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51. 发明申请

US20060043646A1 Method of manufacturing heat-resistant mould articles made of polyethylene terephthalate polyesters 有权
标题翻译：制造由聚对苯二甲酸乙二醇酯聚酯制成的耐热模具制品的方法
公开(公告)号：US20060043646A1
公开(公告)日：2006-03-02
申请号：US10927118
申请日：2004-08-27
申请人： Yukio Kobayashi , Takashi Fujimaki , Takashi Nakamoto
发明人： Yukio Kobayashi , Takashi Fujimaki , Takashi Nakamoto
IPC分类号： B29C35/10 , B29C47/76 , B29C47/88 , B29C51/02 , B29C51/10
CPC分类号： C08J3/226 , B29C47/0004 , B29C47/0019 , B29C47/0021 , B29C47/0054 , B29C47/0057 , B29C47/8805 , B29C47/8845 , B29C47/90 , B29C47/904 , B29C51/002 , B29C51/10 , B29C67/246 , B29C2035/046 , B29C2791/006 , B29C2791/007 , B29K2063/00 , B29K2067/00 , B29K2105/0014 , B29K2105/256 , B29K2105/26 , B29K2995/0017 , B29K2995/0026 , B29L2007/002 , C08J2367/02 , C08J2467/00 , C08K5/098 , C08L63/00 , C08L67/02 , C08L2666/22
摘要： The present invention provides a method of manufacturing high-melting-tension heat-resistant transparent or opaque sheets, boards, and moulds from polyethylene terephthalate (PET). The method is characterised in that a mixture of: (1) PET polyester whose melt flow rate (MFR) is 45-130 g/10 minutes (a); (2) coupling agent master batch (f) comprising coupling agent (d) and substrate (e), wherein coupling agent (d) is a mixture of compounds containing 2 epoxy groups (b) and compounds containing 3 or more epoxy groups (c); and (3) catalyst master batch (i) comprising coupling reaction catalyst (g) and substrate (h); is melted in a reaction-extruder to give PET polyester whose MFR is 40 g/10 minutes or less. The resulting PET polyester is moulded into amorphous sheets or boards, and then heated again to a predetermined temperature to give transparent heat-resistant sheets or boards; or then vacuum-, pressure-, or vacuum-pressure-formed following heat-setting to give transparent heat-resistant or white opaque highly-heat-resistant mould articles.
摘要翻译：本发明提供一种由聚对苯二甲酸乙二醇酯（PET）制造高熔点耐热透明或不透明片材，板材和模具的方法。该方法的特征在于：（1）熔体流动速率（MFR）为45〜130g / 10分钟（a）的PET聚酯的混合物; （2）包含偶联剂（d）和底物（e）的偶联剂母料（f），其中偶联剂（d）是含有2个环氧基团（b）和含有3个或更多个环氧基团的化合物的混合物（c））; 和（3）包含偶联反应催化剂（g）和底物（h）的催化剂母料（i）; 在反应挤出机中熔融，得到MFR为40g / 10分钟以下的PET聚酯。将所得的PET聚酯模制成非晶片或板，然后再次加热至预定温度，得到透明的耐热片或板; 然后在热定型之后进行真空，压力或真空压力成形，以提供透明的耐热或白色不透明的高耐热模具制品。

