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51. 发明授权

US4362885A Process for the manufacture of (iodoorganyl)alkoxysilanes 失效
标题翻译：（碘代有机基）烷氧基硅烷的制备方法
公开(公告)号：US4362885A
公开(公告)日：1982-12-07
申请号：US330355
申请日：1981-12-14
申请人： Peter Panster , Alfons Karl , Wolfgang Buder , Peter Kleinschmit
发明人： Peter Panster , Alfons Karl , Wolfgang Buder , Peter Kleinschmit
IPC分类号： C07F7/18 , C07F7/08
CPC分类号： C07F7/1888
摘要： The subject of the invention is a process for the manufacture of (iodoorganyl)alkoxysilanes of the general formula: ##STR1## in which R.sup.1 is an alkylene group, R.sup.2 is an alkoxy group and R.sup.3 and R.sup.4 an alkoxy group and/or an alkyl or aryl group, whereby the chlorine or bromine compound corresponding to that of formula (1) is caused to react with stoichiometric to double molar quantities of an inorganic iodine donor in the presence of 0.01-5 mol % of an organic substituted onium salt of nitrogen, phosphorus, arsenic or antimony or an organic substituted sulfonium salt or a crown ether as catalyst, in certain solubilizing agents.
摘要翻译：本发明的主题是制备通式如下的（碘代有机基）烷氧基硅烷的方法：其中R1是亚烷基，R2是烷氧基，R3和R4是烷氧基和/或烷基或芳基，其中使与对应于式（1）的氯或溴化合物在0.01-5mol％的有机取代鎓盐的存在下与化学计量比与双摩尔量的无机碘供体反应的氮，磷，砷或锑或有机取代的锍盐或冠醚作为催化剂，在某些增溶剂中。

52. 发明授权

US07102045B2 Method for carrying out-CC-coupling reactions 有权
标题翻译：进行CC-偶联反应的方法
公开(公告)号：US07102045B2
公开(公告)日：2006-09-05
申请号：US10363237
申请日：2001-07-18
申请人： Jürgen Krauter , Jörg Pietsch , Peter Panster , Klaus Köhler , Roland Heidenreich
发明人： Jürgen Krauter , Jörg Pietsch , Peter Panster , Klaus Köhler , Roland Heidenreich
IPC分类号： C07C2/08 , C07C2/72
CPC分类号： C07B37/04
摘要： The invention relates to a method for carrying out CC-coupling reactions, in particular a Heck and Suzuki reaction, in the presence of supported palladium as the catalyst and a base in a monophase or multiphase solvent mixture. According to said method, palladium detaches itself from the support in a characteristic manner, is redeposited after the reaction and the quantity of palladium not deposited after the reaction is significantly lower than 5000 ppm, in relation to the palladium used.
摘要翻译：本发明涉及在负载钯作为催化剂和单相或多相溶剂混合物中的碱的存在下进行CC偶联反应，特别是Heck和Suzuki反应的方法。根据所述方法，钯以特征的方式将其自身从载体上分离出来，在反应后重新沉积，相对于所用的钯，在反应后不沉积的钯的量显着低于5000ppm。

53. 发明授权

US06593270B1 Moldings based on pyrogenic silicon dioxide 失效
标题翻译：基于热解二氧化硅的成型品
公开(公告)号：US06593270B1
公开(公告)日：2003-07-15
申请号：US09187420
申请日：1998-11-06
申请人： Helmfried Krause , Hermanus Lansink Rotgerink , Oliver Feuer , Thomas Tacke , Peter Panster
发明人： Helmfried Krause , Hermanus Lansink Rotgerink , Oliver Feuer , Thomas Tacke , Peter Panster
IPC分类号： B01J2344
CPC分类号： C04B35/14 , B01J21/08 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J37/0018 , C07C67/055 , C07C69/01 , C07C69/15
摘要： Moldings based on pyrogenic silicon dioxide with a pore volume of 0.5 to 1.8 ml/g are prepared by homogenizing pyrogenic silicon dioxide with methylhydroxyethyl cellulose, wax and polyethylene glycol with the addition of water, subjecting this mixture to a compounding and shaping process, extruding, optionally cutting the extrudate to the desired length using a cutting device, drying at a temperature of 70° to 150° C. and conditioning for a period of 30 minutes to 10 hours at a temperature of 400° to 1200° C. The moldings may be used as catalysts or catalyst supports for the preparation of vinyl acetate monomer, the hydration of ethylene and the hydration of propylene.
摘要翻译：通过用甲基羟乙基纤维素，蜡和聚乙二醇与加入水均匀化热解二氧化硅，制备孔体积为0.5至1.8ml / g的热解二氧化硅的模制品，使该混合物进行配混和成型过程，任选地使用切割装置将挤出物切割成所需长度，在70℃至150℃的温度下干燥，并在400-1200℃的温度下调理30分钟至10小时。模制品可以用作制备乙酸乙烯酯单体的催化剂或催化剂载体，乙烯的水合和丙烯的水合。

