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51. 发明授权

US08563675B2 Curable compositions composed of silanes with two hydrolyzable groups 有权
标题翻译：由具有两个可水解基团的硅烷组成的可固化组合物
公开(公告)号：US08563675B2
公开(公告)日：2013-10-22
申请号：US12701959
申请日：2010-02-08
申请人： Lars Zander , Thomas Bachon , Christiane Kunze , Johann Klein , Daniela Braun , Sara Gonzalez , Ulrich Neuhausen
发明人： Lars Zander , Thomas Bachon , Christiane Kunze , Johann Klein , Daniela Braun , Sara Gonzalez , Ulrich Neuhausen
IPC分类号： C08G77/46 , C08F283/06
CPC分类号： C08G65/30 , C08G65/33344 , C08G65/33351 , C08G65/336
摘要： The present invention relates to silane-crosslinking curable compositions encompassing a polymer P having at least two terminal groups of the following formulas (I) and (II) -Am-K1—SiR1XY (I), -Am-K2—SiR2XY (II), and/or two polymers P1 and P2, polymer P1 having terminal groups of the following formula (I) -Am-K1—SiR1XY (I), and polymer P2 having terminal groups of the following formula (II) -Am-K2—SiR2XY (II), in which A denotes a divalent bonding group, K1, K2, mutually independently, denote a divalent aliphatic hydrocarbon group that has a main chain of 1 to 6 carbon atoms, the hydrocarbon groups K1, K2 being different, X, Y mutually independently denote a hydroxy group or a hydrolyzable group, R1, R2 mutually independently denote a hydrocarbon residue having 1 to 20 carbon atoms, and m assumes the values 0 or 1.
摘要翻译：本发明涉及包含具有下式（I）和（II）-Am-K1-SiR1XY（I），-Am-K2-SiR2XY（Ⅱ）的至少两个末端的聚合物P的硅烷交联固化性组合物，，和/或两种聚合物P1和P2，具有下式（I）-Am-K1-SiR1XY（I）的末端的聚合物P1和具有下式（II）的末端的聚合物P2-A-K2- 其中A表示二价键合基团的SiR2XY（II），K1，K2彼此独立地表示具有1-6个碳原子的主链，烃基K1，K2不同的二价脂族烃基，X， Y相互独立地表示羟基或可水解基团，R 1，R 2相互独立地表示碳原子数1〜20的烃残基，m表示0或1。

52. 发明申请

US20130085239A1 POLYETHER BLOCK COPOLYMERS AND COMPOSITIONS THAT CAN BE OBTAINED THEREFROM 有权
标题翻译：聚合物嵌段共聚物和可以从其获得的组合物
公开(公告)号：US20130085239A1
公开(公告)日：2013-04-04
申请号：US13560149
申请日：2012-07-27
申请人： Lars Zander , Uwe Franken , Christiane Kunze , Michael Krebs , Johann Klein
发明人： Lars Zander , Uwe Franken , Christiane Kunze , Michael Krebs , Johann Klein
IPC分类号： C08G63/91
CPC分类号： C08G63/916 , C08G65/20 , C08G65/2663 , C08G2650/24 , C09D171/02 , C09J171/02
摘要： Polyether block copolymers of the general structure B-(A-OH)n are described, where n is greater than or equal to 2 and blocks A are made up of polyoxypropylene units and the central block B of polyoxytetramethylene, polyoxyethylene, polybutadiene, polyisoprene, polyacrylate, polymethacrylate, polyamide, polyurethane, or polyester units. These polyether block copolymers are suitable for the manufacture of compositions that serve as the basis for preparations for use as a one-component moisture-hardening or two-component adhesive or sealant, for assembly bonding, for areal bonding, and/or for coating, as a reactive melt adhesive or as a laminating adhesive.
摘要翻译：其中n为大于或等于2的聚醚嵌段共聚物，其中A为聚氧丙烯单元，聚氧四亚甲基，聚氧乙烯，聚丁二烯，聚异戊二烯，聚丙烯酸酯，聚甲基丙烯酸酯，聚酰胺，聚氨酯或聚酯单元。这些聚醚嵌段共聚物适用于制造用作单组分湿固化或双组分粘合剂或密封剂，用于组装粘合，用于面接合和/或涂覆的制剂的基础的组合物，作为反应性熔融粘合剂或作为层压粘合剂。