52. 发明申请

US20040241419A1 Porous insulating film and its laminates 审中-公开
标题翻译：多孔绝缘膜及其层压板
公开(公告)号：US20040241419A1
公开(公告)日：2004-12-02
申请号：US10784982
申请日：2004-02-25
申请人： Ube Industries, Ltd.
发明人： Shigeru Yao , Yukihiko Asano , Shyusei Ohya , Kenji Fukunaga , Masayuki Kinouchi , Kenji Kawabata
IPC分类号： B32B003/26
CPC分类号： B32B15/08 , B29C41/12 , B29K2995/0006 , B29K2995/0007 , B29K2995/0017 , B29L2031/3061 , B32B3/26 , B32B5/18 , B32B7/12 , B32B27/06 , B32B27/16 , B32B27/281 , B32B2305/026 , B32B2307/202 , B32B2307/204 , B32B2307/206 , B32B2307/306 , B32B2307/714 , B32B2307/7242 , B32B2457/08 , C08G73/105 , C08G73/1067 , C08G73/1071 , C08J5/18 , C08J2379/08 , H01M2/1613 , H01M2/1653 , H01M2/166 , H01M2/1686 , H01M10/056 , H01M2300/0094 , H05K1/0346 , Y10S428/901 , Y10T428/24917 , Y10T428/249958 , Y10T428/249978 , Y10T428/249979 , Y10T428/249982 , Y10T428/24999 , Y10T428/31721
摘要： A porous insulating film comprising a highly heat resistant resin film having a fine porous structure with a mean pore size of 0.01-5 nullm in at least the center of the film, and a porosity of 15-80%. A laminate is prepared by forming a heat resistant adhesive layer or a conductive metal layer or an inorganic or metal substrate on one or both sides of the porous insulating film or by forming an inorganic or metal substrate on one side of the porous insulating film and a conductive metal layer on the other side.
摘要翻译：一种多孔绝缘膜，其特征在于，至少在膜的中央具有平均孔径为0.01-5μm的微孔结构的高耐热性树脂膜，孔隙率为15〜80％。通过在多孔绝缘膜的一面或两面上形成耐热粘合剂层或导电金属层或无机或金属基底或通过在多孔绝缘膜的一侧上形成无机或金属基底而制备层压体，以及导电金属层在另一侧。

53. 发明申请

US20040105970A1 Low density composite rocket nozzle components and process for making the same from standard density phenolic matrix, fiber reinforced materials 审中-公开
标题翻译：低密度复合火箭喷嘴组件及其制备方法由标准密度酚醛树脂基体，纤维增强材料制成
公开(公告)号：US20040105970A1
公开(公告)日：2004-06-03
申请号：US10721697
申请日：2003-11-25
发明人： Allan P. Thompson , John K. Shigley
IPC分类号： B32B003/26 , B32B005/14
CPC分类号： B29C70/44 , B29K2105/04 , B29K2995/0017 , B29K2995/0063 , B29L2031/3097 , Y10T428/249953 , Y10T428/249958
摘要： A process for producing low-density composite components as disclosed herein involves forming a compacted and curable pre-preg into a selected level of compaction whereby voids are capable of forming in the compacted curable pre-preg. The compacted curable pre-preg is then cured at a pressure sufficiently low to permit evolving gases to form voids in the pre-preg as the pre-preg cures into the composite article. The pre-preg is only partially debulked in the process. Rocket nozzle components may be produced with reduced densities while still exhibiting satisfactory erosion and other characteristics desired for products subject to the harsh erosive environment of a rocket motor.
摘要翻译：如本文所公开的生产低密度复合材料组分的方法包括将压实和可固化的预浸料形成为选定的压实水平，由此在压实的可固化预浸料中能够形成空隙。然后将压实的可固化预浸料在足够低的压力下固化，以便在预固化成复合制品之前允许放出的气体在预浸料中形成空隙。在此过程中，pre-preg仅部分减弱。火箭喷嘴部件可以以更低的密度生产，同时仍然表现出令人满意的侵蚀以及受到火箭发动机的严酷腐蚀环境的产品所需的其它特性。

54. 发明申请

US20030136788A1 Fuel tank and method of making same 审中-公开
标题翻译：油箱及其制作方法
公开(公告)号：US20030136788A1
公开(公告)日：2003-07-24
申请号：US10056764
申请日：2002-01-24
发明人： Albert Marion Beaty
IPC分类号： B60P003/00 , B62D033/00 , B65D088/12
CPC分类号： B29C45/0013 , B29B7/90 , B29B9/12 , B29C45/1816 , B29C2791/001 , B29K2023/065 , B29K2105/16 , B29K2995/0017 , B29K2995/0067 , B29L2031/7172
摘要： A heat and effusion resistant fuel tank (34) and method of fabricating it wherein granules (12) of a thermoplastic are melted to a viscous state and amorphous silica in a powder state (14) is added and mixed into a compound. The compound is pelletized (22) and later processed through an injection molding machine (26) to form a fuel tank (34) in a mold (32).
摘要翻译：一种防溢油燃料箱（34）及其制造方法，其中将热塑性塑料的颗粒（12）熔化成粘性状态，并将粉末状态的无定形二氧化硅（14）加入并混合成化合物。将化合物造粒（22），然后通过注塑机（26）加工，以在模具（32）中形成燃料箱（34）。

