration of at least 0.1 g/in3 and a platinum group metal component dispersed on a refractory metal oxide support; and, an SCR catalyst disposed downstream of the NSR catalyst. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
摘要翻译：提供了一种排气流的排放处理系统，其具有NOx吸附剂浓度为至少0.1g / in 3以上的NOx吸收剂的NOx储存还原（NSR）催化剂和分散在耐火金属氧化物载体; 以及设置在NSR催化剂下游的SCR催化剂。排放物处理系统有利地用于处理来自柴油发动机和贫燃汽油发动机的废气流。

62. 发明授权

US06568179B2 Apparatus and method for vehicle emissions control 失效
标题翻译：车辆排放控制装置和方法
公开(公告)号：US06568179B2
公开(公告)日：2003-05-27
申请号：US09797236
申请日：2001-03-01
申请人： Michel Deeba
发明人： Michel Deeba
IPC分类号： F01N300
CPC分类号： F01N3/2046 , F01N3/0814 , F01N3/0842 , F01N3/0885 , F01N3/101 , F01N13/009 , F01N13/0093 , F01N2410/00 , F01N2570/04 , Y02A50/2324 , Y02T10/22 , Y02T10/24 , Y02T10/26
摘要： An apparatus and method for vehicle emissions control are disclosed. More particularly, an apparatus and method for insuring that the temperature of a vehicle's exhaust gas stream entering the underfloor catalytic converter during engine operation does not exceed the temperature at which the capability of the multi-functional catalyst in the converter to absorb NOx starts to fall off. A first temperature sensor is provided in the exhaust outlet leading from the exhaust manifold of the engine and a second temperature sensor is provided in the catalytic converter. The catalytic converter contains a multi-functional catalyst such as a three-way conversion catalyst and a NOx trap as well as a NOx sensor at its outlet for sensing when NOx breakthrough is occurring. The sensors transmit their readings to a controller which transmits signal to a proportional valve located in the exhaust outlet downstream of the first temperature sensor. In response to the signals received from the controller, the proportional valve divides the exhaust gas stream received from the engine exhaust manifold into a first stream in communication with the catalytic converter and a second stream in communication with a heat exchanger. Any stream exiting the heat exchanger is then blended with the non-heat exchanged stream and the blended stream is passed into the catalytic converter. The amount of the exhaust gas stream in the first conduit will vary from that in the second conduit such that the temperature entering the catalytic converter is maintained in the range of about 300 to about 600° C. during the lean mode operation of the engine and further such that the multi-functional catalyst is periodically purged of NOx and/or SOx.
摘要翻译：公开了一种用于车辆排放控制的装置和方法。更具体地，涉及一种用于确保在发动机运转期间进入地板下催化转化器的车辆的废气流的温度不超过转化器中的多功能催化剂吸收NOx的能力开始下降的温度的装置和方法关闭第一温度传感器设置在从发动机的排气歧管引出的排气出口中，并且第二温度传感器设置在催化转化器中。催化转化器包含多功能催化剂，例如三元转化催化剂和NOx捕集器，以及在其出口处的NOx传感器，用于在发生NOx突破时感测。传感器将其读数传送到控制器，该控制器将信号传输到位于第一温度传感器下游的排气出口中的比例阀。响应于从控制器接收的信号，比例阀将从发动机排气歧管接收的废气流分成与催化转化器连通的第一流和与热交换器连通的第二流。然后将离开热交换器的任何物流与未热交换的流混合，并将混合的物流进入催化转化器。第一导管中的废气流的量将与第二导管中的排气流量不同，使得在发动机的稀薄模式运行期间进入催化转化器的温度保持在约300至约600℃的范围内，进一步使得多功能催化剂周期性地清除NOx和/或SOx。

