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    • 53. 发明授权
    • Liquid crystal device and liquid crystal apparatus
    • 液晶装置和液晶装置
    • US5841497A
    • 1998-11-24
    • US681350
    • 1996-07-23
    • Koichi SatoKenji ShinjoMasahiro TeradaSyuji Yamada
    • Koichi SatoKenji ShinjoMasahiro TeradaSyuji Yamada
    • C09K19/34G02F1/1337
    • C09K19/34C09K19/3458G02F1/133723
    • A liquid crystal device is constituted by a pair of substrates each having thereon an electrode for voltage application, a chiral smectic liquid crystal composition disposed between the substrates so as to assume at least two optically stable states. At least one of the substrates is provided with an alignment control layer having a thickness of at most 200 .ANG. or comprising polyimide. The substrates have been subjected to different aligning treatments at their opposite faces each contacting the composition. The composition comprises at least three fluorine-containing mesomorphic compounds each comprising a fluorocarbon terminal portion and a hydrocarbon terminal portion, the terminal portions being connected with a central core, the compounds having smectic mesophase or latent smectic mesophase; said at least three mesomorphic compounds comprising a compound having a fluorocarbon terminal portion containing one catenary ether oxygen atom, a compound having a fluorocarbon terminal portion containing two catenary ether oxygen atoms, and a compound having a fluorocarbon terminal portion containing three catenary ether oxygen atoms. The above liquid crystal device is effective in improving a duration margin to provide good drive characteristic when driven.
    • 液晶装置由一对基板构成,每个基板上具有用于施加电压的电极,设置在基板之间的手性近晶液晶组合物,以呈现至少两个光学稳定状态。 至少一个基板设置有厚度最多为200或包含聚酰亚胺的取向控制层。 在各自的接触组合物的相对面上,基板已进行不同的取向处理。 所述组合物包含至少三种含氟介孔化合物,其各自包含碳氟化合物末端部分和烃末端部分,末端部分与中心核心连接,所述化合物具有近晶中间相或潜在的近晶相中间相; 所述至少三种介晶化合物包含具有含有一个链状醚氧原子的碳氟化合物末端部分的化合物,具有含有两个链状乙烯氧原子的碳氟化合物末端部分的化合物和具有含有三个链状醚氧原子的碳氟化合物末端部分的化合物。 上述液晶装置在驱动时有效地提高持续时间余量以提供良好的驱动特性。
    • 54. 发明授权
    • Liquid crystal composition, liquid crystal device using the composition,
liquid crystal apparatus and display method
    • 液晶组合物,使用组合物的液晶装置,液晶装置和显示方法
    • US5688437A
    • 1997-11-18
    • US422262
    • 1995-04-14
    • Koichi SatoHiroyuki KitayamaKenji ShinjoKatsutoshi NakamuraShinichi Nakamura
    • Koichi SatoHiroyuki KitayamaKenji ShinjoKatsutoshi NakamuraShinichi Nakamura
    • C09K19/34C09K19/12C09K19/20C09K19/32
    • C09K19/34
    • A liquid crystal composition includes a liquid crystal containing at least one mesomorphic compound having a cholesteric phase (Ch phase)-free mesomorphic phase, and at least one compound (e) having a limit of solubility in the liquid crystal and being contained in the composition in a proportion ranging from 20% of the limit of solubility to below the limit of solubility. The liquid crystal composition may preferably include the liquid crystal containing at least one fluorine-containing mesomorphic compound (a) having a fluorocarbon terminal portion and a hydrocarbon terminal portion, and at least one achiral compound (b), a the compound (e), having a specific ring structure and a specific terminal alkyl group free from a perfluorocarbon atom. The compound having a Ch phase-free mesomorphic phase, preferably the compound (a), and the compound (e), preferably the compound (b) are effective in providing the liquid crystal composition with a layer structure of so-called bookshelf or a layer structure having a small inclination angle (closer to bookshelf structure). The liquid crystal composition is useful in improving response characteristics and display characteristics, particularly a contrast ratio, of a liquid crystal device using the liquid crystal composition.
    • 液晶组合物包括含有至少一种具有胆甾型相(Ch相) - 自由相态的介晶化合物的液晶和至少一种在液晶中具有极限溶解性并包含在该组合物中的化合物(e) 其比例范围从溶解度的20%到低于溶解度的极限。 液晶组合物可以优选包含含有至少一种含氟碳末端部分和烃末端部分的含氟介晶化合物(a)的液晶,以及至少一种非手性化合物(b),化合物(e), 具有特定的环结构和不含全氟化碳原子的特定末端烷基。 具有Ch相无介晶相的化合物,优选化合物(a)和化合物(e),优选化合物(b))有效地为所述液晶组合物提供所谓书架或 层结构具有较小的倾斜角度(更靠近书架结构)。 液晶组合物可用于改善使用液晶组合物的液晶装置的响应特性和显示特性,特别是对比度。
    • 55. 发明授权
    • Liquid crystal device for gradational display
    • 液晶显示器
    • US5583682A
    • 1996-12-10
    • US253160
    • 1994-06-02
    • Hiroyuki KitayamaKenji ShinjoSyuji Yamada
    • Hiroyuki KitayamaKenji ShinjoSyuji Yamada
    • G02F1/1337C09K19/02C09K19/34G02F1/141
    • C09K19/34C09K19/0225G02F1/1416G02F2203/30
    • A liquid crystal device for gradational display, comprising: a pair of substrates each provided with an electrode, and a liquid crystal layer comprising a chiral smectic liquid crystal disposed between the substrates; the pair of substrates each having thereon alignment control layer provided with a uniaxial alignment axis, wherein aid liquid crystal layer comprises a striped region and a non-striped region where (1) the striped region and the non-striped region each assume a homogeneous alignment state, (2) the striped region extends in a direction perpendicular to the direction of the uniaxial alignment axis, and (3) each of liquid crystal molecules within the striped region and the non-striped region show bistability; and the liquid crystal molecules within the striped region have a threshold voltage, for switching between two stable states, different from that given by the liquid crystal molecules within the on-striped region. The above two regions (striped and non-striped region) having different threshold voltages each other are suitable as a display region for a liquid crystal device providing good gradation characteristic.
    • 一种用于梯度显示的液晶显示装置,包括:一对基板,每个基板均设置有电极;以及液晶层,其包括设置在所述基板之间的手性近晶液晶; 所述一对基板各自具有设置有单轴取向轴的取向控制层,其中辅助液晶层包括条纹区域和非条带区域,其中(1)所述条纹区域和所述非条纹区域各自呈均匀对准 状态,(2)条纹区域沿垂直于单轴取向轴线方向的方向延伸,(3)条纹区域和非条纹区域中的每个液晶分子显示双稳态; 并且条纹区域内的液晶分子具有阈值电压,用于在两个稳定状态之间切换,不同于在条纹区域内的液晶分子给出的稳定状态。 具有不同阈值电压的上述两个区域(条纹和非条纹区域)适合作为提供良好灰度特性的液晶装置的显示区域。