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51. 发明申请

US20110245375A1 CURABLE COMPOSITION COMPRISING A THERMOLATENT BASE 有权
标题翻译：包含热稳定基的可固化组合物
公开(公告)号：US20110245375A1
公开(公告)日：2011-10-06
申请号：US13130331
申请日：2009-11-18
申请人： Peter Nesvadba , Lucienne Bugnon Folger , Ralf Knischka
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Ralf Knischka
IPC分类号： C09D163/00 , C08L63/00 , C07D213/72 , C07D215/38
CPC分类号： C07D213/74 , C07D215/38 , C08G59/4246 , C08G59/686 , C08L63/00
摘要： The present invention relates to curable compositions comprising a thermolatent amidine base and an organic material which is polymerisable or crosslinkable with a basic or nucleophilic catalyst. In particular, the invention relates to curable coating compositions, especially powder coating compositions, and curable adhesive compositions, as well as to the use a thermo-latent amidine base as a curing catalyst for thermally induced base- catalyzed polymerisation or crosslinking reactions.
摘要翻译：本发明涉及可固化组合物，其包含热中和脒碱和可与碱性或亲核催化剂聚合或可交联的有机材料。特别地，本发明涉及可固化涂料组合物，特别是粉末涂料组合物和可固化粘合剂组合物，以及使用热潜伏脒碱作为热诱导的碱催化聚合或交联反应的固化催化剂。

52. 发明授权

US07902368B2 Cationic substituted 2,2,6,6-tetraalkylpiperidinyl alkoxyamines 有权
标题翻译：阳离子取代的2,2,6,6-四烷基哌啶基烷氧基胺
公开(公告)号：US07902368B2
公开(公告)日：2011-03-08
申请号：US12535747
申请日：2009-08-05
申请人： Andreas Mühlebach , Peter Nesvadba , Andreas Kramer
发明人： Andreas Mühlebach , Peter Nesvadba , Andreas Kramer
IPC分类号： C07D211/00
CPC分类号： C08F4/00 , C07D211/94 , C07D241/08 , C07F9/4006 , C07F9/59
摘要： Cationic 2,2,6,6-tetraalkylpiperidinyl alkoxyamines of, for example, formula (1a) and (1b) are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays. Compositions comprising improved nanocomposites produced by this process are useful as, for example, coatings, sealants, caulks, adhesives and plastic additives wherein Q1 is a direct bond or a —CH2— group T1, T2, T3 and T4 are independently methyl or ethyl with the proviso that at least one is ethyl; T7 and T8 are hydrogen or methyl; T5 and T6 are hydrogen or T5 and T6 together are a group ═O, ═NOH, ═NO-T9 or T5 is hydrogen and T6 is —O-T9 or —NR9-T9 T9 is hydrogen, R9 or —C(O)—R9; R9 is hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkynyl, phenyl or C7-C9phenylalkyl unsubstituted or substituted by hydroxy, halogen or C1-C4alkoxy; K1 and K2 are hydrogen, C1-C18alkyl, C5-C12cycloalkyl, phenyl or C7-C9phenylalkyl and K3 is a group containing selected amine containing salts.
摘要翻译：例如式（1a）和（1b）的阳离子2,2,6,6-四烷基哌啶基烷氧基胺可用作控制稳定的自由基聚合方法中的聚合引发剂/调节剂，以产生自然或/或合成粘土。包含通过该方法制备的改进的纳米复合材料的组合物可用作例如涂料，密封剂，填隙剂，粘合剂和塑料添加剂，其中Q1是直接键或-CH 2 - 基团T1，T 2，T 3和T 4独立地是甲基或乙基，条件是至少一个是乙基; T7和T8是氢或甲基; T5和T6是氢或T5和T6一起是基团= O，≡NOH，≡NO-T9或T5是氢，T6是-O-T9或-NR9-T9，T9是氢，R9或-C（O） -R9; R 9是氢，C 1 -C 18烷基，C 3 -C 18烯基，C 3 -C 18炔基，苯基或未被取代或被羟基，卤素或C 1 -C 4烷氧基取代的C 7 -C 9苯基烷基; K 1和K 2是氢，C 1 -C 18烷基，C 5 -C 12环烷基，苯基或C 7 -C 9苯基烷基，K 3是含有选择的含胺盐的基团。