55. 发明授权

US6099789A Molded article laminated with heat insulating sheet member and production process therefor 有权
标题翻译：用隔热片材层压的模制品及其制造方法
公开(公告)号：US6099789A
公开(公告)日：2000-08-08
申请号：US296478
申请日：1999-04-22
申请人： Takehiko Sumi
发明人： Takehiko Sumi
IPC分类号： B29C49/20 , B29C49/00 , B29C49/04 , B29C49/24 , B29C45/14 , B29C45/16 , B29C45/32 , B29C49/06 , B29D22/00
CPC分类号： B29C49/0005 , B29C49/24 , B29C2049/2412 , B29C49/04 , B29K2105/16 , B29K2713/00 , B29K2995/0017 , B29L2024/00 , Y10T428/1362 , Y10T428/1372 , Y10T428/1386
摘要： A molded article includes a hollow molded body formed of a base material and a heat insulating sheet member laminated to an outer surface of the hollow molded body. The base material is a blended material which contains about 50% by weight to about 90% by weight of a thermoplastic resin and about 10% by weight to about 50% by weight of an inorganic material, and has a flexural rigidity of at least about 1,350 MPa at 23.degree. C. and a flexural rigidity of at least about 550 MPa at 60.degree. C. A process for producing a molded article includes placing a heat insulating sheet member on a surface of a mold cavity of at least one mold half of separated mold halves, inserting a parison formed of a blended material having the above-described composition and flexural rigidity characteristics between the mold halves, clamping the mold halves, and introducing a pressurized fluid into the parison to inflate the parison in conformity with a shape of the mold cavity and bond the heat insulating sheet member thereto, to produce a molded article including a hollow molded body having a heat insulating sheet member laminated to an outer surface thereof.
摘要翻译：模制品包括由基材形成的中空成型体和层压到中空成型体的外表面的隔热片构件。基材是一种混合材料，其包含约50重量％至约90重量％的热塑性树脂和约10重量％至约50重量％的无机材料，并且具有至少约在23℃下为1350MPa，在60℃下的抗弯刚度为至少约550MPa。制造模制品的方法包括将绝热片构件放置在至少一个模具半部的模腔表面上分离的半模，在半模之间插入由具有上述组成和弯曲刚度特性的混合材料形成的型坯，夹紧半模，并将加压流体引入型坯中，以使型坯膨胀，模具腔并将绝热片材结合到其上，以制造包括中空成型体的模制品，该中空成型体具有层压到其外表面的绝热片材。

56. 发明授权

US5928742A Double-blown pet bottle shaped container having essentially no residual stress and superior heat resistance 失效
标题翻译：双吹宠物瓶形容器基本上没有残余应力和优异的耐热性
公开(公告)号：US5928742A
公开(公告)日：1999-07-27
申请号：US980019
申请日：1997-11-26
申请人： Horoaki Sugiura , Fuminori Tanaka , Daisuke Uesugi
发明人： Horoaki Sugiura , Fuminori Tanaka , Daisuke Uesugi
IPC分类号： B29C49/00 , B29C49/06 , B29C49/16 , B29C49/18 , B29C49/64 , B29C61/02 , B29C49/08 , B29D22/00
CPC分类号： B29C49/649 , B29C49/16 , B29C49/18 , B29C49/00 , B29C49/06 , B29C61/02 , B29K2067/00 , B29K2995/0017 , B29K2995/0053 , Y10S264/906 , Y10S264/908 , Y10S264/909 , Y10S428/91 , Y10T428/1352 , Y10T428/1397
摘要： A biaxially oriented polyethylene terephthalate resin bottle-shaped container, and method of blow-molding the same, is disclosed. The method comprises the steps of heating the body portion of a preform at 90.degree. to 130.degree. C., biaxial-orientation blow-molding the preform in a primary blowing mold heated at 110 to 230.degree. C. to form a primary intermediate molded bottle-shaped piece, heating the primary intermediate molded bottle-shaped piece at 130 to 255.degree. C. or at a temperature which is at least 20.degree. C. greater than the primary blowing mold temperature to form a secondary intermediate molded bottle-shaped piece, and blow-molding the secondary intermediate molded bottle-shaped piece in a secondary blowing mold heated at 100.degree. to 150.degree. C. to form a bottle-shaped container. The temperature of the secondary blowing mold is several degrees greater than the maximum temperature the molded bottle-shaped container will be subjected to during use. The bottle-shaped container of the present invention has no stress remaining from biaxial orientation blow-molding and has a high heat resistance temperature value.
摘要翻译：公开了一种双轴取向的聚对苯二甲酸乙二醇酯树脂瓶形容器及其吹塑方法。该方法包括以下步骤：将预制件的主体部分在90°至130℃加热，双轴取向吹塑成型预成型件，该模具加热至110-230℃，以形成初级中间模塑瓶在130-255℃或比初级吹塑模具温度高至少20℃的温度下加热初级中间模塑瓶形件以形成二次中间成型瓶形件，并将二次中间成型的瓶形件吹塑在加热至100-150℃的二次吹塑模具中以形成瓶形容器。二次吹塑模具的温度比成型瓶形容器在使用过程中经受的最高温度大几度。本发明的瓶状容器在双轴取向吹塑成型中没有应力残留，耐热温度高。

