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    • 56. 发明授权
    • Catalyst and process for oxychlorination of ethylene to EDC
    • 催化剂和乙烯氧氯化为EDC的方法
    • US5382726A
    • 1995-01-17
    • US156142
    • 1993-11-22
    • George H. YoungJoseph A. CowferVictor J. Johnston
    • George H. YoungJoseph A. CowferVictor J. Johnston
    • B01J23/78B01J23/83B01J27/138C07B61/00C07C17/156C07C19/045
    • B01J23/83C07C17/156
    • The subject invention relates to catalyst compositions for oxychlorination of ethylene to produce 1,2-dichloroethane. The catalysts comprise copper chloride, at least one alkali metal, at least one rare earth metal, and at least one Group IIA metal on a high surface area support for fluid bed applications or on a high or low surface area support for fixed bed applications. The catalyst compositions are prepared by depositing the metals on a support. The use of the catalyst compositions of the invention in the oxychlorination of ethylene to EDC results in high percent ethylene efficiency, high EDC product purity and high percent HCl conversion without exhibiting catalyst stickiness. A process for oxychlorination of ethylene to produce 1,2-dichloroethane is also disclosed. The process relies on contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.
    • 本发明涉及乙烯氧氯化以产生1,2-二氯乙烷的催化剂组合物。 催化剂包括氯化铜,至少一种碱金属,至少一种稀土金属和高表面积上的至少一种IIA族金属,用于流化床应用或用于固定床应用的高表面或低表面积。 通过将金属沉积在载体上来制备催化剂组合物。 使用本发明的催化剂组合物将乙烯氧氯化成EDC导致乙烯效率高,高EDC产物纯度和高HCl HCl转化率而不显示催化剂粘性。 还公开了乙烯氧氯化生产1,2-二氯乙烷的方法。 该方法依靠将乙烯,含氧气或含氧气体和氯化氢的混合物与固定或流化催化剂组合物在反应区中接触并从反应区的流出物回收1,2-二氯乙烷。
    • 57. 发明授权
    • Catalyst and process for oxychlorination of ethylene to EDC
    • 催化剂和乙烯氧氯化为EDC的方法
    • US5292703A
    • 1994-03-08
    • US920721
    • 1992-07-28
    • George H. YoungJoseph A. CowferVictor J. Johnston
    • George H. YoungJoseph A. CowferVictor J. Johnston
    • B01J23/78B01J23/83B01J27/138C07B61/00C07C17/156C07C19/045B01J23/72B01J23/10
    • B01J23/83C07C17/156
    • The subject invention relates to catalyst compositions for oxychlorination of ethylene to produce 1,2-dichloroethane. The catalysts comprise copper chloride, at least one alkali metal, at least one rare earth metal, and at least one Group IIA metal on a high surface area support for fluid bed applications or on a high or low surface area support for fixed bed applications. The catalyst compositions are prepared by depositing the metals on a support. The use of the catalyst compositions of the invention in the oxychlorination of ethylene to EDC results in high percent ethylene efficiency, high EDC product purity and high percent HCl conversion without exhibiting catalyst stickiness. A process for oxychlorination of ethylene to produce 1,2-dichloroethane is also disclosed. The process relies on contacting a mixture of ethylene, oxygen or oxygen containing gas and hydrogen chloride with a fixed or fluidized catalyst composition in a reaction zone and recovering 1,2-dichloroethane from the effluents of the reaction zone.
    • 本发明涉及乙烯氧氯化以产生1,2-二氯乙烷的催化剂组合物。 催化剂包括氯化铜,至少一种碱金属,至少一种稀土金属和高表面积上的至少一种IIA族金属,用于流化床应用或用于固定床应用的高表面或低表面积。 通过将金属沉积在载体上来制备催化剂组合物。 使用本发明的催化剂组合物将乙烯氧氯化成EDC导致乙烯效率高,高EDC产物纯度和高HCl HCl转化率而不显示催化剂粘性。 还公开了乙烯氧氯化生产1,2-二氯乙烷的方法。 该方法依靠将乙烯,含氧气或含氧气体和氯化氢的混合物与固定或流化催化剂组合物在反应区中接触并从反应区的流出物回收1,2-二氯乙烷。