53. 发明申请

US20100143805A1 NITROXIDES FOR LITHIUM-ION BATTERIES 审中-公开
标题翻译：硝酸锂用于锂离子电池
公开(公告)号：US20100143805A1
公开(公告)日：2010-06-10
申请号：US12529720
申请日：2008-02-29
申请人： Tobias Hintermann , Peter Nesvadba , Markus Frey , Lucienne Bugnon Folger
发明人： Tobias Hintermann , Peter Nesvadba , Markus Frey , Lucienne Bugnon Folger
IPC分类号： H01M6/16 , H01M10/05 , H01M10/26 , C07D241/04 , C07F9/06 , C07D233/54
CPC分类号： C07D233/32 , C07D233/42 , C07D235/02 , C07D241/08 , C07D241/52 , C07D243/14 , C07D265/32 , C07D265/34 , C07D265/36 , C07D405/06 , C07F9/6584 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/4235
摘要： This invention relates to overcharge protection and molecular redox shuttles in rechargeable lithium-ion cells. For this, specific nitroxyls or oxoammonium salts are used in the electrolyte. This invention also relates to a method of producing such lithium-ion cells and to a method of recharging such lithium-ion cells. This invention also pertains to some nitroxyls compounds and oxoammonium salts.
摘要翻译：本发明涉及可充电锂离子电池中的过充电保护和分子氧化还原梭。为此，在电解质中使用特定的硝酰氧基或氧代铵盐。本发明还涉及这种锂离子电池的制造方法和锂离子电池的充电方法。本发明还涉及一些硝酰基化合物和氧代铵盐。

54. 发明授权

US07723399B2 N-substituted imides as polymerization initiators 有权
标题翻译： N-取代酰亚胺作为聚合引发剂
公开(公告)号：US07723399B2
公开(公告)日：2010-05-25
申请号：US11666887
申请日：2005-10-31
申请人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
发明人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
IPC分类号： C08F299/00 , C07D221/04 , C07D209/56 , C07D209/48
CPC分类号： C07D207/404 , B33Y70/00 , C07D207/46 , C07D209/48 , C07D221/14 , C08F4/00
摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C-18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O— and/or S-atoms.
摘要翻译：本发明涉及新型的N-取代的酰亚胺和包含这些N-取代的酰亚胺的可聚合组合物。本发明还涉及N-取代的酰亚胺作为聚合引发剂的用途。酰亚胺是式（I）和（II）的化合物，其中n为1或2; m为1或2; R 1和R 2各自独立地为氢，C 1 -C 18烷基，C 1 -C 18烯基C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 1-6烷氧基，羰基，C 1 -C 6烷氧基羰基; 或R 1和R 2与相邻的-CO-N-CO-基团一起可以形成单环，双环或多环，所述环具有至多50个非氢原子，并且其中所述环可含有结构单元（式III）一旦; 如果n为1，R 3为C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，OR 10或SR 11，NR 12 R 13; 其中如果n为2，R 3为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基R4和R 5对应于R 1和R 2; 如果n为1，R 6为氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，NR 14 R 15; 其中如果n为2，R 6为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基; R 7是氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 6烷氧基，羰基，C 1 -C 6烷氧基 - 羰基取代; 或R 7和R 14或R 7和R 15与连接至R 7的N-原子一起形成5-6元环，任选被-NH-，-N（C 1 -C 8烷基） - ， - 和 - 或S-原子。