57. 发明授权

US5747130A Intermediate product capable of being formed into a biaxially oriented polyethylene terephthalate resin bottle-shaped container and method of blow-molding the same 失效
标题翻译：能够形成双轴取向的聚对苯二甲酸乙二醇酯树脂瓶形容器的中间产物及其吹塑成型方法
公开(公告)号：US5747130A
公开(公告)日：1998-05-05
申请号：US683431
申请日：1996-07-18
申请人： Horoaki Sugiura , Fuminori Tanaka , Daisuke Uesugi
发明人： Horoaki Sugiura , Fuminori Tanaka , Daisuke Uesugi
IPC分类号： B29C49/00 , B29C49/06 , B29C49/16 , B29C49/18 , B29C49/64 , B29C61/02 , B29C49/08 , B29D22/00
CPC分类号： B29C49/649 , B29C49/16 , B29C49/18 , B29C49/00 , B29C49/06 , B29C61/02 , B29K2067/00 , B29K2995/0017 , B29K2995/0053 , Y10S264/906 , Y10S264/908 , Y10S264/909 , Y10S428/91 , Y10T428/1352 , Y10T428/1397
摘要： A biaxially oriented polyethylene terephthalate resin bottle-shaped container, and method of blow-molding the same, is disclosed. The method comprises the steps of heating the body portion of a preform at 90.degree. to 130.degree. C., biaxial-orientation blow-molding the preform in a primary blowing mold heated at 110.degree. to 230.degree. C. to form a primary intermediate molded bottle-shaped piece, heating the primary intermediate molded bottle-shaped piece at 130.degree. to 255.degree. C. or at a temperature which is at least 20.degree. C. greater than the primary blowing mold temperature to form a secondary intermediate molded bottle-shaped piece, and blow-molding the secondary intermediate molded bottle-shaped piece in a secondary blowing mold heated at 100.degree. to 150.degree. C. to form a bottle-shaped container. The temperature of the secondary blowing mold is several degrees greater than the maximum temperature the molded bottle-shaped container will be subjected to during use. The bottle-shaped container of the present invention has no stress remaining from biaxial orientation blow-molding and has a high heat resistance temperature value.
摘要翻译：公开了一种双轴取向的聚对苯二甲酸乙二醇酯树脂瓶形容器及其吹塑方法。该方法包括以下步骤：将预成型体的主体部分加热到90℃至130℃，双轴取向吹塑成型预成型坯，在初始吹塑模具中加热至110℃至230℃，以形成初级中间成型瓶形件，将初级中间成型瓶形件在130℃至255℃或在比初始吹塑模具温度高至少20℃的温度下加热以形成二次中间成型瓶形将二次中间成型的瓶状件吹塑成加热至100-150℃的二次吹塑成型体，形成瓶状容器。二次吹塑模具的温度比成型瓶形容器在使用过程中经受的最高温度大几度。本发明的瓶状容器在双轴取向吹塑成型中没有应力残留，耐热温度高。

