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    • 53. 发明申请
    • POLYETHYLENE MOLDING COMPOSITION FOR PRODUCING BLOWN FILMS HAVING IMPROVED PROCESSABILITY
    • 用于生产具有改进的可加工性的薄膜的聚乙烯模塑组合物
    • US20160251504A1
    • 2016-09-01
    • US15154800
    • 2016-05-13
    • Basell Polyolefine GmbH
    • Joachim BertholdLutz-Gerd HeinickeGerhardus Meier
    • C08L23/06C08J5/18
    • C08L23/06C08J5/18C08J2323/04C08J2323/06C08J2423/08C08L23/04C08L23/08C08L23/0807C08L23/0815C08L2203/16C08L2205/025C08L2205/03C08L2666/06
    • The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 μm. The molding composition has a density at a temperature of 23° C. in the range from 0.953 to 0.960 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight. The molding composition of the invention allows to produce thin films having improved processability without impairing the mechanical properties.
    • 本发明涉及具有特别适用于厚度在8至200μm范围内的吹塑薄膜的多峰摩尔质量分布的聚乙烯模塑组合物。 模塑组合物的密度在23℃的温度范围为0.953至0.960g / cm3,挤出后的最终产品的MFR 190/5为0.10至0.50dg / min。 该组合物包含30至60重量%的由具有第一分子量的均聚物A制成的第一乙烯聚合物部分,22至40重量%的由其它均聚物或第一共聚物B制成的第二乙烯聚合物部分 乙烯和来自具有4至8个碳原子的烯烃基团的至少一种第一共聚单体,第一共聚物B具有高于第一分子量的第二分子量和10至30重量%的第三乙烯聚合物部分 由具有高于第二分子量的第三分子量的第二共聚物C制成。 本发明的模塑组合物允许制造具有改进加工性能的薄膜而不损害机械性能。
    • 54. 发明授权
    • Solution polymerization processes with reduced energy usage
    • 溶液聚合过程减少能源消耗
    • US09428597B2
    • 2016-08-30
    • US14771355
    • 2014-03-04
    • NOVA Chemicals (International) S.A.
    • Terri A PriceFazle SibtainEric Cheluget
    • C08F10/02C08F2/06C08F6/02C08F6/06C08F6/10C08J11/02C08F6/00
    • C08F10/02C08F6/003C08F6/02C08J11/02C08L23/04C08F2/01C08F2/06C08F210/16C08F210/14
    • An improved solution polymerization process wherein energy consumption is reduced comprising: i) injecting ethylene, solvent, catalyst, α-olefins and hydrogen into at least one reactor to produce a polyethylene in a single liquid phase solution; ii) deactivating the single liquid phase solution; iii) passing the deactivated solution into a vapor/liquid separator forming a bottom stream of polyethylene rich solvent and a gaseous overhead stream; iv) passing not more than 40% of the gaseous overhead stream to distillation; v) condensing the remainder of the gaseous overhead stream to form a recycle stream, while generating low pressure steam; vi) passing the recycle stream through a means for oligomer removal; vii) passing the recycle stream through a lights separator; viii) passing the recycle stream through a purification step; ix) collecting the recycle stream in a recycle drum, passing the recycle stream through a pump and injecting a high pressure recycle stream into said reactors.
    • 改进的溶液聚合方法,其中能量消耗降低,包括:i)将乙烯,溶剂,催化剂,α-烯烃和氢气注入至少一个反应器中以在单一液相溶液中制备聚乙烯; ii)使单一液相溶液失活; iii)将失活的溶液通入形成富含聚乙烯的溶剂和气态塔顶液流的底部流的气/液分离器; iv)将不超过40%的塔顶气流送入蒸馏; v)冷凝剩余的气态塔顶物流以形成循环流,同时产生低压蒸汽; vi)使再循环流通过用于低聚物去除的装置; vii)使循环流通过灯分离器; viii)使循环流通过净化步骤; ix)在再循环鼓中收集循环物流,使循环流通过泵并将高压循环物流注入所述反应器。