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    • 54. 发明授权
    • Heat exchange system for processing solid particulates
    • 用于处理固体颗粒物的热交换系统
    • US5320168A
    • 1994-06-14
    • US52175
    • 1993-04-23
    • Ehrick K. Haight
    • Ehrick K. Haight
    • B01J8/08B01J8/12F28F3/14F28F3/12
    • B01J8/087B01J8/12F28F3/14Y10S165/92
    • A system for heat exchange processing of particulate solid material is disclosed. The particulate solids are flowed by gravity through a housing packed with flat, internally cooled (or heated) heat exchange panels spaced apart to define generally vertical channels for the passage of the solid particulate. The panels are formed of opposed metal sheets, sealed around their edges, spot welded together in limited areas of joinder, in a predetermined pattern over their surfaces, and hydrostatically expanded in the areas between to form surfaces that are quilt-like in appearance. The panels are configured in two alternate forms such that, when a plurality of panels are assembled in a stack, the hydrostatically expanded portions of one panel are disposed opposite the areas of joinder of an adjacent panel of alternate configuration, creating a sinuous, but relatively uniform flow path for the flow of particulate solids between panels. High system efficiency is achieved by enabling adjacent panels to be spaced closer together while still avoiding the problem of "bridging" of the solid particulate material between panels.
    • 公开了一种用于颗粒状固体材料的热交换处理的系统。 颗粒固体通过重力流动通过间隔开的平坦的,内部冷却(或加热的)热交换板的壳体,以限定用于固体颗粒通过的大体上垂直的通道。 面板由相对的金属板形成,围绕它们的边缘密封,在有限的接合区域中在其表面上以预定图案点焊在一起,并且在形成被外观的表面之间的区域中进行流体静力膨胀。 面板被配置成两种替代形式,使得当多个面板组装成堆叠时,一个面板的流体静力学膨胀的部分与相邻的替代构造的面板的接合区域相对设置,产生弯曲但相对的 用于板之间的颗粒状固体流动的均匀流动路径。 通过使相邻的面板间隔得较近,可以实现高系统效率,同时避免了在面板之间“固定”固体颗粒材料的问题。
    • 55. 发明授权
    • Catalyst regeneration apparatus with radial flow distribution
    • 具有径向流量分布的催化剂再生装置
    • US5277880A
    • 1994-01-11
    • US826498
    • 1992-01-27
    • Paul A. SechristWilliam J. Koves
    • Paul A. SechristWilliam J. Koves
    • B01J8/12B01J38/32B01J38/40C10G45/12
    • B01J38/40B01J38/32B01J8/12C10G45/12
    • Apparatus for regenerating spent hydrocarbon conversion catalyst. Catalyst particles in a vertically-elongated movable tapered bed are contacted with a hot oxygen-containing gas stream in order to remove, by means of combustion, coke which accumulated on the catalyst particles while they were used in a hydrocarbon conversion zone. Catalyst moves downward under the influence of gravity. The catalyst bed is tapered such that the thickness of the bed, in a dimension which is transverse to the direction of catalyst movement, varies from a minimum at the top of the tapered bed to a maximum at the bottom of the tapered bed. Gas passes through the tapered bed in a direction which is substantially transverse to the direction of catalyst movement. Substantially, all of the catalyst in the bed is in contact with the flowing gas. The variation in bed thickness causes a varying gas flow rate through the bed, from a maximum flow rate at the top of the tapered bed to a minimum flow rate at the bottom of the tapered bed and reduces the time that catalyst is exposed to high temperature gases. This flow pattern results in the delivery of oxygen in a manner which more closely matches the oxygen requirement for combustion at each point in the tapered bed. Advantages of the invention include increased coke burning capacity and longer catalyst life. Catalytic reforming is an example of a hydrocarbon conversion process in which the invention may be advantageously employed.