58. 发明授权

US5505612A Appartus for blow mold annealing and heat treating thermoplastic articles 失效
标题翻译： Appartus用于吹塑退火和热处理热塑性制品
公开(公告)号：US5505612A
公开(公告)日：1996-04-09
申请号：US373547
申请日：1995-01-17
申请人： Christopher Mero , John Cahill
发明人： Christopher Mero , John Cahill
IPC分类号： B29C35/02 , B29C35/16 , B29C49/06 , B29C49/18 , B29C49/48 , B29C49/64 , B29C49/66
CPC分类号： B29C49/6481 , B29C49/18 , B29C49/4823 , B29C49/66 , B29B11/08 , B29B11/14 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14106 , B29B2911/14113 , B29B2911/14133 , B29B2911/1414 , B29B2911/14326 , B29B2911/14333 , B29B2911/1444 , B29B2911/14606 , B29B2911/14633 , B29B2911/1464 , B29B2911/14753 , B29C2035/0211 , B29C2035/1616 , B29C2049/4843 , B29C49/06 , B29K2067/00 , B29K2995/0017 , B29K2995/0025 , B29K2995/004 , B29K2995/0041 , Y10S264/903
摘要： An apparatus for annealing and heat treating biaxially oriented articles is disclosed, particularly blow molded articles prepared from preforms which are simultaneously annealed using warm fluid in a first segmented mold. The blown article is transferred to a second, larger mold where the article is pressurized against the mold to form the final container design and to heat treat at least a portion of the bottle wall to improve crystallinity and strength. Portions of the mold, used to form and anneal the articles, are temperature controlled at various temperatures by passing warm water through conduits in the neck-shoulder portion and body portion of the mold and cold water through the bottom and shoulder portion of the mold to bring the temperature of the article wall to about 65.degree. C. to 95.degree. C. for PET bottles. The second mold is up to 10% larger in volume and preferably employs resistance heating to heat treat the side wall to 110.degree. C. to 220.degree. C. and the neck-shoulder wall to less than the side wall but within the 110.degree. C. to 220.degree. C. temperature range for up to 30 seconds. The article is next cooled by injecting an evaporatable fluid like water which evaporates and immediately cools the article which is then removed from the mold. The heat treatment increases the article's structural strength, does not affect biaxial crystallinity reduces gas permeability, retains transparency and allows for multiple reuse of the article including hot washing thereof.
摘要翻译：公开了一种用于退火和热处理双轴取向制品的设备，特别是由预成型件制备的吹塑制品，其在第一分段模具中使用温热流体同时退火。将吹塑制品转移到第二较大的模具中，其中制品被压靠在模具上以形成最终的容器设计，并且热处理瓶壁的至少一部分以改善结晶度和强度。用于形成和退火物品的模具的部分通过将温水通过模具的颈肩部分和主体部分中的导管以及通过模具的底部和肩部的冷水通过温水在各种温度下进行温度控制，使PET瓶的温度达到约65℃至95℃。第二个模具的体积可达10％，最好采用电阻加热来将侧壁热处理至110℃至220℃，颈肩部壁小于侧壁但在110℃ 至220℃的温度范围达30秒。然后通过注入可蒸发的流体如水蒸发并立即冷却制品然后将其从模具中取出而冷却制品。热处理增加了制品的结构强度，不影响双轴结晶度降低气体透过性，保持透明性并允许制品的多重再利用，包括其热洗涤。

