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51. 发明申请

US20060264596A1 Fluorinated organosilicon compounds and fluorochemical surfactants 失效
公开(公告)号：US20060264596A1
公开(公告)日：2006-11-23
申请号：US11435766
申请日：2006-05-18
申请人： Hiromasa Yamaguchi , Hirofumi Kishita , Koichi Yamaguchi
发明人： Hiromasa Yamaguchi , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C08G77/24
CPC分类号： C11D1/004 , B01D19/0427 , C07F7/0838 , B01D19/0409
摘要： Fluorinated organosilicon compounds having formula (1) wherein Rf is a perfluoroalkyl group containing at least one ether bond, Q is a polyether group in the form of a homopolymer chain of ethylene glycol or propylene glycol or a copolymer chain of both, R is hydrogen or alkyl, X is a divalent linking group exclusive of oxygen atom, Y is a divalent linking group, p is an integer of at least 3, and n is a number of 0

52. 发明授权

US6010815A Anti-offsetting oil 失效
标题翻译：防补油
公开(公告)号：US6010815A
公开(公告)日：2000-01-04
申请号：US178492
申请日：1998-10-26
申请人： Hiromasa Yamaguchi , Hirofumi Kishita
发明人： Hiromasa Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/24 , C08G77/34 , G03G15/20 , G03S13/20
CPC分类号： C08G77/24 , C08G77/34 , G03G15/2025 , G03G2215/2093
摘要： An anti-offsetting oil including an organopolysiloxane having the formula (1) below and containing low molecular weight organopolysiloxanes having a molecular weight of 3,000 or less in a content of 50 ppm or less. ##STR1## wherein R.sub.f 's represent a perf luoroalkyl which may contain at least one ether linkage; R's represent a monovalent hydrocarbon group; Y's represent a divalent organic group having 2 to 5 carbon atoms; a represents an integer of 1 or more and b represents an integer of 0 or more, provided that a and b satisfy 3a+3b+2=15 to 4,000; and c and d are an integer of 0 to 3. This fluid has a good wettability to silicone rubber or fluorine forming the surfaces of fixing rolls of electrophotographic copying machines, and hence can effectively prevent offset. Since it contains no low-molecular weight organopolysiloxanes, the electric-contact failure may hardly occur.
摘要翻译：一种抗偏移油，其包含下述式（1）的有机聚硅氧烷，其含有分子量为3,000以下的低分子量有机聚硅氧烷，含量为50ppm以下。其中Rf代表可含有至少一个醚键的全氟烷基; R代表一价烃基; Y代表具有2至5个碳原子的二价有机基团; a表示1以上的整数，b表示0以上的整数，条件是a和b满足3a + 3b + 2 = 15〜4,000。 c和d为0〜3的整数。这种流体对于形成电子照相复印机的定影辊的表面的硅橡胶或氟具有良好的润湿性，因此可以有效地防止偏移。由于不含有低分子量的有机聚硅氧烷，因此几乎不发生电接触失效。

53. 发明授权

US5073422A Pressure-sensitive adhesive structure 失效
标题翻译：压敏胶粘结构
公开(公告)号：US5073422A
公开(公告)日：1991-12-17
申请号：US282320
申请日：1988-12-09
申请人： Hiroki Konno , Hirofumi Kishita
发明人： Hiroki Konno , Hirofumi Kishita
IPC分类号： C08L83/08 , B32B7/06 , B32B27/00 , C08G77/24 , C08L83/07 , C09J7/02
CPC分类号： C09J7/046 , C08G77/24 , C09J7/0225 , C09J7/0246 , C09J7/025 , C09J7/045 , C09J2427/005 , C09J2483/005 , Y10T428/1429 , Y10T428/2839
摘要： A pressure-sensitive adhesive structure such as a pressure-sensitive adhesive tape, label or the like having a release agent layer, wherein said release agent layer comprises a cured fluorosilicone composition comprising:(a) a particular organopolysiloxane having in its molecule silicon-bonded alkenyl groups and at least one member selected from the group consisting of silicon-bonded fluorine-containing substituents represented respectively by Formulas (1) to (4): ##STR1## where n is an integer of 1 to 5. ##STR2## where n is an integer of 1 to 5.C.sub.m F.sub.2m+1 CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 --(3) where m is an integer of 3 to 10.C.sub.m F.sub.2m+1 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 -- (4) where m is an integer of 3 to 10.(b) an organohydrogenpolysiloxane; and(c) a catalyst, in a particular proportion. The release properties of the release agent layer show good and high stability with time, promising practical utilities over a long period of time.
摘要翻译：具有剥离剂层的压敏粘合带，标签等的压敏粘合剂结构体，其中所述脱模剂层包含固化氟硅酮组合物，其包含：（a）在其分子中具有硅键合的特定有机聚硅氧烷烯基和选自分别由式（1）至（4）表示的与硅键合的含氟取代基中的至少一个：其中n为1至5的整数。

