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51. 发明授权

US07507854B2 Impurity reduction in Olefin metathesis reactions 失效
标题翻译：烯烃复分解反应的杂质减少
公开(公告)号：US07507854B2
公开(公告)日：2009-03-24
申请号：US10924743
申请日：2004-08-23
申请人： Choon Woo Lee , Soon Hyeok Hong , Daniel P. Sanders , Robert H. Grubbs , Richard L. Pederson
发明人： Choon Woo Lee , Soon Hyeok Hong , Daniel P. Sanders , Robert H. Grubbs , Richard L. Pederson
IPC分类号： C07C69/52
CPC分类号： C07D303/04 , C07C6/04 , C07C67/293 , C07C2531/24 , C07D207/20 , C07C69/007 , C07C69/145 , C07C69/533
摘要： The present invention relates to the use of isomerization inhibitors in olefin metathesis reactions. The inhibitors are low molecular weight organic acids such as formic acid, acetic acid, benzoic acid, and the like.
摘要翻译：本发明涉及异构化抑制剂在烯烃复分解反应中的用途。抑制剂是低分子量有机酸，例如甲酸，乙酸，苯甲酸等。

52. 发明授权

US07268242B2 Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts 有权
标题翻译：螯合卡宾配体前体及其在复分解催化剂合成中的应用
公开(公告)号：US07268242B2
公开(公告)日：2007-09-11
申请号：US11344637
申请日：2006-01-31
申请人： Richard L. Pederson , Jason K. Woertink , Christopher M. Haar , David E. Gindelberger , Yann Schrodi
发明人： Richard L. Pederson , Jason K. Woertink , Christopher M. Haar , David E. Gindelberger , Yann Schrodi
IPC分类号： C07F15/00 , C07F9/02 , C07C39/00
CPC分类号： B01J31/2414 , B01J31/1805 , B01J31/2204 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J2231/50 , B01J2231/54 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046
摘要： Chelating ligand precursors for the preparation of olefin metathesis catalysts are disclosed. The resulting catalysts are air stable monomeric species capable of promoting various metathesis reactions efficiently, which can be recovered from the reaction mixture and reused. Internal olefin compounds, specifically beta-substituted styrenes, are used as ligand precursors. Compared to terminal olefin compounds such as unsubstituted styrenes, the beta-substituted styrenes are easier and less costly to prepare, and more stable since they are less prone to spontaneous polymerization. Methods of preparing chelating-carbene metathesis catalysts without the use of CuCl are disclosed. This eliminates the need for CuCl by replacing it with organic acids, mineral acids, mild oxidants or even water, resulting in high yields of Hoveyda-type metathesis catalysts. The invention provides an efficient method for preparing chelating-carbene metathesis catalysts by reacting a suitable ruthenium complex in high concentrations of the ligand precursors followed by crystallization from an organic solvent.
摘要翻译：公开了用于制备烯烃复分解催化剂的螯合配体前体。所得催化剂是能够有效促进各种复分解反应的空气稳定的单体物质，其可以从反应混合物中回收并重复使用。使用内部烯烃化合物，特别是β-取代的苯乙烯作为配体前体。与末端烯烃化合物如未取代的苯乙烯相比，β-取代的苯乙烯更容易制备成本更低，更稳定，因为它们不易于自发聚合。公开了不使用CuCl制备螯合 - 碳烯复分解催化剂的方法。这通过用有机酸，无机酸，温和氧化剂甚至水代替它来消除对CuCl的需要，导致Hoveyda型复分解催化剂的高产率。本发明提供了一种制备螯合碳烯复分解催化剂的有效方法，该方法是通过在高浓度配体前体中合适的钌络合物，然后从有机溶剂中结晶而制备。