53. 发明申请

US20120067249A1 MOISTURE CURABLE POLYDISULFIDES 审中-公开
标题翻译：水分可固化聚氨酯
公开(公告)号：US20120067249A1
公开(公告)日：2012-03-22
申请号：US13285187
申请日：2011-10-31
申请人： John G. Woods , Anthony F. Jacobine , Johann Klein , Kathrin Isenbuegel
发明人： John G. Woods , Anthony F. Jacobine , Johann Klein , Kathrin Isenbuegel
IPC分类号： C09J9/00 , C07F7/18
CPC分类号： C08G75/14 , C07F7/1804 , C08L81/04 , C09K3/1012 , C08L81/00
摘要： Provided are polydisulfides that are useful in moisture curable sealants. The polydisulfides have an S—S link in the backbone and are end-capped with at least one alkoxysilane functional group. Also provided are methods of making the polydisulfides, including methods that do not require the presence of a catalyst.
摘要翻译：提供可用于湿固化密封剂的多硫化物。多硫化物在主链中具有S-S连接并且被至少一个烷氧基硅烷官能团封端。还提供了制备多硫化物的方法，包括不需要催化剂存在的方法。

54. 发明授权

US08076444B2 Curable compositions consisting of silanes with three hydrolysable groups 有权
标题翻译：由具有三个可水解基团的硅烷组成的可固化组合物
公开(公告)号：US08076444B2
公开(公告)日：2011-12-13
申请号：US12732233
申请日：2010-03-26
申请人： Ulrich Neuhausen , Daniela Braun , Johann Klein , Christiane Kunze , Sara Gonzalez , Lars Zander , Thomas Bachon
发明人： Ulrich Neuhausen , Daniela Braun , Johann Klein , Christiane Kunze , Sara Gonzalez , Lars Zander , Thomas Bachon
IPC分类号： C08G77/04
CPC分类号： C08G65/30 , C08G65/33351 , C08G65/336 , C09D171/02 , C09K3/10 , C09K2200/0657
摘要： The invention relates to silane cross-linking curable compositions, comprising a polymer P with at least two terminal groups of the following formulae (I) and (II) -Am-K1—SiXYZ (I), -Am-K2—SiXYZ (II), and/or two polymers P1 and P2, the polymer P1 having terminal groups of the following formula (I) -Am-K1—SiXYZ (I), and the polymer P2 having terminal groups of the following formula (II) -Am-K2—SiXYZ (II). In said formulae, A represents a bivalent binding group K1 and K2 independently of one another represent a bivalent aliphatic hydrocarbon group with a main chain of between 1 and 6 carbon atoms, the hydrocarbon groups K1, K2 being different, X, Y and Z independently of one another represent a hydroxy group of a hydrolysable group and m stands for 0 or 1.
摘要翻译：本发明涉及硅烷交联可固化组合物，其包含具有至少两个下式（I）和（II）的末端的聚合物P：-Am-K1-SiXYZ（I），-Am-K2-SiXYZ（II ）和/或两种聚合物P1和P2，具有下式（I）-Am-K1-SiXYZ（I）的端基的聚合物P1和具有下式（II）的端基的聚合物P2-Am -K2-SiXYZ（II）。在所述式中，A表示二价结合基团K1和K2彼此独立地表示主链为1-6个碳原子的二价脂族烃基，烃基K1，K2独立地为X，Y和Z独立地彼此表示可水解基团的羟基，m表示0或1。

55. 发明申请

US20110282007A1 METHOD FOR PRODUCING ABA-TRIBLOCK COPOLYMERS WITH A WIDELY DISTRIBUTED B-BLOCK 有权
标题翻译：生产具有宽带分布B块的ABA-TRIBLOCK共聚物的方法
公开(公告)号：US20110282007A1
公开(公告)日：2011-11-17
申请号：US13128777
申请日：2009-10-06
申请人： Sven Balk , Holger Kautz , Stephan Fengler , Monika Maerz , Christine Troemer , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
发明人： Sven Balk , Holger Kautz , Stephan Fengler , Monika Maerz , Christine Troemer , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
IPC分类号： C08F297/00
CPC分类号： C08F2/001 , C08F2/06 , C08F2/38 , C08F6/02 , C08F8/26 , C08F8/34 , C08F293/005 , C08F2438/01 , C08L53/00 , C08L2666/02 , C09D153/00 , C09J153/00
摘要： The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks having a narrow, monomodal molecular weight distribution, and a B-block having a wide, monomodal molecular weight distribution. The invention further relates to the use thereof as binders in glues or sealing compounds.
摘要翻译：本发明涉及一种基于（甲基）丙烯酸酯与具有窄单分子量分布的A嵌段和具有宽单分子量分布的B嵌段生产ABA-三嵌段共聚物的受控聚合方法。本发明还涉及其作为胶水或密封化合物中的粘合剂的用途。

