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    • 53. 发明授权
    • Grapho-epitaxy DSA process with dimension control of template pattern
    • Grapho外延DSA过程与模板图案的尺寸控制
    • US09123658B2
    • 2015-09-01
    • US14327968
    • 2014-07-10
    • INTERNATIONAL BUSINESS MACHINES CORPORATION
    • Jassem A. AbdallahMatthew E. ColburnSteven J. HolmesChi-Chun Liu
    • H01L21/311H01L21/308H01L21/3065
    • H01L21/3086G03F7/0002H01L21/0337H01L21/3065H01L21/3081
    • A method for defining a template for directed self-assembly (DSA) materials includes patterning a resist on a stack including an ARC and a mask formed over a hydrophilic layer. A pattern is formed by etching the ARC and the mask to form template lines which are trimmed to less than a minimum feature size (L). Hydrophobic spacers are formed on the template lines and include a fractional width of L. A neutral brush layer is grafted to the hydrophilic layer. A DSA material is deposited between the spacers and annealed to form material domains in a form of alternating lines of a first and a second material wherein the first material in contact with the spacers includes a width less than a width of the lines. A metal is added to the domains forming an etch resistant second material. The first material and the spacers are removed to form a DSA template pattern.
    • 用于定义用于定向自组装(DSA)材料的模板的方法包括在包括ARC和在亲水层上形成的掩模的堆叠上构图抗蚀剂。 通过蚀刻ARC和掩模形成图案,以形成修剪成小于最小特征尺寸(L)的模板线。 在模板线上形成疏水间隔物,并包括L的分数宽度。将中性刷层接枝到亲水层。 DSA材料沉积在间隔物之间​​并退火以形成第一和第二材料的交替线形式的材料区域,其中与间隔物接触的第一材料包括小于线宽度的宽度。 向形成耐蚀刻第二材料的区域中加入金属。 去除第一材料和间隔物以形成DSA模板图案。