53. 发明授权

US10711090B2 Thermal insulation 有权
公开(公告)号：US10711090B2
公开(公告)日：2020-07-14
申请号：US15122860
申请日：2014-12-23
申请人： MATERIA, INC.
发明人： Christopher J. Cruce , Michael A. Giardello , Brian L. Conley , Anthony R. Stephen
IPC分类号： C08G61/02 , F16L59/20 , C08G61/08 , C08L65/00 , F16L58/10 , C09D165/00 , B05D7/22 , F16L59/14 , F16L59/02 , F16L58/18
摘要： The present invention is directed to addressing one or more of the aforementioned concerns and relates to thermal insulation materials and thermal insulation material compositions and methods for thermally insulating pipelines and associated equipment, structures, and objects used in offshore drilling. The present invention is directed to articles of manufacture comprising the thermal insulation materials and/or thermal insulation material compositions of the invention. More particularly the present invention relates to the use of ring opening metathesis polymerization polymers (ROMP polymers) and/or ROMP polymer composites for thermally insulating pipelines and associated equipment, structures, and objects used in offshore oil drilling.

54. 发明授权

US10633484B2 Method and composition for improving adhesion of metathesis compositions to substrates 有权
公开(公告)号：US10633484B2
公开(公告)日：2020-04-28
申请号：US15109703
申请日：2015-01-12
申请人： MATERIA, INC.
发明人： Anthony R. Stephen , Christopher J. Cruce , Mark S. Trimmer , Michael A. Giardello
IPC分类号： C08G61/02 , C03C25/30 , C03C17/32 , C08J5/04 , C08K5/14 , C08K5/5419 , C08L65/00 , C08K3/36 , C08K7/14 , C08K7/28 , C08K3/40 , C08K5/5425 , C08G61/08 , B29B15/12 , C09D165/00 , B29K309/08
CPC分类号： C08G61/02 , B29B15/122 , C03C17/328 , C03C25/30 , C08G61/08 , C08J5/043 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00 , B29K2309/08 , C08G2261/3325 , C08G2261/964 , C08J2323/20 , C08L65/00 , C08K5/5419 , C08K5/14 , C08L65/00 , C08K5/5425 , C08K5/14 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K3/36 , C08K3/40 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K3/40 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K7/14 , C08L65/00 , C08K5/5425 , C08K5/14 , C08K3/36 , C08K7/28
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter.

55. 发明授权

US10059857B2 Method and composition for improving adhesion of metathesis compositions to substrates 有权
公开(公告)号：US10059857B2
公开(公告)日：2018-08-28
申请号：US15413703
申请日：2017-01-24
申请人： MATERIA, INC.
发明人： Anthony R. Stephen , Christopher J. Cruce , Mark S. Trimmer , Michael A. Giardello
IPC分类号： C09D145/00 , C09D143/00
CPC分类号： C09D143/00 , C09D143/04
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

56. 发明申请

US20180237581A1 METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-公开
公开(公告)号：US20180237581A1
公开(公告)日：2018-08-23
申请号：US15955876
申请日：2018-04-18
申请人： MATERIA, INC.
发明人： Anthony R. STEPHEN , Christopher J. CRUCE , Mark S. TRIMMER , Michael A. GIARDELLO
IPC分类号： C08G61/02 , C03C17/32 , C09D165/00 , B29B15/12
CPC分类号： C08G61/02 , B29B15/122 , B29K2309/08 , C03C17/328 , C03C25/30 , C08G61/08 , C08G2261/3325 , C08G2261/964 , C08J5/043 , C08J2323/20 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

