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    • 54. 发明授权
    • Red nitride phosphor and production method thereof
    • 红色氮化物荧光粉及其制备方法
    • US08148886B2
    • 2012-04-03
    • US11795298
    • 2006-01-25
    • Shin-ichi SakataTakeshi YamaoTetsuo Yamada
    • Shin-ichi SakataTakeshi YamaoTetsuo Yamada
    • C09K11/59C09K11/08
    • C09K11/0883C01B21/0602C01P2002/54C01P2002/72C01P2002/77C01P2002/84C01P2006/60C09K11/7728
    • A red phosphor where the crystal phase constituting the phosphor is monoclinic Eu-activated CaAlSiN3. A red phosphor which is Eu-activated CaAlSiN3 powder having an average particle diameter of 10 μm or less as measured in the non-pulverized state by the laser scattering particle size distribution analysis. A light-emitting device comprising a blue light-emitting element, a yellow phosphor capable of converting the blue light emitted from the blue light-emitting element into yellow light, and the above-described red phosphor capable of converting the blue light emitted from the blue light-emitting element into red light. A method for producing Eu-activated CaAlSiN3, comprising firing a raw material powder comprising Ca3N2, AlN, Si3N4 and EuN at 1,400 to 2,000° C. in a nitrogen-containing atmosphere, the Ca3N2, AlN and Si3N4 giving a composition falling in the region surrounded by a straight line connecting the following four points A to D in the composition diagram of FIG. 1, and EuN being contained in an amount of 0.01 to 10 parts by weight as Eu per 100 parts by weight in total of Ca3N2, AlN and Si3N4.
    • 构成荧光体的晶相的红色荧光体为单斜晶Eu激活CaAlSiN3。 一种红色荧光体,其是通过激光散射粒度分布分析在非粉碎状态下测定的平均粒径为10μm以下的Eu活化CaAlSiN 3粉末。 一种发光装置,包括蓝色发光元件,能够将从蓝色发光元件发射的蓝色光转换成黄色光的黄色荧光体,以及上述红色荧光体,其能够将从蓝色发光元件发出的蓝色光 蓝色发光元件变成红灯。 一种Eu活化的CaAlSiN 3的制造方法,其特征在于,在含氮气氛中,在1400〜2000℃下烧成含有Ca3N2,AlN,Si3N4,EuN的原料粉末,使Ca3N2,AlN,Si3N4在该区域 由连接图4的组成图中的以下四点A至D的直线包围。 1,EuN的含量相对于Ca3N2,AlN和Si3N4总计为100重量份,为Eu为0.01〜10重量份。
    • 58. 发明授权
    • Luminescent silicon nanoparticle-polymer composites, composite wavelength converter and white LED
    • 发光硅纳米颗粒 - 聚合物复合材料,复合波长转换器和白光LED
    • US08076410B2
    • 2011-12-13
    • US12241870
    • 2008-09-30
    • Munir H. NayfehSalman A. H. Alrokayan
    • Munir H. NayfehSalman A. H. Alrokayan
    • C08F292/00C09K11/59H01J1/63
    • C09K11/02C09K11/59H01L33/502
    • An embodiment of the invention is luminescent silicon nanoparticle polymer composite that can serve as a wavelength converter or a UV absorber. The composite includes a polymer or an organosilicon compound; and within the polymer or organosilicon compound, a dispersion of luminescent silicon nanoparticles. In a preferred composite, the silicon nanoparticles have multiple Si—H termination sites, the silicon nanoparticles being linked to a C site to produce a silicon carbide bond (Si—C). In a preferred embodiment, the polymer comprises polyurethane. A composite of the invention can perform wavelength conversion. In a wavelength converted film of the invention, the silicon nanoparticles are incorporated into the polymer or organosilicon compound in a quantity sufficient for wavelength conversion but small enough to have no or an insubstantial effect on the properties of the polymer or the organosilicon compound. A white LED of the invention includes a light emitting diode having a narrow band wavelength output. A luminescent silicon wavelength converter includes a composite film as described above for converting the narrow band wavelength output into wide band wavelength output. In a preferred embodiment, the LED comprises a GaN LED, and the wavelength converter film is disposed on an active region of the LED.
    • 本发明的一个实施方案是可用作波长转换器或UV吸收剂的发光硅纳米颗粒聚合物复合材料。 复合材料包括聚合物或有机硅化合物; 并且在聚合物或有机硅化合物内,发光硅纳米颗粒的分散体。 在优选的复合材料中,硅纳米颗粒具有多个Si-H终止位点,硅纳米颗粒与C位点连接以产生碳化硅键(Si-C)。 在优选的实施方案中,聚合物包含聚氨酯。 本发明的复合物可以进行波长转换。 在本发明的波长转换膜中,将硅纳米颗粒掺入到聚合物或有机硅化合物中,其量足够于波长转换,但足够小以致对聚合物或有机硅化合物的性质没有或没有实质性的影响。 本发明的白色LED包括具有窄带波长输出的发光二极管。 发光硅波长转换器包括如上所述的用于将窄带波长输出转换成宽带波长输出的复合膜。 在优选实施例中,LED包括GaN LED,并且波长转换器膜设置在LED的有源区上。