54. 发明授权

US06316646B1 Process for the continuous catalytic transformation of organic compounds 失效
标题翻译：有机化合物的连续催化转化工艺
公开(公告)号：US06316646B1
公开(公告)日：2001-11-13
申请号：US09073810
申请日：1998-05-07
申请人： Thomas Tacke , Stefan Röder , Inge Beul , Steffen Laporte , Peter Panster
发明人： Thomas Tacke , Stefan Röder , Inge Beul , Steffen Laporte , Peter Panster
IPC分类号： C07C5136
CPC分类号： C11B3/006 , C07C51/36 , C07C67/303 , C11C3/12
摘要： A process for the continuous catalytic conversion of organic compounds, that, together with unwanted attendant materials, form a starting substance: first the organic compounds of the starting material are purposely extracted by means of condensed fluids. Then the extract, containing the condensed fluids and organic compounds as the reaction mixture is contacted with a catalyst for the catalytic conversion of the organic compounds to form a product mixture, which contains the individual products of the catalytic conversion. The product mixture is separated from the reaction mixture and the fluids employed are, optionally, conducted back for extraction.
摘要翻译：有机化合物的连续催化转化的方法，与不需要的伴随物质一起形成起始物质：首先，通过冷凝流体有目的地提取原料的有机化合物。然后将含有作为反应混合物的冷凝流体和有机化合物的提取物与用于催化转化有机化合物的催化剂接触以形成含有催化转化的各个产物的产物混合物。将产物混合物与反应混合物分离，并且任选地将所用流体引导回提取。

55. 发明授权

US5959164A Use of catalysts based on catalyst supports containing silicon dioxide for catalytic reactions under hydrothermal conditions 失效
标题翻译：在含有二氧化硅的催化剂载体上，在水热条件下催化反应使用催化剂
公开(公告)号：US5959164A
公开(公告)日：1999-09-28
申请号：US806715
申请日：1997-02-27
申请人： H. G. J. Lansink-Rotgerink , Heike Riedemann , Thomas Tacke , Helmfried Krause , Andreas Freund , Roland Burmeister , Peter Panster
发明人： H. G. J. Lansink-Rotgerink , Heike Riedemann , Thomas Tacke , Helmfried Krause , Andreas Freund , Roland Burmeister , Peter Panster
IPC分类号： B01J21/06 , B01J21/08 , B01J27/16 , C07C29/04
CPC分类号： B01J21/066 , B01J21/063 , B01J21/08 , B01J27/16 , C07C29/04
摘要： The use of modified silicon dioxide as a catalyst support in catalytic reactions under hydrothermal conditions is described. The pore structure of the supports may be stabilized against hydrothermal reaction conditions by impregnating the catalyst supports with elements of Group IVB of the Periodic Tube of Elements.
摘要翻译：描述了在水热条件下在催化反应中使用改性二氧化硅作为催化剂载体。通过用元素周期管的IVB族元素浸渍催化剂载体，可以稳定支撑体的孔结构，防止水热反应条件。