57. 发明授权

US09758445B2 Preparation of surfactants via cross-metathesis 有权
公开(公告)号：US09758445B2
公开(公告)日：2017-09-12
申请号：US14877632
申请日：2015-10-07
申请人： MATERIA, INC.
发明人： Adam M. Johns , Richard L. Pederson , Rosemary Conrad Kiser
IPC分类号： C07C309/00 , C07C5/03 , C07C43/178 , C07D309/12 , C07C2/74 , C07C6/04 , C07C67/11 , C07C33/20 , C07C41/16 , C07C41/26 , C07C43/164 , C07C29/09 , C11D1/72
CPC分类号： C07C5/03 , C07C2/74 , C07C6/04 , C07C29/095 , C07C33/20 , C07C41/16 , C07C41/26 , C07C43/164 , C07C43/1782 , C07C67/11 , C07C2521/18 , C07C2523/44 , C07C2531/24 , C07D309/12 , C11D1/72 , C11D1/721 , C07C69/157 , C07C15/44 , C07C11/02 , C07C11/113 , C07C15/107
摘要： The present invention relates to compositions comprising alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; methods for making alkene benzenes or alkene benzene sulfonates or alkylbenzenes or alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. More particularly, the present invention relates to compositions comprising 2-phenyl linear alkene benzenes or 2-phenyl linear alkene benzene sulfonates or 2-phenyl linear alkylbenzenes or 2-phenyl linear alkylbenzene sulfonates; methods for making 2-phenyl alkene benzenes or 2-phenyl alkene benzene sulfonates or 2-phenyl alkylbenzenes or 2-phenyl alkylbenzene sulfonates; where the benzene ring is optionally substituted with one or more groups designated R*, where R* is defined herein. This invention also relates to compositions, methods of making, use of, and articles of manufacture comprising 2-ethoxylated hydroxymethylphenyl linear alkyl benzenes. This invention also relates to compositions, methods of making, use of, and articles of manufacture comprising 2-propoxylated hydroxymethylphenyl linear alkyl benzenes.

58. 发明授权

US09527982B2 Storage stable adhesion promoter compositions for cyclic olefin resin compositions 有权
标题翻译：用于环烯烃树脂组合物的储存稳定的助粘剂组合物
公开(公告)号：US09527982B2
公开(公告)日：2016-12-27
申请号：US14133793
申请日：2013-12-19
申请人： MATERIA, INC.
发明人： Christopher J. Cruce , Brian Edgecombe , Paul W. Boothe , Michael A. Giardello
IPC分类号： C08G61/06 , C08K5/29 , C08L75/04 , C08G61/08
CPC分类号： C08K5/29 , C08G61/06 , C08G61/08 , C08G2261/418 , C08G2261/76 , C08L75/04
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials. More particularly, the invention relates to compositions and methods for improving the adhesion of ROMP compositions to substrate materials using an adhesion promoter composition, where the adhesion promoter composition comprises a pre-reacted mixture comprising at least one compound containing at least two isocyanate groups and at least one compound comprising a heteroatom-containing functional group and a metathesis active olefin, where the adhesion promoter composition possesses in-resin storage stability when added to a resin composition, particularly a cyclic olefin resin composition, such as a ROMP composition. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.
摘要翻译：本发明涉及用于改善树脂组合物与基材的粘合性的组合物和方法。更具体地说，本发明涉及使用粘合促进剂组合物改进ROMP组合物与基材的粘合性的组合物和方法，其中粘合促进剂组合物包含预反应的混合物，其包含至少一种含有至少两个异氰酸酯基团的化合物和至少一种包含含杂原子的官能团和易位活性烯烃的化合物，其中当加入到树脂组合物中时，粘合促进剂组合物具有树脂存储稳定性，特别是环状烯烃树脂组合物，例如ROMP组合物。通过本发明的ROMP反应生产的聚合物产品可用于广泛的材料和复合材料应用。本发明在聚合物和材料化学和制造领域具有实用性。