56. 发明申请

US20110281999A1 PROCESS FOR PREPARING AB DIBLOCK COPOLYMERS WITH A BROADLY DISTRIBUTED A BLOCK 有权
标题翻译：用于制备具有广泛分布的块的AB嵌段共聚物的方法
公开(公告)号：US20110281999A1
公开(公告)日：2011-11-17
申请号：US13128957
申请日：2009-10-06
申请人： Holger Kautz , Sven Balk , Stephan Fengler , Dorothea Staschik , Christine Miess , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
发明人： Holger Kautz , Sven Balk , Stephan Fengler , Dorothea Staschik , Christine Miess , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
IPC分类号： C09D153/00 , C08F220/10
CPC分类号： C08F2/38 , C08F2/001 , C08F2/06 , C08F4/00 , C08F6/02 , C08F293/005 , C08F2438/01 , C08L53/00 , C09D153/00 , C09J153/00
摘要： The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad monomodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.
摘要翻译：本发明涉及一种用于制备具有窄单峰分子量分布的B嵌段的基于（甲基）丙烯酸酯的AB二嵌段共聚物和具有宽单峰分子量分布的A嵌段的受控聚合方法及其用途，例如作为粘合剂或密封剂中的粘合剂。

57. 发明申请

US20110224359A1 PROCESS FOR PREPARING AB DIBLOCK COPOLYMERS WITH A BIMODALLY DISTRIBUTED A BLOCK 有权
标题翻译：用双模分布的块制备AB二嵌段共聚物的方法
公开(公告)号：US20110224359A1
公开(公告)日：2011-09-15
申请号：US13125177
申请日：2009-10-06
申请人： Holger Kautz , Sven Balk , Stephan Fengler , Dorothea Staschik , Christine Miess , Lars Zander , Jens Lückert , Johann Klein , Thomas Möller , Volker Erb
发明人： Holger Kautz , Sven Balk , Stephan Fengler , Dorothea Staschik , Christine Miess , Lars Zander , Jens Lückert , Johann Klein , Thomas Möller , Volker Erb
IPC分类号： C08F293/00 , C09D153/00 , C09J153/00
CPC分类号： C09K3/10 , C08F293/005 , C08F2438/01 , C09J153/00 , C09K2200/0625
摘要： The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad bimodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.
摘要翻译：本发明涉及一种用于制备具有窄单峰分子量分布的B嵌段的基于（甲基）丙烯酸酯的AB二嵌段共聚物的受控聚合方法和具有宽双峰分子量分布的A嵌段及其用途，例如作为粘合剂或密封剂中的粘合剂。

58. 发明申请

US20110207876A1 METHOD FOR PRODUCING ABA-TRIBLOCK COPOLYMERS WITH A BIMODAL B-BLOCK 有权
标题翻译：用双模B块生产ABA-TRIBLOCK共聚物的方法
公开(公告)号：US20110207876A1
公开(公告)日：2011-08-25
申请号：US13127159
申请日：2009-10-06
申请人： Sven Balk , Holger Kautz , Stephan Fengler , Christine Troemer , Monika Maerz , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
发明人： Sven Balk , Holger Kautz , Stephan Fengler , Christine Troemer , Monika Maerz , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller , Volker Erb
IPC分类号： C09J153/00 , C08F299/04 , C08F299/08 , C09D153/00
CPC分类号： C08F2/38 , C08F2/001 , C08F2/06 , C08F6/02 , C08F293/005 , C08F2438/01 , C08L53/00 , C08L2666/02 , C09D153/00 , C09J153/00
摘要： The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks which have a narrow, monomodal molecular weight distribution and a B-block which has a bimodal molecular weight distribution, and to the use thereof as binders in glues and sealing materials
摘要翻译：本发明涉及一种基于（甲基）丙烯酸酯与具有窄单分子量分布的A-嵌段和具有双峰分子量分布的B嵌段生产ABA-三嵌段共聚物的受控聚合方法，以及其用作胶粘剂和密封材料中的粘合剂