63. 发明授权

US06375910B1 Multi-zoned catalytic trap and methods of making and using the same 有权
公开(公告)号：US06375910B1
公开(公告)日：2002-04-23
申请号：US09527910
申请日：2000-03-17
申请人： Michel Deeba , Uwe Dahle , Stefan Brandt
发明人： Michel Deeba , Uwe Dahle , Stefan Brandt
IPC分类号： B01D5394
CPC分类号： B01J23/63 , B01D53/9422 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2027 , B01D2255/2042 , B01D2255/9022 , B01D2255/903 , B01D2258/012 , B01J23/58 , B01J35/0006 , B01J35/04 , B01J37/0242 , B01J37/0244 , B01J37/0248 , F01N3/0807 , F01N3/0814 , F01N3/0842 , F01N3/0871 , F01N3/2828 , F01N2330/00 , F01N2330/06 , F01N2570/14 , F01N2610/03 , Y02A50/2344
摘要： A multi-zoned catalytic trap for conversion of NOx in an exhaust gas stream which emanates from an engine which is operated with periodic alternations between lean, and stoichiometric or rich, conditions. The catalytic trap comprises a first zone, a second zone and, optionally, one or more intermediate zones disposed between the first zone and the second zone. Each of the zones comprises a catalytic trap material coated on a refractory carrier member. In the first zone, the catalytic trap material comprises a refractory metal oxide support having dispersed thereon a palladium catalytic component in the amount of about 30 to about 300 g/ft3, a platinum catalytic component in the amount of 0 to about 100 g/ft3 and a rhodium catalytic component in the amount of 0 to about 10 g/ft3; and a NOx sorbent comprising one or more basic oxygenated compounds of one or more alkaline earth metals and optionally, one or more basic oxygenated compounds of one or more alkali metals. In the second zone, the catalytic trap material comprises a refractory metal oxide support having dispersed thereon a palladium catalytic component in the amount of 0 to about 50 g/ft3, a platinum catalytic component in the amount of about 10 to about 100 g/ft3 and a rhodium catalytic component in the amount of about 5 to about 20 g/ft3; and a NOx sorbent comprising one or more basic oxygenated compounds of one or metals selected from the group consisting of alkali metals and alkaline earth metals. In the optional zone(s), the catalytic trap material comprises a refractory metal oxide support having dispersed thereon a palladium catalytic component in the amount of about 25 to about 75 g/ft3, a platinum catalytic component in the amount of about 5 to about 30 g/ft3 and a rhodium catalytic component in the amount of 0 to about 10 g/ft3; and a NOx sorbent comprising one or more basic oxygenated compounds of one or metals selected from the group consisting of alkali metals and alkaline earth metals.

64. 发明授权

US06093378A Four-way diesel exhaust catalyst and method of use 失效
标题翻译：四通柴油机尾气催化剂及其使用方法
公开(公告)号：US06093378A
公开(公告)日：2000-07-25
申请号：US852458
申请日：1997-05-07
申请人： Michel Deeba , Yiu Kwan Lui , Joseph C. Dettling
发明人： Michel Deeba , Yiu Kwan Lui , Joseph C. Dettling
IPC分类号： B01J29/46 , B01D53/94 , B01J20/18 , B01J29/06 , B01J29/44 , B01J29/70 , B01J29/74 , B01J29/80 , B01J37/02 , F01N3/10 , F01N3/28
CPC分类号： B01J37/0246 , B01D53/945 , B01J29/44 , B01J29/7007 , B01J37/0244 , B01J2229/26 , B01J2229/36 , B01J2229/42 , Y02T10/22
摘要： A catalyst composition and structure containing the same and methods for treating diesel exhaust including a catalyst comprising a precious metal on a support, a first zeolite component in the presence of a precious metal and a second zeolite component comprising a zeolite and a precious metal, and a non-catalytic pore-containing zeolite.
摘要翻译：含有该催化剂组合物的催化剂组合物和结构以及用于处理柴油机废气的方法，包括在载体上包含贵金属的催化剂，在贵金属存在下的第一沸石组分和包含沸石和贵金属的第二沸石组分，以及非催化孔隙沸石。

65. 发明授权

US5849256A Method for oxidizing carbon monoxide in a gas stream containing oxidizable sulphur compounds 失效
标题翻译：在含有可氧化硫化合物的气流中氧化一氧化碳的方法
公开(公告)号：US5849256A
公开(公告)日：1998-12-15
申请号：US638413
申请日：1996-04-26
申请人： Michel Deeba , Barry K. Speronello
发明人： Michel Deeba , Barry K. Speronello
IPC分类号： B01D53/94 , B01J23/644 , B01D53/62
CPC分类号： B01D53/944 , B01J23/6447
摘要： A method for oxidizing carbon monoxide in a waste gas stream that also contains sulfur dioxide is carried out by contacting the waste gas stream under oxidizing conditions with an oxidation catalyst which is effective for promoting the oxidation of carbon monoxide but produces less sulfur trioxide from the sulfur dioxide. The catalyst according to the invention contains platinum dispersed on a refractory inorganic oxide support material with a So.sub.3 -inhibiting quantity of a bismuth compound, such as Bi.sub.2 O.sub.3. The atomic molar ratio of bismuth to platinum is in the range of from about 0.1:1 to 6:1, e.g., 0.5:1 to 3:1, e.g., 1:1.
摘要翻译：通过在氧化条件下使废气流与氧化催化剂接触来进行还含有二氧化硫的废气流中的一氧化碳的方法，所述氧化催化剂有效促进一氧化碳的氧化，但是从硫中产生较少的三氧化硫二氧化碳根据本发明的催化剂包含分散在具有抑制Sb的铋化合物如Bi 2 O 3的耐火无机氧化物载体材料上的铂。铋与铂的原子摩尔比在约0.1:1至6:1的范围内，例如0.5:1至3:1，例如1:1。