59. 发明授权

US09452568B2 VARTM flow modifications for low viscosity resin systems 有权
标题翻译：用于低粘度树脂体系的VARTM流动修饰
公开(公告)号：US09452568B2
公开(公告)日：2016-09-27
申请号：US13818271
申请日：2011-08-23
申请人： Sergio Corral , Stephen Crane , Anthony R. Stephen , Christopher J. Cruce , Everardo Garcia Flores
发明人： Sergio Corral , Stephen Crane , Anthony R. Stephen , Christopher J. Cruce , Everardo Garcia Flores
IPC分类号： B29C70/44 , B29C70/02 , B29C70/54
CPC分类号： B29C70/021 , B29C70/443 , B29C70/546 , Y10T428/31924
摘要： A vacuum-assisted resin transfer molding (VARTM) method is disclosed, the method comprising: providing a vacuum-assisted resin transfer mold assembly comprising a mold having a first mold surface and a second mold surface arranged to enclose a laminate assembly within a space between the first and second mold surfaces when the laminate assembly is placed on the first mold surface; providing a laminate assembly comprising a laminate pre-form, a peel ply, and a resin distribution media pervious to the flow of a resin, the laminate pre-form having first and second surfaces, the first surface of the pre-form positioned to be in contact with the first mold surface, the peel ply positioned such that the second surface of the laminate pre-form is in contact with the peel ply, and the resin distribution media positioned to be contained within the first and second mold surfaces; positioning at least one resin flow control structure to modify the flow of resin within the resin distribution media; providing at least one inlet and at least one outlet in the laminate assembly such that the resin can be introduced into the assembly through the inlet; arranging and sealing the second mold surface to enclose the laminate assembly within the space between the first and second mold surfaces such that a vacuum can be pulled on the laminate assembly contained within the space between the first and second mold surfaces; applying a vacuum to the mold assembly; allowing the resin to flow into the laminate assembly through the at least one inlet such that the resin flow into the resin distribution media; allowing the resin to flow out of the laminate assembly through the at least one outlet; and allowing the resin to cure in the laminate material. An article of manufacture made by said VARTM method.
摘要翻译：公开了一种真空辅助树脂传递模塑（VARTM）方法，该方法包括：提供一种真空辅助树脂转移模具组件，其包括具有第一模具表面和第二模具表面的模具，该模具布置成将层压组件包围在当层压组件放置在第一模具表面上时的第一和第二模具表面; 提供层压组件，其包括层压预成型件，剥离层和可透过树脂流动的树脂分配介质，所述层压预成型件具有第一和第二表面，预成型件的第一表面定位成与第一模具表面接触，剥离层定位成使得层压预成型件的第二表面与剥离层接触，并且树脂分配介质定位成容纳在第一和第二模具表面内; 定位至少一个树脂流量控制结构以改变树脂分布介质内的树脂流动; 在所述层叠组件中提供至少一个入口和至少一个出口，使得所述树脂可以通过所述入口被引入到所述组件中; 布置和密封第二模具表面以将层压体组件包围在第一和第二模具表面之间的空间内，使得可以在包含在第一和第二模具表面之间的空间内的层压组件上拉动真空; 向模具组件施加真空; 允许树脂通过至少一个入口流入层压组件，使得树脂流入树脂分布介质; 允许树脂通过至少一个出口流出层压组件; 并使树脂在层压材料中固化。由VARTM方法制造的制品。

60. 发明申请

US20160185689A1 SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES AND ETHYLENE VIA OLEFIN METATHESIS 审中-公开
公开(公告)号：US20160185689A1
公开(公告)日：2016-06-30
申请号：US14985653
申请日：2015-12-31
申请人： MATERIA, INC.
发明人： Yann Schrodi
IPC分类号： C07C6/04 , B01J31/12 , C07C67/333
CPC分类号： C07C6/04 , B01J31/12 , B01J31/2265 , B01J2231/543 , B01J2531/821 , C07C67/333 , C07C2531/18 , C07C2531/22 , C07C2531/24 , C07C2531/28 , C07F15/0046 , C07C11/02 , C07C69/533
摘要： This invention relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by a selected olefin metathesis catalyst. In one embodiment of the invention, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting an olefinic substrate comprised of at least one internal olefin with ethylene, in the presence of a metathesis catalyst, wherein the catalyst is present in an amount that is less than about 1000 ppm relative to the olefinic substrate, and wherein the metathesis catalyst has the structure of formula (II) wherein the various substituents are as defined herein. The invention has utility, for example, in the fields of catalysis, organic synthesis, and industrial chemistry.

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