56. 发明授权

US5354831A Shaped organopolysiloxanes containing sulfonate groups, a process for their production and their use 失效
标题翻译：含有磺酸盐基团的有机聚硅氧烷，其生产方法及其用途
公开(公告)号：US5354831A
公开(公告)日：1994-10-11
申请号：US85960
申请日：1993-07-06
申请人： Peter Panster , Peter Kleinschmit
发明人： Peter Panster , Peter Kleinschmit
IPC分类号： B01J31/06 , B01J23/72 , B01J31/02 , B01J31/10 , B01J31/12 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , B01J37/10 , B01J39/18 , C07B61/00 , C07C1/20 , C07C11/09 , C07C31/04 , C08G77/22 , C08G77/28 , C08G77/32 , C08G77/58 , C08J3/12 , C07F7/08 , C07F5/06 , C07F7/28
CPC分类号： B01J31/124 , B01J31/0225 , B01J31/10 , B01J35/0026 , B01J35/023 , B01J37/0072 , B01J39/185 , C08G77/28 , C08G77/58 , C08J3/12 , B01J2231/49 , B01J23/72 , B01J35/1019 , B01J35/1023 , B01J35/1047 , B01J37/10 , C08J2383/08
摘要： Disclosed are shaped organopolysiloxanes containing sulfonate groups and consisting of units(O.sub.3/2 Si--R.sup.1 --SO.sub.3.sup.-).sub.x M.sup.x+ (I)in which R.sup.1 is an alkylene group, x is a number from 1 to 4 depending on M, and M is hydrogen or a monovalent to tetravalent optionally complex metal ion, and the valencies of the silicon linked oxygen atoms are saturated by silicon atoms of other groups (I) or by crosslinking silicon and aluminum compounds, the ratio of the silicon atoms in (I) to the silicon and aluminum atoms of the crosslinker being from 1:4 to 1:20. The organopolysiloxanes containing sulfonate groups are present in the form of spherical particles with a diameter of 0.01 to 3 mm, a specific surface of 0.1 to 1200 m.sup.2 /g, a specific pore volume of 0.01 to 6 ml/g, and an apparent density of 50 to 1000 g/l. Also disclosed are processes for the production of the shaped sulfonated organopolysiloxanes and to their use as a solid acid catalyst.
摘要翻译：公开了含有磺酸酯基的成型有机聚硅氧烷，其由R 1为亚烷基的单元（O 3 / 2Si-R 1 -SO 3 - ）x M x +（I）组成，x取决于M为1至4，M为氢或一价至四价任选的复合金属离子，并且硅连接的氧原子的价态由其他基团（I）的硅原子或硅和铝化合物的硅原子饱和，（I）中的硅原子与硅并且交联剂的铝原子为1:4至1:20。含有磺酸盐基团的有机聚硅氧烷以直径为0.01〜3mm，比表面积为0.1〜1200m 2 / g，比孔体积为0.01〜6ml / g的球状颗粒的形式存在，表观密度为 50〜1000g / l。还公开了制备成型磺化有机聚硅氧烷的方法及其作为固体酸催化剂的用途。

57. 发明授权

US5187134A Formed, polymeric transition-metal complex catalysts with organosiloxane phenylphosphine ligands 失效
标题翻译：形成有机硅氧基苯基膦配位体的聚合物过渡金属络合物催化剂
公开(公告)号：US5187134A
公开(公告)日：1993-02-16
申请号：US784951
申请日：1991-11-01
申请人： Peter Panster , Robert Gradl
发明人： Peter Panster , Robert Gradl
IPC分类号： C08G77/26 , B01J31/00 , B01J31/16 , B01J31/18 , B01J31/24 , B01J31/28 , C07C45/50 , C08G77/22 , C08G77/28 , C08G77/30 , C08G77/38 , C08G77/54 , C08G77/58
CPC分类号： C08G77/58 , B01J31/1675 , B01J31/1805 , B01J31/2404 , C07C45/50 , C08G77/22 , C08G77/54 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： This invention relates to formed, polymeric complexes of metals of the eighth subgroup of the periodic system with ligands of an organosiloxane copolycondensate optionally cross-linked by means of cross-linking agents containing Si, Ti, Zr and/or Al, in the form of statistical, block or mixed copolycondensates. The ratio between the number of moles of phosphine units and the number of moles of bound metal atoms is 1:1 to 1000 to 1 and the ratio between the amine units and the phosphine is preferably 5:95 to 95:5 mole %. The polymeric complex compounds are present macroscopically as spherical particles with a diameter in the range of 0.01 to 3.0 mm, a BET surface of greater than 0 to 1000 m.sup.2 /g, a specific pore volume of 0.01 to 6.5 ml/g and a bulk density of 50 to 1000 g/l. The invention also includes several methods of preparing the complexes with post-treatment stages and the use of the polymeric metal complexes as catalysts in organic chemistry.
摘要翻译：本发明涉及周期性系统的第八亚组的金属的形成的聚合物络合物与有机硅氧烷共缩聚物的配体，任选地通过含Si，Ti，Zr和/或Al的交联剂交联，其形式为统计学，块状或混合共缩聚物。膦单元的摩尔数与结合金属原子的摩尔数之比为1:1〜1000:1，胺单元与膦的比例优选为5:95〜95:5摩尔％。聚合物络合物以宏观形式存在，其直径范围为0.01〜3.0mm，BET表面积大于0〜1000m2 / g，比孔体积为0.01〜6.5ml / g，体积密度为50〜1000g / l。本发明还包括几种在后处理阶段制备络合物的方法以及在有机化学中使用聚合物金属络合物作为催化剂。