66. 发明授权

US4960941A Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts 失效
标题翻译：芳香胺的氢化生成它们的环氢化对应物
公开(公告)号：US4960941A
公开(公告)日：1990-10-02
申请号：US175444
申请日：1988-03-30
申请人： Gamini A. Vedage , William W. Henderson , Bernard A. Toseland , Michel Deeba
发明人： Gamini A. Vedage , William W. Henderson , Bernard A. Toseland , Michel Deeba
IPC分类号： B01J23/46 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/72 , C07C211/35 , C07C211/36
CPC分类号： C07C209/72 , B01J23/464 , C07C2101/14
摘要： This invention relates to an improved hydrogenation process wherein aromatic amines are hydrogenated to their ring hydrogenated counterparts. These aromatic amines are presented by the formulas: ##STR1## wherein R is hydrogen or C.sub.1-6 aliphatic, R.sub.1 and R.sub.2 are hydrogen or C.sub.1-6 aliphatic, A is C.sub.1-4, NH or ##STR2## n is 0-2, x is 1-3 and y is 1 to 2 except the sum of the y groups in Formula I excluding A may be 1.The improvement resides in the use of a rhodium catalyst carried on titania support.

67. 发明授权

US4918233A Production of ethylenediamine from monoethanolamine and ammonia 失效
标题翻译：从单乙醇胺和氨生产乙二胺
公开(公告)号：US4918233A
公开(公告)日：1990-04-17
申请号：US883000
申请日：1986-07-08
申请人： Michel Deeba , Michael E. Ford , Thomas A. Johnson
发明人： Michel Deeba , Michael E. Ford , Thomas A. Johnson
IPC分类号： C07C209/16 , C07C211/10
CPC分类号： C07C209/16
摘要： This invention relates to a process for producing ethylene diamine in high selectivity and high conversion by reacting monoethanolamine with ammonia in the presence of a catalyst. The catalyst which permits the production of ethylenediamine in high selectivity and high conversion is a hydrogen mordenite catalyst that has been treated in such a manner as to raise the silicon to aluminum ratio of the mordenite, such treatment, then being referred to as partial dealumination.
摘要翻译：本发明涉及通过在催化剂存在下使单乙醇胺与氨反应而以高选择性和高转化率生产乙二胺的方法。允许以高选择性和高转化率生产乙二胺的催化剂是已经以使升丝剂的硅与铝比例升高的方式处理的氢丝光沸石催化剂，这种处理，然后被称为部分脱铝。

68. 发明授权

US4458092A Highly active catalysts for methanol amination 失效
标题翻译：用于甲醇胺化的高活性催化剂
公开(公告)号：US4458092A
公开(公告)日：1984-07-03
申请号：US344164
申请日：1982-01-29
申请人： Michel Deeba , Robert N. Cochran
发明人： Michel Deeba , Robert N. Cochran
IPC分类号： B01J29/08 , C07C85/06
CPC分类号： B01J29/084
摘要： A process for improving the methanol conversion rate in the reaction of methanol and ammonia to produce methylamines which comprises effecting the reaction in the presence of a highly acidic dehydrated aluminosilicate catalyst manifesting microporous diffusivity for the methylamines. Rare earth Y zeolite and hydrogen exchanged Y zeolite are the preferred catalysts.
摘要翻译：一种提高甲醇和氨反应产生甲胺的甲醇转化率的方法，其包括在高度酸性脱水的硅铝酸盐催化剂存在下进行反应，表现出甲胺的微孔扩散性。稀土Y沸石和氢交换的Y沸石是优选的催化剂。

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