54. 发明授权

US08420763B2 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译：含有含氟氧化烯基的聚合物组合物，包含该组合物的表面处理剂和用该试剂处理的制品
公开(公告)号：US08420763B2
公开(公告)日：2013-04-16
申请号：US12911890
申请日：2010-10-26
申请人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
发明人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C08G77/24
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.
摘要翻译：本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性，良好的耐污染性，并提供包含该表面处理剂的表面处理剂。本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

55. 发明授权

US08362186B2 Coating composition and a coating therefrom having waterdrop sliding property 有权
标题翻译：涂料组合物及其具有水滑滑性的涂层
公开(公告)号：US08362186B2
公开(公告)日：2013-01-29
申请号：US12167873
申请日：2008-07-03
申请人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
发明人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/24
CPC分类号： C08L83/12 , C09D183/12 , Y10T428/31663
摘要： A coating composition comprising a fluorine-containing silicon compound represented by the following formula (1) wherein Z is a linear or branched divalent polyorganosiloxane residue having 1 to 40 siloxane units, R is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, Q is a C2-12 divalent connecting group, a is an integer of 2 or 3, b is an integer of from 1 to 10, y is an integer of 1 to 5, and Rf is a group represented by the following formula (2) -Rf1-(Q-W-Q-Rf1)q- (2) wherein Rf1 is a perfluoropolyether residue, W is an organopolysiloxane residue having 1 to 40 siloxane units and Q is as defined above and may be the same with or different from each other, and q is an integer of from 0 to 3, and at least one solvent selected from the group consisting of alcohols, esters, ethers, ketones, and perfluoroethers. The coating prepared from the composition is oil-repellent, water-repellent and has water sliding property.
摘要翻译：一种涂料组合物，其包含由下式（1）表示的含氟硅化合物，其中Z为具有1至40个硅氧烷单元的直链或支链二价聚有机硅氧烷残基，R为具有1至4个碳原子的烷基或苯基 X为水解性基团，Q为C2-12二价连接基团，a为2或3的整数，b为1〜10的整数，y为1〜5的整数，Rf为基团由下式（2）-Rf1-（QWQ-Rf1）q-（2）表示，其中Rf1是全氟聚醚残基，W是具有1至40个硅氧烷单元的有机聚硅氧烷残基，Q如上定义并且可以相同 q为0〜3的整数，以及选自醇，酯，醚，酮，全氟醚中的至少一种溶剂。由该组合物制备的涂料具有防油，防水，具有水滑动性。

56. 发明申请

US20110251339A1 SOLVENTLESS RELEASER COMPOSITION FOR USE WITH SILICONE PRESSURE-SENSITIVE ADHESIVES AND RELEASE LINER 审中-公开
标题翻译：无溶剂释放剂组合物，与硅胶压敏粘合剂和释放衬垫一起使用
公开(公告)号：US20110251339A1
公开(公告)日：2011-10-13
申请号：US13082708
申请日：2011-04-08
申请人： Koichi YAMAGUCHI , Hirofumi Kishita
发明人： Koichi YAMAGUCHI , Hirofumi Kishita
IPC分类号： C09D183/06
CPC分类号： C09D183/04 , C08G77/12 , C08G77/20 , C08G77/24 , C08L83/04 , C08L83/08 , C08L2205/02 , C09D183/08 , C09J7/401 , C09J183/04 , C09J183/08 , C09J2427/005 , C09J2483/005
摘要： A solventless releaser composition is provided comprising (A) an organopolysiloxane containing at least two alkenyl groups and at least one monovalent fluorinated substituent group and having a fluorine content of 30-50 wt % and a viscosity of 100-2,000 mPa-s at 25° C., (B) an organohydrogenpolysiloxane containing at least three SiH groups, (C) a reaction regulator, and (D) a platinum catalyst. The composition is coated and cured to a substrate to form a release liner for use with silicone pressure-sensitive adhesives.
摘要翻译：提供了一种无溶剂释放剂组合物，其包含（A）含有至少两个烯基和至少一个一价氟化取代基并且在25℃下氟含量为30-50重量％和粘度为100-2,000mPa·s的有机聚硅氧烷（B）含有至少三个SiH基团的有机氢聚硅氧烷，（C）反应调节剂和（D）铂催化剂。将组合物涂布并固化至基底以形成用于硅氧烷压敏粘合剂的剥离衬垫。