58. 发明授权

US5061773A Aminoalkyl-substituted organopolysiloxane thiourea derivatives and methods of preparation and use thereof 失效
标题翻译：氨基烷基取代的有机聚硅氧烷硫脲衍生物及其制备和使用方法
公开(公告)号：US5061773A
公开(公告)日：1991-10-29
申请号：US558867
申请日：1990-07-30
申请人： Peter Panster , Ulrich Deschler , Peter Kleinschmit
发明人： Peter Panster , Ulrich Deschler , Peter Kleinschmit
IPC分类号： C02F1/62 , B01J20/26 , C02F1/28 , C08G77/28 , C08G77/48 , C08G77/54 , C08G77/58
CPC分类号： C02F1/285 , B01J20/26 , C08G77/28 , C08G77/54 , C08G77/58
摘要： Aminoalkyl-substituted organopolysiloxane thioureas are disclosed which consist of the units ##STR1## whereby R.sup.1 stands for a group ##STR2## R.sup.5 is an alkylene grouping, R.sup.2 is equal to R.sup.1 or H, R.sup.3 is equal to R.sup.1 or H or a group (CH.sub.2).sub.n --N(R.sup.6).sub.2 (III) (in which n=1-6, R.sup.6 =H or an alkyl group with C.sub.1 -C.sub.5) and R.sup.4 =H or a group of the formula (III), whereby (I) contains at most 2 (III) groups and at most 2 (III) groups and the free valances of the oxygen atoms sitting on the silicon atom are saturated by silicon atoms of other (III) groups, optionally with the insertion of cross-linking agents containing Si, Ti or Zr. The compounds can be random copolycondensates, block copolycondensates or mixed copolycondensates in relation to the optionally present cross-linking agents. In addition, various methods of preparing the compounds are indicated. The compounds can be used especially for the removal of dissolved metals from aqueous or organic phases.
摘要翻译：（I）单元组成的氨基烷基取代的有机聚硅氧烷硫脲，其中R1代表一个基团（II）R5是亚烷基，R2等于R1或H，R3等于R1或 H或基团（CH 2）n N（R 6）2（III）（其中n = 1-6，R 6 = H或具有C 1 -C 5的烷基）和R 4 = H或式（III）的基团，其中（I）含有至多2个（III）基团和至多2个（III）基团，并且位于硅原子上的氧原子的游离价数被其它（III）基团的硅原子饱和，任选地插入含有Si，Ti或Zr的交联剂。所述化合物可以是无规共聚缩合物，相对于任选存在的交联剂阻断共聚缩聚物或混合的共缩聚物。另外，表示了制备化合物的各种方法。该化合物特别用于从水相或有机相中除去溶解的金属。