    • 废碳氢转化催化剂再生设备。 在垂直细长的可移动锥形床中的催化剂颗粒与含热氧气流接触,以便通过燃烧除去在烃转化区中使用时积聚在催化剂颗粒上的焦炭。 催化剂在重力的作用下向下移动。 催化剂床是锥形的,使得床的厚度在垂直于催化剂运动方向的尺寸上从锥形床顶部的最小值到锥形床底部的最大值。 气体沿着基本上横向于催化剂运动方向的方向通过锥形床。 基本上,床中的所有催化剂与流动的气体接触。 床厚度的变化导致通过床的不同气体流速,从锥形床顶部的最大流速到锥形床底部的最小流速,并减少催化剂暴露于高温的时间 气体。 该流动模式导致氧气的传送方式与锥形床中的每个点处的燃烧氧需求更接近。 本发明的优点包括增加焦炭燃烧能力和更长的催化剂寿命。 催化重整是可以有利地使用本发明的烃转化方法的实例。
    • 56. 发明授权
    • Moving-bed reactor, in particular for the treatment of flue gases
    • 移动床反应器,特别是用于处理烟道气
    • US5169607A
    • 1992-12-08
    • US647505
    • 1991-01-29
    • Wolfgang KrambrockJoerg SchwedesHarald Wilms
    • Wolfgang KrambrockJoerg SchwedesHarald Wilms
    • B01D53/08B01D53/34B01D53/74B01D53/81B01J8/12F23J15/00F23J15/02
    • B01J8/12B01D53/74F23J15/02
    • A moving bed reactor for the treatment of fluid in a countercurrent process includes a reactor vessel having, in an upper region thereof, an inlet for receiving particulate material and an outlet for discharging treated fluid, the reactor vessel also having, in a lower region thereof, a downward tapering first funnel leading to an outlet, the first funnel guiding the particulate material to the outlet for discharge from the reactor vessel, the first funnel being formed by wall sections which mutually overlap in louvre fashion to create slot-shaped passages for the fluid to be treated to enter the vessel. A second funnel is provided, surrounding the first funnel and communicating with the slot-shaped passages, the second funnel having an inlet for receiving the fluid to be treated, there being provided an annular canal between the second funnel and the first funnel at the lower regions thereof, which annular canal communicates with the particulate discharge outlet so that any particulate material which enters the second funnel by the slot-shaped passages is guided to the particulate discharge outlet through the annular canal.
    • 用于在逆流过程中处理流体的移动床反应器包括反应器容器,其在其上部区域中具有用于接收颗粒材料的入口和用于排出处理过的流体的出口,反应器容器在其下部区域中还具有 通向出口的向下渐缩的第一漏斗,第一漏斗将颗粒材料引导到出口以从反应器容器排出,第一漏斗由壁部分形成,壁部分以百叶窗方式相互重叠以形成槽形通道,用于 待处理的流体进入容器。 提供第二漏斗,围绕第一漏斗并与槽形通道连通,第二漏斗具有用于接收待处理流体的入口,在第二漏斗和下漏斗之间的第一漏斗之间设置有环形管道 其环形管道与颗粒排出口连通,使得通过槽形通道进入第二漏斗的任何颗粒材料通过环形管被引导到颗粒排放出口。
    • 57. 发明授权
    • Apparatus for powder falling gas-solid contacting operation
    • 用于粉末气体固体接触操作的装置
    • US5113598A
    • 1992-05-19
    • US598306
    • 1990-10-16
    • Shun WachiJohn G. Yates
    • Shun WachiJohn G. Yates
    • B01J8/12B01J8/00B01J8/18
    • B01J8/1881B01J8/003B01J8/1809
    • An apparatus for powder falling type gas-solid contacting operation which comprises a hopper for feeding solid particles, a fluidizing bunker wherein the fed particles are fluidized by introduction of a fluidizing gas, a standpipe provided between the hopper and the bunker for feeding the particles from the hopper to the bunker, the lower end of the standpipe being located in the bunker, and a vertical gas-solid column connected to the bottom of the bunker for bringing the particles falling down from the bunker into contact with a gas countercurrently, in which a vertical tube is provided in the bunker so as to surround at least the lower end part of the standpipe and extend to a position below the lower end of the standpipe, whereby the height of the fluidized bed of the particles in the bunker is stably kept constant and the particles are fed from the bunker to the gas-solid column at a constant rate.
