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51. 发明授权

US06906147B2 Catalytic systems 失效
标题翻译：催化系统
公开(公告)号：US06906147B2
公开(公告)日：2005-06-14
申请号：US10102162
申请日：2002-03-20
申请人： Yi-Feng Wang , Peter D. Phelps
发明人： Yi-Feng Wang , Peter D. Phelps
IPC分类号： B01J31/02 , B01J31/18 , B01J31/22 , C07F7/00 , C08G63/82 , C08G63/85 , C08G63/87 , C08F20/10
CPC分类号： B01J31/2239 , B01J31/0214 , B01J31/0228 , B01J31/223 , B01J31/2243 , B01J2231/14 , B01J2531/46 , C07F7/003 , C08G63/82 , C08G63/85 , C08G63/87 , Y10T428/31786
摘要： This invention relates to single-component and multi-component catalytic systems using aryl titanates. Aryl titanate compounds are useful as catalysts and co-catalysts in single-component and multi-component catalytic systems (e.g., for the polymerization of macrocyclic oligoesters and the depolymerization of polyesters). Multi-component catalytic systems using aryl titanates allow increased versatility in applications such as liquid molding.
摘要翻译：本发明涉及使用芳基钛酸盐的单组分和多组分催化体系。钛酸酯化合物可用作单组分和多组分催化体系中的催化剂和助催化剂（例如，用于大环低聚酯的聚合和聚酯的解聚）。使用芳基钛酸盐的多组分催化体系允许在诸如液体成型的应用中增加多功能性。

52. 发明授权

US06770588B2 Reduction of carbonyl compounds by a silane in the presence of a zinc catalyst 有权
标题翻译：在锌催化剂存在下通过硅烷还原羰基化合物
公开(公告)号：US06770588B2
公开(公告)日：2004-08-03
申请号：US10345285
申请日：2003-01-16
申请人： Hubert Mimoun
发明人： Hubert Mimoun
IPC分类号： B01J3100
CPC分类号： B01J31/2226 , B01J31/1805 , B01J31/181 , B01J31/1815 , B01J31/2234 , B01J31/2239 , B01J31/2243 , B01J2231/64 , B01J2531/0216 , B01J2531/26 , C07C29/14 , C07C29/143 , C07C29/147 , C07C403/02 , C07C403/08 , C07C2601/10 , C07C2601/16 , C07C2602/28 , C07C33/22 , C07C33/025 , C07C33/14 , C07C33/20 , C07C33/16 , C07C35/36 , C07C33/02 , C07C33/12 , C07C35/08 , C07C31/125
摘要： A reductive system including a silane, preferably PMHS, and an active zinc compound, which is monomeric and not a hydride, wherein a reduction of a carbonyl substrate to a corresponding alcohol is achievable.
摘要翻译：包括硅烷，优选PMHS和活性锌化合物的还原体系，其为单体且不是氢化物，其中羰基底物还原成相应的醇是可实现的。

53. 发明申请

US20040010103A1 Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom 有权
公开(公告)号：US20040010103A1
公开(公告)日：2004-01-15
申请号：US10421235
申请日：2003-04-23
申请人： Symyx Technologies, Inc.
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A.W. Shoemaker
IPC分类号： C08F004/44
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands, compositions, metal-ligand complexes and arrays with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

54. 发明授权

US06677490B2 Method for producing alcohol/ketone mixtures 失效
标题翻译：生产醇/酮混合物的方法
公开(公告)号：US06677490B2
公开(公告)日：2004-01-13
申请号：US10149650
申请日：2002-10-15
申请人： James Clark , Eric Fache , Ducan Macquarrie , Peter Price , John Rafelt
发明人： James Clark , Eric Fache , Ducan Macquarrie , Peter Price , John Rafelt
IPC分类号： C07C4541
CPC分类号： C07C409/14 , B01J31/1633 , B01J31/2243 , B01J2531/16 , B01J2531/62 , C07C29/132 , C07C45/53 , C07C407/00 , C07C2601/14 , Y02P20/588 , C07C49/403 , C07C35/08
摘要： The invention relates to a method for producing a mixture of alcohols/ketones by decomposing an alkyl hydroperoxide, particularly to a method for producing a cyclohexanol/cyclohexanone by decomposing cyclohexyl hydroperoxide in the presence of a heterogeneous catalyst. According to the invention, the reaction is carried out in the presence of a heterogeneous catalyst containing an organometallic segment fixed on the surface of a porous solid compound such as silicon. The organometallic segment can be formula (I).
摘要翻译：本发明涉及通过分解烷基氢过氧化物来生产醇/酮的混合物的方法，特别是通过在多相催化剂存在下分解环己基氢过氧化物制备环己醇/环己酮的方法。根据本发明，反应在含有固定在多孔固体化合物如硅的表面上的有机金属链段的多相催化剂存在下进行。有机金属片段可以是式（I）。