59. 发明授权

US5019637A Organopolysiloxane urea derivatives and organopolysiloxane thiourea derivatives, methods of their preparation and use 失效
标题翻译：有机聚硅氧烷脲衍生物和有机聚硅氧烷硫脲衍生物，其制备方法及用途
公开(公告)号：US5019637A
公开(公告)日：1991-05-28
申请号：US431219
申请日：1989-11-03
申请人： Peter Panster , Ulrich Deschler
发明人： Peter Panster , Ulrich Deschler
IPC分类号： B01J20/26 , B01J20/22 , C08G77/42 , C08G77/44 , C08G77/48 , C08G77/54 , C08G77/58
CPC分类号： B01J20/22 , C08G77/54 , C08G77/58
摘要： The invention is relative to optionally cross-linked organopolysiloxane urea derivatives and thiourea derivatives consisting of: ##STR1## wherein X stands for 0 or S andR.sup.1 is a group of the formula: ##STR2## in which R.sup.5 is alkylene with 1 to 10 C atoms or cycloalkylene with 5 to 8 C atoms or a group of the formula: ##STR3## with n=1-6 (on the nitrogen)m=0-6 (on the silicon), wherein R.sup.2 has the same meaning as R.sup.1 or stands for H, R.sup.3 and R.sup.4 have the same meaning as R.sup.1 or stands for H or alkyl with 1 to 5 C atoms. At least two but at the most three groups according to formula (2) are bound to the units according to formula (1). The free valances of the oxygen atoms bound to the silicon atom are saturated by silicon atoms of further groups of formula (2) with the optional inclusion of cross-linking agents. In addition, preparative methods for the products and a use for the removal of dissolved metals from liquid phases are indicated.
摘要翻译：本发明相对于任选的交联的有机聚硅氧烷脲衍生物和硫脲衍生物，其由以下组成：其中X代表0或S，R1是下式的基团：其中R5是具有1至10个C原子的亚烷基或具有5至8个碳原子的亚环烷基或具有n = 1-6（在氮上）m = 0-6（在硅上的下式的基团：），其中R2具有与R 1相同的含义或代表H，R 3和R 4具有与R 1相同的含义或代表H或具有1至5个C原子的烷基。根据式（2），至少两个但最多三个基团与根据式（1）的单元结合。与硅原子结合的氧原子的自由价数由另外的式（2）基团的硅原子饱和，任选地包含交联剂。此外，还指出了产品的制备方法和用于从液相中除去溶解的金属的用途。

60. 发明授权

US5003024A Organosiloxane amine copolycondensates, method of their preparation and use (I) 失效
标题翻译：有机硅氧烷胺共缩聚物，其制备方法和用途（I）
公开(公告)号：US5003024A
公开(公告)日：1991-03-26
申请号：US431218
申请日：1989-11-03
申请人： Peter Panster , Robert Gradl , Peter Kleinschmit
发明人： Peter Panster , Robert Gradl , Peter Kleinschmit
IPC分类号： B01J20/26 , B01J20/22 , C08G77/26 , C08G77/42 , C08G77/44 , C08G77/48 , C08G77/50 , C08G77/54 , C08G77/58
CPC分类号： B01J20/22 , C08G77/26 , C08G77/54 , C08G77/58
摘要： Organosiloxane amine copolycondensates as statistic or block copolycondensates or mixtures thereof consisting of the units ##STR1## in which R.sup.1 to R.sup.5 is ##STR2## and R.sup.6 is bound directly to the nitrogen atom or the double-bonding X group and is alkylene, cycloalkylene or ##STR3## in which n is 1 to 6 and m 0 to 6. The free valences of the oxygen atoms bound to the silicon atom are saturated by silicon atoms of further groups of formula III, optionally with the inclusion of cross-linking agents, X stands for ##STR4## in which R" is H or alkyl. In addition, preparation methods and the use of the products for the removal of dissolved metals from liquid phase or for the adsorption of gaseous compounds.
摘要翻译：有机硅氧烷胺共缩聚物作为统计或嵌段共缩合物或其混合物，其由其中R 1至R 5为（III）且R 6直接键合到氮原子上的单元（I）和（VI）双键X基并且是亚烷基，亚环烷基或者其中n为1至6且m 0至6的亚环烷基或亚环烷基或者其中n为0至6的键。硅原子结合的氧原子的游离价数被硅原子饱和的另外的式III基团，任选地含有交联剂，X代表其中R“是H或烷基的 + TR 。另外，制备方法和产品用于从液相中除去溶解的金属或用于气态化合物的吸附。

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