55. 发明授权

US07723398B2 In-can stabilizer blend 有权
标题翻译：罐内稳定剂混合物
公开(公告)号：US07723398B2
公开(公告)日：2010-05-25
申请号：US11918694
申请日：2006-04-12
申请人： Stephan Ilg , Edith Pighetti , Peter Nesvadba , André Fuchs
发明人： Stephan Ilg , Edith Pighetti , Peter Nesvadba , André Fuchs
IPC分类号： C08F2/50 , C08J3/28 , C08K5/04 , C08K5/15 , C08K5/16
CPC分类号： C08K5/3435 , C07B63/04 , C08K5/08 , C09D7/63 , C09D11/101
摘要： The invention relates to a radiation curable coating or an ink composition comprising a photoinitiator and a stabilizer blend of a sterically hindered nitroxyl radical and a quinone methide.
摘要翻译：本发明涉及一种可辐照固化涂层或油墨组合物，其包含光引发剂和空间位阻硝酰基和醌甲基化物的稳定剂共混物。

56. 发明授权

US07579411B2 Process for the controlled increase in the molecular weight of polyethylenes 有权
标题翻译：控制聚乙烯分子量增加的方法
公开(公告)号：US07579411B2
公开(公告)日：2009-08-25
申请号：US12069641
申请日：2008-02-12
申请人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
发明人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
IPC分类号： C08C19/22 , C08F8/32
CPC分类号： C07D491/10 , C07C239/22 , C07D209/44 , C07D211/94 , C07D233/32 , C07D233/38 , C07D241/08 , C07D295/24 , C07D401/14 , C07D487/10 , C07F9/59 , C08F2/38 , C08F4/00 , C08F8/30 , C08F8/50 , C08F110/02 , C08F110/06 , C08K5/3435 , C08L23/06 , C08L23/10 , C08L2023/44 , C08L2205/02 , C08L2666/06 , C08F8/00
摘要： The invention relates to hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer and methods for achieving a controlled increase in the molecular weight of polyethylene.
摘要翻译：本发明涉及羟胺酯和包含这些羟胺酯和烯属不饱和单体或低聚物的可聚合组合物以及用于实现聚乙烯分子量控制增加的方法。

57. 发明授权

US07572869B2 N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith 失效
标题翻译： N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控的自由基聚合
公开(公告)号：US07572869B2
公开(公告)日：2009-08-11
申请号：US11903093
申请日：2007-09-20
申请人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
发明人： Peter Nesvadba , Marie-Odile Zink , Wiebke Wunderlich
IPC分类号： C08F2/38 , C07D211/94 , C08F12/08
CPC分类号： C07D211/94 , C07D491/113 , C07D491/22 , C07D519/00 , C08F2/46 , C08F4/00
摘要： The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基哌啶衍生物，其在4位被两个形成开链或环状缩酮结构的氧原子取代，所述可聚合组合物包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。本发明的另外的方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成用于受控聚合的开链或环状缩酮结构。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