57. 发明申请

US20110098402A1 FLUOROOXYALKYLENE GROUP-CONTAINING POLYMER COMPOSITION, A SURFACE TREATMENT AGENT COMPRISING THE SAME AND AN ARTICLE TREATED WITH THE AGENT 有权
标题翻译：包含含氟聚合物的含聚合物组合物，包含该聚合物组合物的表面处理剂和与该试剂一起处理的物品
公开(公告)号：US20110098402A1
公开(公告)日：2011-04-28
申请号：US12911890
申请日：2010-10-26
申请人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
发明人： Yuji Yamane , Noriyuki Koike , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C09D127/12
CPC分类号： G02B1/14 , C08G65/007 , C08G65/336 , C08G2650/48 , C08L71/02 , C09D5/165 , C09D171/02 , G02B1/105 , G02B27/0006 , C08L2666/22
摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.
摘要翻译：本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性，良好的耐污染性，并提供包含该表面处理剂的表面处理剂。本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

58. 发明授权

US07794843B2 Fluorine-containing organopolysiloxane, a surface treatment composition comprising the same and an article treated with the composition 有权
标题翻译：含氟有机聚硅氧烷，包含其的表面处理组合物和用该组合物处理的制品
公开(公告)号：US07794843B2
公开(公告)日：2010-09-14
申请号：US11643988
申请日：2006-12-22
申请人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
发明人： Yuji Yamane , Noriyuki Koike , Koichi Yamaguchi , Hirofumi Kishita
IPC分类号： C08G77/46
CPC分类号： C08G77/385 , C07F7/21 , C08G77/50 , Y10T428/31663
摘要： An organopolysiloxane represented by the following general formula (A), (B) or(C) SinR12n+2On−1 (A) SinR12nOn (B) SinR12n+2R2kOn−k (C) wherein R1 may be the same with or different from each other and is a hydrogen atom or a monovalent organic group, R2 is an alkylene group having 2 to 6 carbon atoms, n is an integer of from 2 to 40 and k is an integer of 1 to 3, characterized in that at least two R1's are represented by the following formula (i): wherein X is a hydrolyzable group, R3 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, y is an integer of from 1 to 5 and a is 2 or 3; and one SiOSi bond is replaced with a bond represented by the following formula (iii): SiQRf2QSi (iii) wherein Rf1 is a monovalent group containing a perfluoroether residue, Rf2 is a divalent group containing a perfluoroether residue, and Q is a divalent organic group.
摘要翻译：由以下通式（A），（B）或（C）表示的有机聚硅氧烷SinR12n + 2On-1（A）SinR12nOn（B）SinR12n + 2R2kOn-k（C）其中R1可以相同或不同另一个是氢原子或一价有机基团，R 2是具有2至6个碳原子的亚烷基，n是2至40的整数，k是1至3的整数，其特征在于，至少两个R 1的由下式（i）表示：其中X是可水解基团，R 3是具有1至4个碳原子的烷基或苯基，y是1至5的整数，a是2或3; 并且一个SiOSi键用下式（ⅲ）表示的键代替：SiQRf2QSi（ⅲ）其中Rf1是含有全氟醚残基的一价基团，Rf2是含有全氟醚残基的二价基团，Q是二价有机基团。