55. 发明申请

US20040005984A1 Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom 有权
标题翻译：桥联双芳族配体，催化剂，聚合方法和聚合物
公开(公告)号：US20040005984A1
公开(公告)日：2004-01-08
申请号：US10421219
申请日：2003-04-23
申请人： Symyx Technologies, Inc.
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margaret K. Leclerc , James A.W. Shoemaker
IPC分类号： B01J031/00
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands, compositions, metal-ligand complexes and arrays with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
摘要翻译：公开了新配体，组合物，金属 - 配体络合物和具有桥连双芳族配体的阵列，其催化单体聚合成聚合物。这些具有金属中心的催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，丙烯或苯乙烯。催化剂还将丙烯聚合成全同立构聚丙烯。

56. 发明申请

US20030224929A1 Spray-drying catalyst compositions and methods of spray-drying 失效
标题翻译：喷雾干燥催化剂组合物和喷雾干燥方法
公开(公告)号：US20030224929A1
公开(公告)日：2003-12-04
申请号：US10362204
申请日：2003-02-21
发明人： Jessica A Cook
IPC分类号： B01J031/00
CPC分类号： B01J31/2243 , B01J21/12 , B01J31/0274 , B01J31/14 , B01J31/143 , B01J31/1616 , B01J31/1805 , B01J31/1815 , B01J31/189 , B01J31/226 , B01J31/24 , B01J37/0045 , B01J2531/0205 , B01J2531/0216 , B01J2531/0244 , B01J2531/0255 , B01J2531/48 , B01J2531/847 , C08F4/659 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F2410/03 , Y02P20/588 , C08F210/14 , C08F4/64044 , C08F4/7042 , C08F4/7006 , C08F4/7022 , C08F4/7004 , C08F4/7021 , C08F4/7019 , C08F4/7026
摘要： A spray drying process for preparing a solid catalyst and composition for use therein comprising a catalyst compound, an activator for the catalyst compound, and at least one compound selected from among siloxanes, polyalkylene glycols, C1-4 alkyl or phenyl ether or diether derivatives of polyalkylene glycols, and crown ethers, and optionally a filler or support.
摘要翻译：一种用于制备固体催化剂和用于其中的组合物的喷雾干燥方法，包括催化剂化合物，催化剂化合物的活化剂和至少一种选自硅氧烷，聚亚烷基二醇，C 1-4烷基或苯基醚或二醚衍生物的化合物聚亚烷基二醇和冠醚，以及任选的填料或载体。

57. 发明授权

US06602817B1 Combination approach to chiral reagents or catalysts having amine or amino alcohol ligands 有权
标题翻译：具有胺或氨基醇配体的手性试剂或催化剂的组合方法
公开(公告)号：US06602817B1
公开(公告)日：2003-08-05
申请号：US09425498
申请日：1999-10-22
申请人： Nicos A. Petasis
发明人： Nicos A. Petasis
IPC分类号： B01J3100
CPC分类号： B01J31/2243 , B01J31/1805 , B01J31/223 , B01J2219/00738 , B01J2219/00745 , B01J2219/00747 , B01J2531/10 , B01J2531/20 , B01J2531/30 , B01J2531/40 , B01J2531/82 , B01J2531/84 , C07B53/00 , C07B2200/07 , C07C215/28 , C07C215/30 , C07C215/50 , C07C229/36 , C07D307/52 , C07K5/06026 , C40B30/08 , C40B40/18
摘要： Functionalized amine derivatives are prepared by reacting an amine, a carbonyl derivative, and an organoboron compound under mild conditions. Organoboronic acids react with amines and alpha-hydroxy aldehydes to give anti-alpha-amino alcohols with very high diastereoselectivities (>99% de). When optically pure alpha-hydroxy aldehydes are used in this process, no racemization occurs and the products are obtained with very high enantioselectivities (>99% ee). The reaction also works with unprotected glyceraldehyde to give the corresponding amino diol derivatives, while unprotected carbohydrates give the corresponding amino polyols. The chiral amino alcohol products of this process or their derivatives, react further with metals or non-metals to give adducts that are effective catalysts for a variety of asymmetric reactions. Overall, the present invention relies on the facile synthesis of the chiral amino alcohol ligands for the rapid construction of combinatorial libraries of chiral catalysts. These libraries can then be used to identify the most suitable catalyst for a particular asymmetric transformation.
摘要翻译：官能化胺衍生物通过在温和条件下使胺，羰基衍生物和有机硼化合物反应来制备。有机硼酸与胺和α-羟基醛反应得到具有非常高的非对映选择性（> 99％de）的抗α-氨基醇。当在该方法中使用光学纯的α-羟基醛时，不会发生外消旋化，并且以非常高的对映选择性（> 99％ee）获得产物。该反应也适用于未保护的甘油醛，得到相应的氨基二醇衍生物，而未保护的碳水化合物则得到相应的氨基多元醇。该方法的手性氨基醇产物或其衍生物进一步与金属或非金属反应，得到作为各种不对称反应的有效催化剂的加合物。总之，本发明依赖于手性氨基醇配体的容易合成，用于快速构建手性催化剂组合文库。然后可以使用这些文库来识别用于特定不对称转化的最合适的催化剂。

