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    • 64. 发明授权
    • Dibenzylidene sorbitol composition and process for preparation thereof
    • 二亚苄基山梨醇组合物及其制备方法
    • US4388119A
    • 1983-06-14
    • US282739
    • 1981-07-13
    • Hiroshi Uchiyama
    • Hiroshi Uchiyama
    • C08L23/00C08K9/00C08K9/04C08L7/00C08L21/00C08L101/00C09K3/00C08K5/15
    • C08K9/04
    • A composition consisting essentially of solid powdery dibenzylidene sorbitol and a higher fatty acid, the surface of the dibenzylidene sorbitol being coated with the higher fatty acid; and a process for producing dibenzylidene sorbitol powder having a coating of a higher fatty acid on its surface, which comprises a step of forming an aqueous emulsion of the higher fatty acid by adding an alkali to an organic solvent solution or hot molten mass of the higher fatty acid partially saponify the higher fatty acid and dispersing the resulting mixture of the higher fatty acid and its saponification product in water, a step of coating the surface of dibenzylidene sorbitol powder with the higher fatty acid by adding the dibenzylidene sorbitol to the resulting emulsion, and a step of separating the solid from the mixture, drying the solid and recovering the dried product. The transparency and rigidity of a polyolefin resin is improved by addition of aforesaid dibenzylidene sorbitol composition.
    • 基本上由固体粉末二亚苄基山梨糖醇和高级脂肪酸组成的组合物,二亚苄基山梨醇的表面被高级脂肪酸包被; 以及其表面具有高级脂肪酸的涂层的二亚苄基山梨糖醇粉末的制造方法,其包括通过向有机溶剂溶液中加入碱而形成高级脂肪酸的水性乳液的步骤, 脂肪酸部分皂化高级脂肪酸,并将所得到的高级脂肪酸及其皂化物的混合物分散在水中,通过向所得乳液中加入二亚苄基山梨糖醇,将高级脂肪酸二亚苄基山梨糖醇粉末的表面进行涂布, 和从混合物中分离固体的步骤,干燥固体并回收干燥产物。 通过加入上述二亚苄基山梨糖醇组合物可提高聚烯烃树脂的透明度和刚性。