59. 发明申请

US20100147191A1 FLUORINE-CONTAINING ACRYLATE 有权
标题翻译：含氟丙烯酸酯
公开(公告)号：US20100147191A1
公开(公告)日：2010-06-17
申请号：US12619135
申请日：2009-11-16
申请人： Yasunori SAKANO , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori SAKANO , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C09D4/00 , C07F7/10
CPC分类号： C08G77/045 , C07F7/21 , C08F220/22 , C08F220/24 , C08F230/08 , C08G18/61 , C08G18/8116 , C08G77/38 , C08G77/388 , C09D175/16
摘要： The present invention is a fluorine-containing acrylate or alpha-substituted, fluorine-containing acrylate, represented by the following formula (1): wherein a is an integer of from 1 to 4 and b is an integer of from 1 to 4, provided that a total of a and b is 3, 4, or 5;R1 is a group represented by the following formula (2): —(C4H8O)d(C3H6O)e(C2H4O)f(CH2O)g— (2) wherein d, e, f, and g are, independently of each other, an integer of from 0 to 4, provided that a molecular weight of R1 is in a range of 30 to 300, andthese repeating units may be sequenced at random;R2 is an acryl group- or alpha-substituted acryl group-containing group having 4 to 20 carbon atoms and represented by the following formula (3): wherein R3 is, independently of each other, a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group,R4 is a divalent or trivalent linking moiety having 1 to 18 carbon atoms, optionally having an ether bond and/or an ester bond, andn is 1 or 2;Rf is a perfluoropolyether residue represented by the following formula (4): wherein j, k, l, and m are, independently of each other, an integer of from 0 to 50, provided that a molecular weight of Rf is in a range of 200 to 6000,X is a fluorine atom or a trifluoromethyl group, andthese repeating units may be sequenced at random;Z is a divalent organic group; andc is 0 or 1.
摘要翻译：本发明是由下式（1）表示的含氟丙烯酸酯或α-取代的含氟丙烯酸酯，其中a为1〜4的整数，b为1〜4的整数，总共a和b为3,4或5; R1是由下式（2）表示的基团： - （C4H8O）d（C3H6O）e（C2H4O）f（CH2O）g-（2）其中d，e，f和g彼此独立地是如果R1的分子量在30〜300的范围内，则0〜4的整数，这些重复单元可以随机排列; R2是具有4〜20个碳原子的丙烯酰基或α-取代的含丙烯酰基的基团，由下式（3）表示：其中R 3彼此独立地为氢原子，氟原子，甲基基团或三氟甲基，R 4是具有1至18个碳原子的二价或三价连接部分，任选具有醚键和/或酯键，n为1或2; Rf是由下式（4）表示的全氟聚醚残基：其中j，k，l和m彼此独立地为0至50的整数，条件是Rf的分子量在 200〜6000，X为氟原子或三氟甲基，这些重复单元可以随机排列; Z是二价有机基团; c为0或1。

60. 发明授权

US07488839B2 Fluorinated organosilicon compounds and fluorochemical surfactants 失效
标题翻译：氟化有机硅化合物和含氟表面活性剂
公开(公告)号：US07488839B2
公开(公告)日：2009-02-10
申请号：US11435766
申请日：2006-05-18
申请人： Hiromasa Yamaguchi , Hirofumi Kishita , Koichi Yamaguchi
发明人： Hiromasa Yamaguchi , Hirofumi Kishita , Koichi Yamaguchi
IPC分类号： C07F7/08
CPC分类号： C11D1/004 , B01D19/0427 , C07F7/0838 , B01D19/0409
摘要： Fluorinated organosilicon compounds having formula (1) wherein Rf is a perfluoroalkyl group containing at least one ether bond, Q is a polyether group in the form of a homopolymer chain of ethylene glycol or propylene glycol or a copolymer chain of both, R is hydrogen or alkyl, X is a divalent linking group exclusive of oxygen atom, Y is a divalent linking group, p is an integer of at least 3, and n is a number of 0
摘要翻译：具有式（1）的氟化有机硅化合物，其中Rf是含有至少一个醚键的全氟烷基，Q是乙二醇或丙二醇或两者的共聚物链的均聚物链形式的聚醚基，R是氢或烷基，X是不含氧原子的二价连接基团，Y是二价连接基团，p是至少3的整数，n是0

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