59. 发明申请

US20110086984A1 METHOD FOR PRODUCING SILYL-FUNCTIONALIZED ABA TRIBLOCK COPOLYMERS ON THE BASIS OF (METH)ACRYLATE 有权
标题翻译：基于（甲基）丙烯酸酯生产硅官能化ABA三嵌段共聚物的方法
公开(公告)号：US20110086984A1
公开(公告)日：2011-04-14
申请号：US12992430
申请日：2009-04-14
申请人： Sven Balk , Gerd Loehden , Holger Kautz , Christine Troemer , Monika Maerz , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller
发明人： Sven Balk , Gerd Loehden , Holger Kautz , Christine Troemer , Monika Maerz , Lars Zander , Jens Lueckert , Johann Klein , Thomas Moeller
IPC分类号： C08F293/00
CPC分类号： C09K3/10 , C08F293/005 , C08L53/005 , C08L2666/02 , C09J153/005 , C09K2200/0625
摘要： The invention relates to a process for preparing (meth)acrylate-based ABA triblock copolymers with a silyl functionalization of the A blocks.
摘要翻译：本发明涉及一种制备（甲基）丙烯酸酯基ABA三嵌段共聚物的方法，其具有A嵌段的甲硅烷基官能化。

60. 发明申请

US20110028640A1 HARDENABLE COMPOSITIONS BASED ON SILYLATED POLYURETHANES 审中-公开
标题翻译：基于苯乙烯基聚氨酯的复合组合物
公开(公告)号：US20110028640A1
公开(公告)日：2011-02-03
申请号：US12906215
申请日：2010-10-18
申请人： Johann Klein , Sara Gonzalez , Lars Zander , Christiane Kunze , Thomas Bachon , Andreas Bolte , Martin Majolo , Thomas Tamcke
发明人： Johann Klein , Sara Gonzalez , Lars Zander , Christiane Kunze , Thomas Bachon , Andreas Bolte , Martin Majolo , Thomas Tamcke
IPC分类号： C08L83/08 , C08G77/08
CPC分类号： C08G18/4866 , C08G18/10 , C08G18/227 , C08G2190/00 , C09J175/08 , C08G18/718
摘要： The invention relates to a method for producing cross-linkable formulations. In a first step of the method, at least one α,ω-difunctional organic polymer of formula (1) X-A-X (1) is converted into organyloxysilyl-terminated polymers P1, using organofunctional silanes of formula (2) Y—R—Si—(R1)m(—OR2)3m (2), in the presence of catalysts (A) selected from the group consisting of potassium, iron, indium, zinc, bismuth and copper compounds. In said formulae, R is a bivalent, optionally substituted hydrocarbon group which comprises between 1 and 12 carbon atoms and can be interrupted with heteroatoms, R1 and R2 are the same or different, monovalent, optionally substituted hydrocarbon groups which comprise between 1 and 12 carbon atoms and can be interrupted with heteroatoms, A is bivalent, optionally substituted hydrocarbon group which comprises at least 6 carbon atoms and can be interrupted with heteroatoms, m is equal to 0, 1 or 2, X is a hydroxyl group and Y is an isocyanate group, or X is an isocyanate group and Y is a hydroxyl group or a primary or secondary amino group. In a second step, the polymers P1 obtained in the first step are mixed with a silane condensation catalyst (B) selected from the group consisting of compounds of elements of the third main group and/or fourth secondary group and heterocyclic organic amines, amine complexes of the element compounds, or the mixtures thereof. Optionally, said mixture is mixed with other substances (C). The formulations do not contain organic tin compounds, and are suitable for using as adhesives, sealants, or coating agents.
摘要翻译：本发明涉及一种生产可交联制剂的方法。在该方法的第一步中，使用式（2）的有机官能硅烷将至少一种式（1）XAX（1）的α，ω-双官能有机聚合物转化为有机甲硅烷基封端的聚合物P1，Y-R-Si- （R1）m（-OR2）3m（2），在选自钾，铁，铟，锌，铋和铜化合物的催化剂（A）的存在下。在所述式中，R是二价任选取代的烃基，其包含1至12个碳原子并且可被杂原子间隔，R 1和R 2是相同或不同的，包含1至12个碳的单价，任选取代的烃基原子并且可以被杂原子中断，A是二价的，任选取代的烃基，其包含至少6个碳原子并且可以被杂原子间隔，m等于0,1或2，X是羟基，Y是异氰酸酯基团，或X为异氰酸酯基团，Y为羟基或伯或仲氨基。在第二步骤中，将第一步中获得的聚合物P1与选自第三主族和/或第四仲
子的元素化合物和杂环有机胺的硅烷缩合催化剂（B），胺络合物的元素化合物，或其混合物。任选地，将所述混合物与其它物质（C）混合。配方不含有机锡化合物，适用于粘合剂，密封剂或涂层剂。

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