    • 一种用于粉末落下式气固接触操作的装置,包括用于供给固体颗粒的料斗,流化料仓,其中所述进料颗粒通过引入流化气体而流化,设置在料斗和料仓之间的竖管,用于将颗粒从 料斗到沙坑,竖管的下端位于沙坑中,垂直的气固柱连接到沙坑的底部,用于使从沙坑落下的颗粒逆流地与气体接触,其中 竖管设置在沙坑中,以便至少围绕立管的下端部并且延伸到立管的下端下方的位置,从而稳定地保持了料仓中的颗粒的流化床的高度 恒定,并且颗粒以恒定速率从燃料舱输送到气固塔。
    • 59. 发明授权
    • Apparatus for upgrading liquid hydrocarbons
    • 液化烃升级装置
    • US4944845A
    • 1990-07-31
    • US365118
    • 1989-07-03
    • David B. Bartholic
    • David B. Bartholic
    • B01J8/08B01J8/12C10G25/08
    • B01J8/12B01J8/085C10G25/08
    • Apparatus for the treatment of a liquid hydrocarbon charge containing solids or solids-forming contaminants, e.g., inorganic solids, metals and asphaltenes, which includes a contactor vessel having a liquid charge inlet, a vaporizing media inlet above the charge inlet and a vapor-solids outlet. An atomizer is positioned in the charge inlet for forming small particles of the liquid charge and directing the particles of liquid in a substantially horizontal flat pattern into the contactor vessel. A premix downcomer having a dispersion grid positioned therein is located in the vaporizing media inlet for introducing a fluidized mixture of a gas dispersion media and hot circulating solid particles into the contactor vessel in a substantially vertical flat pattern to traverse the path of the liquid particles and intimately contact the liquid particles. The vapor-solids-outlet is positioned in the contactor vessel substantially opposite the liquid charge inlet to receive product vapors and entrain solid particles and rapidly pass the same into cyclones connected to the vapor-solids-outlet for separating solid particles from product vapors. A stripper vessel is located beneath the contactor vessel for receiving heavy solid particles and stripping hydrocarbons therefrom.
    • 用于处理含有固体或固体形成污染物的液体烃装料的设备,例如无机固体,金属和沥青质,其包括具有液体进料口的接触器容器,在进料口上方的蒸发介质入口和蒸气固体 出口。 雾化器位于充电入口中,用于形成液体电荷的小颗粒,并将基本上水平的平坦图案的液体颗粒引导到接触器容器中。 具有位于其中的分散格栅的预混合降液管位于蒸发介质入口中,用于以基本垂直的平坦图案将气体分散介质和热循环固体颗粒的流化混合物引入接触器容器中以横穿液体颗粒的路径, 紧密接触液体颗粒。 蒸气固体出口位于接触器容器中,基本上与液体进料口相对,以接收产品蒸气并夹带固体颗粒,并将其快速通过连接到蒸汽固体出口的旋风分离器,以将固体颗粒与产物蒸气分离。 剥离器容器位于接触器容器下面,用于接收重的固体颗粒并从其中汽提碳氢化合物。
    • 60. 发明授权
    • Upgrading naphtha in a single riser fluidized catalytic cracking
operation employing a catalyst mixture
    • 在使用催化剂混合物的单提升流化催化裂化操作中升级石脑油
    • US4892643A
    • 1990-01-09
    • US336571
    • 1989-04-11
    • Joseph A. HerbstHartley OwenPaul H. Schipper
    • Joseph A. HerbstHartley OwenPaul H. Schipper
    • B01J8/00B01J8/12C10G11/18
    • C10G11/18B01J8/005B01J8/12
    • The present invention discloses a catalytic cracking operation featuring a single riser in which a variety of hydrocarbon conversion reactions takes place, a stripping unit in which entrained hydrocarbon material is removed from catalyst and a regeneration zone in which spent cracking catalyst is regenerated, which comprises:(a) converting a relatively high boiling charge material introduced to the riser at a lower level thereof in the presence of a first catalyst component which is an amorphous cracking catalyst and/or a large pore crystalline silicate cracking catalyst to provide lighter products including significant quantities of naphtha; and,(b) converting a naphtha charge material introduced to the riser at a higher level thereof in the presence of a second catalyst componet which is a shape selective medium pore crystalline silicate zeolite catalyst to provide a relatively high octane gasoline product.
    • 本发明公开了一种催化裂化操作,其特征在于单个提升管中发生各种烃转化反应,其中从催化剂中除去夹带烃材料的汽提单元和再生废裂解催化剂的再生区,其包括: (a)在第一催化剂组分(其是无定形裂化催化剂和/或大孔结晶硅酸盐裂化催化剂)存在下,将其引入其提升管的较高沸点的加料物质转化为较低水平,以提供包括显着量 的石脑油 和(b)在第二催化剂组分(其是形状选择性中孔孔结晶硅酸盐沸石催化剂)存在下,将在其较高水平引入的提升管的石脑油加料物质转化,以提供相对高的辛烷值汽油产物。