58. 发明申请

US20030144554A1 Catalytic preparation of aryl methyl ketones using a molecular oxygen-containing gas as the oxidant 失效
标题翻译：使用含分子氧的气体作为氧化剂催化制备芳基甲基酮
公开(公告)号：US20030144554A1
公开(公告)日：2003-07-31
申请号：US10055016
申请日：2002-01-25
申请人： The Hong Kong Polytechnic University
发明人： Albert Sun-Chi Chan , Jian-Ying Qi , Cheng-Chao Pai , Xian-Jun Li , Li-Sheng Deng , Wen-Zao Li , Bin Sun , Jia-Yuan Hu
IPC分类号： C07F015/00 , C07C045/27 , C07F001/08
CPC分类号： B01J31/181 , B01J31/2243 , B01J2531/16 , B01J2531/72 , B01J2531/821 , B01J2531/845 , B01J2531/847 , C07C45/36 , C07F13/005 , C07F15/0053 , C07F15/045 , C07C49/78 , C07C49/807 , C07C49/76
摘要： A method for the preparation of aryl methyl ketones converts a variety of ethyl arenas to the corresponding aryl methyl ketones using a dioxygen-containing gas as the oxidant. The catalyst used for the reaction is a metal complex bearing general formulas as disclosed.
摘要翻译：芳基甲基酮的制备方法使用含二氧化碳的气体作为氧化剂，将各种乙基化合物转化为相应的芳基甲基酮。用于反应的催化剂是带有所公开的通式的金属络合物。

59. 发明申请

US20030105250A1 Olefin oligomerization catalysts, their production and use 审中-公开
公开(公告)号：US20030105250A1
公开(公告)日：2003-06-05
申请号：US10300110
申请日：2002-11-19
发明人： Gregory T. Whiteker
IPC分类号： C08F004/06 , C08F004/44 , C08F004/72
CPC分类号： B01J31/146 , B01J21/06 , B01J21/063 , B01J21/066 , B01J31/143 , B01J31/2243 , B01J31/2295 , B01J2231/20 , B01J2531/48 , C07C2/32 , C07C2521/04 , C07C2531/14 , C07C2531/22 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F4/659 , C08F2500/02 , C08F2500/23
摘要： This invention relates to a method to oligomerize ethylene comprising combining ethylene with a catalyst system comprising an activator and one or more phenoxide group metal compounds represented by the formula: 1 wherein R3, R4, R5, R8, R9 and R10 may each independently be hydrogen, a halogen, a heteroatom containing group or a C1 to C100 group, provided that at least one of these groups has a Hammett nullp value (Hansch, et al Chem. Rev. 1991, 91, 165) greater than 0.20; R2 and R7 may each independently be alkyl, aryl or silyl groups; R1 and R6 may each independently be an alkyl group, an aryl group, an alkoxy group, or an amino group; N is nitrogen; H is hydrogen; O is oxygen; M is a group 4 transition metal; and each X may each independently be an anionic ligand or a dianionic ligand.

60. 发明授权

US06462239B2 Oxidation catalyst and oxidation process using the same 失效
标题翻译：氧化催化剂和氧化过程使用相同
公开(公告)号：US06462239B2
公开(公告)日：2002-10-08
申请号：US09832104
申请日：2001-04-11
申请人： Ikuo Takahashi , Hikaru Shibata
发明人： Ikuo Takahashi , Hikaru Shibata
IPC分类号： C07C4527
CPC分类号： B01J31/2243 , B01J2231/70 , B01J2531/0252 , B01J2531/72 , C07C45/34 , C07C49/603
摘要： In the presence of (1) an oxidation catalyst comprising a crystalline complex of manganese with an N,N′-disalicylidenediamine (e.g. N,N′-disalicylidene C2-8 alkylenediamines and N,N′-disalicylidene C6-12 arylenediamines), or (2) an oxidation catalyst comprising the above complex and a basic nitrogen-containing compound, a substrate (e.g., &bgr;-isophorone or a derivative thereof) is oxidized with molecular oxygen to produce a corresponding oxide (e.g., ketoisophorone). Ketoisophorone can be obtained from &bgr;-isophorone with high conversion and high selectivity.
摘要翻译：在（1）包含锰与N，N'-二水杨酸二亚胺（例如N，N'-二亚癸基C 2-8亚烷基二胺和N，N'-二亚苄基C 6-12亚芳基二胺）的结晶配合物的氧化催化剂的存在下，或（2）包含上述络合物和碱性含氮化合物的氧化催化剂，底物（例如，β-异佛尔酮或其衍生物）用分子氧氧化以产生相应的氧化物（例如酮异佛尔酮）。酮异佛尔酮可以从高转化率和高选择性的β-异佛尔酮获得。

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