58. 发明申请

US20090198033A1 Novel Alkoxyamines Containing Unsaturated Groups 有权
标题翻译：含有不饱和基团的新型烷氧基胺
公开(公告)号：US20090198033A1
公开(公告)日：2009-08-06
申请号：US12084022
申请日：2006-10-16
申请人： Lothar Alexander Engelbrecht , Peter Nesvadba
发明人： Lothar Alexander Engelbrecht , Peter Nesvadba
IPC分类号： C08G77/10 , C08G77/08 , C08G77/12 , C07D211/98 , C07D211/94
CPC分类号： C08G77/10
摘要： The invention relates to new alkoxyamines suitable for hydrosilylation reactions, to siloxane modified alkoxamines and to siloxane modified polymers and to their use as slip and leveling agent or as dispersant. The alkoxamines are compounds of formula (I) or (II) wherein A is a group capable of forming a stable free nitroxyl radical A. which is bound via its oxygen atom to the carbon atom; R1 and R2 independently of one another are hydrogen, C1-C18-alkyl, C3-C8cycloalkyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; R3, R4 and R5 independently of one another are hydrogen or C1-C18alkyl or phenyl; or R3 and R5 together with the linking group C═C form a 5 to 12 membered ring; R6 is X hydrogen or C1-C18alkyl or phenyl; X is O, NH or NR7, wherein R7 is C1-C18alkyl, C3-C8cycloalkyl or phenyl; Y is a direct bond, C1-C30alkylene or C6-C12arylene, with the proviso that the compound of formula (I) is not (1) or (2).
摘要翻译：本发明涉及适用于氢化硅烷化反应的新型烷氧基胺，硅氧烷改性烷氧基胺和硅氧烷改性聚合物，以及它们作为滑爽和流平剂或分散剂的用途。烷氧基胺是式（I）或（II）的化合物，其中A是能够形成稳定的游离硝酰基A的基团，其通过其氧原子与碳原子结合; R 1和R 2彼此独立地是氢，C 1 -C 18 - 烷基，C 3 -C 8环烷基或未被NO 2，卤素，氨基，羟基，氰基，羧基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基氨基或二（C 1 -C 4烷基）氨基; R 3，R 4和R 5彼此独立地是氢或C 1 -C 18烷基或苯基; 或R3和R5与连接基团C-C一起形成5-12元环; R6是X氢或C1-C18烷基或苯基; X是O，NH或NR 7，其中R 7是C 1 -C 18烷基，C 3 -C 8环烷基或苯基; Y是直接键，C 1 -C 30亚烷基或C 6 -C 12亚芳基，条件是式（I）化合物不是（1）或（2）。

59. 发明申请

US20050250884A1 Polymeric alkoyamines prepared by atom transfer radical addition (atra) 失效
标题翻译：通过原子转移自由基加成制备的聚合烷基胺（atra）
公开(公告)号：US20050250884A1
公开(公告)日：2005-11-10
申请号：US10526693
申请日：2003-09-16
申请人： Peter Nesvadba
发明人： Peter Nesvadba
IPC分类号： C08F4/00 , C08F4/40 , C08K5/32 , C08K5/3435 , C08K5/34 , C09K15/00
CPC分类号： C08F4/00 , C08K5/3435
摘要： The instant invention pertains to polymeric alkoxyamines, which are prepared by atom transfer radical addition polymerization (ATRA). Further aspects of the invention are a process for their preparation and their use as light stabilizers, flame retardants and polymerization regulators/initiators in controlled radical polymerization processes. Yet another aspect of the invention are novel monomeric intermediate alkoxyamines, which are also useful as polymerization regulators/initiators.
摘要翻译：本发明涉及通过原子转移自由基加成聚合（ATRA）制备的聚合烷氧基胺。本发明的其它方面是其制备方法及其作为受控自由基聚合方法中的光稳定剂，阻燃剂和聚合调节剂/引发剂的用途。本发明的另一方面是新颖的单体中间体烷氧基胺，其也可用作聚合调节剂/引发剂。

60. 发明申请

US20050124814A1 Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization 失效
标题翻译：开链烷氧基胺及其相应的氮氧化物用于控制低温自由基聚合
公开(公告)号：US20050124814A1
公开(公告)日：2005-06-09
申请号：US10506700
申请日：2003-02-25
申请人： Tobias Hintermann , Peter Nesvadba , Andreas Kramer , Jochen Fink
发明人： Tobias Hintermann , Peter Nesvadba , Andreas Kramer , Jochen Fink
IPC分类号： C07D333/40 , C07C219/22 , C07C239/20 , C07C291/00 , C07C321/28 , C07D265/32 , C07D265/34 , C08F4/00 , C07D401/00
CPC分类号： C08F4/00
摘要： The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.
摘要翻译：本发明涉及开链烷氧基胺化合物，可聚合组合物，其包含a）至少一种烯键式不饱和单体和b）至少一种开链烷氧基胺化合物。本发明的另外的方面是用于聚合烯键式不饱和单体的方法，以及使用开链烷氧基胺化合物用于受控聚合。中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及其聚合的方法和用途也是本发明的主题。

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