59. 发明授权

US5445784A Method of blow-molding biaxially-oriented polyethylene terephthalate resin bottle-shaped container 失效
标题翻译：双轴取向聚对苯二甲酸乙二醇酯树脂瓶形容器吹塑方法
公开(公告)号：US5445784A
公开(公告)日：1995-08-29
申请号：US327894
申请日：1994-10-24
申请人： Horoaki Sugiura , Fuminori Tanaka , Daisuke Uesugi
发明人： Horoaki Sugiura , Fuminori Tanaka , Daisuke Uesugi
IPC分类号： B29C49/00 , B29C49/06 , B29C49/16 , B29C49/18 , B29C49/64 , B29C61/02
CPC分类号： B29C49/16 , B29C49/18 , B29C49/649 , B29C49/00 , B29C49/06 , B29C61/02 , B29K2067/00 , B29K2995/0017 , B29K2995/0053 , Y10S264/906
摘要： A biaxially oriented polyethylene terephthalate resin bottle-shaped container, and method of blow molding the same by heating the body portion of a preform at 90.degree. C. to 130.degree. C., biaxial-orientation blow-molding the preform in a primary blowing mold heated at 110.degree. C. to 230.degree. C. to form a primary intermediate molded bottle-shaped piece, heating the primary intermediate molded bottle-shaped piece at 130.degree. C. to 255.degree. C. or at a temperature which is 20.degree. C. or higher than the primary blowing mold temperature to form a secondary intermediate molded bottle-shaped piece, and blow-molding the secondary intermediate molded bottle-shaped piece in a secondary blowing mold heated at 100.degree. C. to 150.degree. C. to form a bottle-shaped container. The temperature of the secondary blowing mold is several degrees greater than the maximum temperature the molded bottle-shaped container will be subjected to during use. The bottle-shaped container has no stress remaining from biaxial orientation blow-molding and has a high heat resistance temperature value.
摘要翻译：双轴取向的聚对苯二甲酸乙二醇酯树脂瓶形容器，以及通过在90℃至130℃下加热预成型体的主体部分来吹塑成型方法，在一次吹塑模具中双轴取向吹塑预制件加热至110℃至230℃，形成初级中间成型瓶形件，将初级中间成型瓶形件加热至130℃至255℃或温度为20℃ 或高于初级吹塑模具温度，以形成二次中间成型瓶形件，并将二次中间成型的瓶形件吹塑到加热至100℃至150℃的二次吹塑模具中以形成一个瓶形容器。二次吹塑模具的温度比成型瓶形容器在使用过程中经受的最高温度大几度。瓶形容器从双轴取向吹塑成型中没有应力残留，并且具有高的耐热温度值。

60. 发明授权

US5344912A Elevated temperature dimensionally stable polyester with low gas permeability 失效
标题翻译：高温尺寸稳定的聚酯，透气性低
公开(公告)号：US5344912A
公开(公告)日：1994-09-06
申请号：US863204
申请日：1992-04-03
申请人： Edward J. Dalgewicz, III , Richard A. Freundlich
发明人： Edward J. Dalgewicz, III , Richard A. Freundlich
IPC分类号： B29C49/00 , B29C71/00 , B65D81/34 , C08G63/88 , C08L67/02 , C08L101/00 , C08G63/16
CPC分类号： B29C49/0005 , B65D81/34 , C08G63/88 , C08L67/02 , B29C71/0063 , B29K2067/00 , B29K2995/0017 , B29K2995/004 , B29K2995/0041 , B29K2995/0067 , B65D81/3453 , C08L101/00 , Y10T428/13 , Y10T428/1321 , Y10T428/1328 , Y10T428/1352 , Y10T428/1397 , Y10T428/31786
摘要： The invention provides a polyester having an oxygen permeability of from about 0.2 to about 4.9 cc-mil/100 in.sup.2 -24 hr-atm at a temperature of 23.degree. C. and at 00% relative humidity inside and 60% relative humidity outside, and an enthalpy of recrystallization of from about 0 to about -2.1 cal/g, as well as a linear dimensional shrinkage between about 0% and 6% when heated from about -60.degree. C. to about 200.degree. C. The invention also provides a process of manufacturing the above polyester, an article comprising this polyester and a process for making this article. The crystalline polyester article is useful as a container for microwavable, ovenable and/or frozen foods, and has good gas barrier properties, and post-mold dimensional stability from about -60.degree. C. to about 200.degree. C.
摘要翻译：本发明提供了一种在23℃的温度和在00％的相对湿度以及相对湿度为室外的情况下，透氧率为约0.2-约4.9cc-mil / 100-2-24小时的聚酯，以及约0至约-2.1cal / g的重结晶焓，以及当约-60℃至约200℃加热时约0％至6％的线性尺寸收缩率。本发明还提供了一种制造上述聚酯的方法，包含该聚酯的制品以及制备该制品的方法。结晶性聚酯制品可用作微波炉，可烘烤和/或冷冻食品的容器，并且具有良好的阻气性和约-60℃至约200℃的后模尺寸稳定性。

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