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51. 发明授权

US06835687B2 Method for producing double metal cyanide (DMC) catalysts 有权
标题翻译：双金属氰化物（DMC）催化剂的制备方法
公开(公告)号：US06835687B2
公开(公告)日：2004-12-28
申请号：US10257706
申请日：2003-03-05
申请人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Thorsten Fechtel , Matthias Ruhland , Jürgen Scholz , Franz Föhles , Ulrich Esser
发明人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Thorsten Fechtel , Matthias Ruhland , Jürgen Scholz , Franz Föhles , Ulrich Esser
IPC分类号： B01J2726
CPC分类号： C08G65/2663 , B01J27/26
摘要： The invention provides an improved process for the preparation of double metal cyanide (DMC) catalysts for the preparation of polyether polyols by polyaddition of alkylene oxides on to starter compounds containing active hydrogen atoms, in which aqueous solutions of a metal salt and a metal cyanide salt are first reacted in the presence of an organic complexing ligand and optionally one or more further complex-forming components to form a DMC catalyst dispersion, this dispersion is then filtered, the filter cake is subsequently washed with one or more aqueous or non-aqueous solutions of the organic complexing ligand and optionally one or more further complex-forming components by a filter cake washing and the washed filter cake is finally dried, after an optional pressing out or mechanical removal of moisture.
摘要翻译：本发明提供了一种改进的制备双金属氰化物（DMC）催化剂的方法，用于通过将环氧烷烃加成到含有活性氢原子的起始化合物上制备聚醚多元醇，其中金属盐和金属氰化物盐的水溶液首先在有机络合配体和任选的一种或多种其它形成复合物的组分的存在下反应以形成DMC催化剂分散体，然后过滤该分散体，随后用一种或多种水或非水溶液洗涤滤饼的有机络合配体和任选的一种或多种通过滤饼洗涤的复合物形成组分，并且在任选的压出或机械除去水分后，最后干燥洗涤过的滤饼。

52. 发明授权

US06818587B2 Double-metal cyanide catalysts for preparing polyether polyols 失效
标题翻译：用于制备聚醚多元醇的双金属氰化物催化剂
公开(公告)号：US06818587B2
公开(公告)日：2004-11-16
申请号：US10229882
申请日：2002-08-28
申请人： Walter Schäfer , Jörg Hofmann , Pieter Ooms
发明人： Walter Schäfer , Jörg Hofmann , Pieter Ooms
IPC分类号： B01J2726
CPC分类号： B01J31/1805 , B01J21/08 , B01J27/26 , B01J29/049 , B01J31/2208 , B01J31/223 , B01J31/26 , B01J31/28 , B01J35/1019 , B01J2231/10 , B01J2531/0238 , B01J2531/26 , B01J2531/62 , B01J2531/827 , B01J2531/84 , B01J2531/845 , C08G65/2663
摘要： The invention relates to double-metal cyanide (DMC) catalysts for preparing polyether polyols by the polyaddition of alkylene oxides on to starter compounds containing active hydrogen atoms, wherein the DMC catalysts are composed of: a) at least one DMC compound; b) at least one organic complexing ligand which is not a cyclic polyol; and c) at least one cyclic polyol. The DMC catalysts of the present invention have increased activity compared to known catalyst.
摘要翻译：本发明涉及通过将环氧烷烃加成到含有活性氢原子的起始化合物上制备聚醚多元醇的双金属氰化物（DMC）催化剂，其中DMC催化剂由以下组成：a）至少一种DMC化合物; b）至少一种不是环状多元醇的有机络合配体; 和c）至少一种环状多元醇。与已知的催化剂相比，本发明的DMC催化剂具有增加的活性。

53. 发明授权

US06624286B2 Double-metal cyanide catalysts containing polyester for preparing polyether polyols 失效
标题翻译：含有制备聚醚多元醇的聚酯的双金属氰化物催化剂
公开(公告)号：US06624286B2
公开(公告)日：2003-09-23
申请号：US10006065
申请日：2001-12-05
申请人： Jörg Hofmann , Pramod Gupta , Robert-Joseph Kumpf , Pieter Ooms , Walter Schäfer
发明人： Jörg Hofmann , Pramod Gupta , Robert-Joseph Kumpf , Pieter Ooms , Walter Schäfer
IPC分类号： C08G6504
CPC分类号： C08G65/2663 , B01J27/26
摘要： The invention relates to new improved double-metal cyanide (DMC) catalysts for the preparation of polyether-polyols by polyaddition of alkylene oxides on to starter compounds containing active hydrogen atoms, the catalyst comprising a double-metal cyanide compound, an organic complexing ligand and 5-80 wt. %, based on the amount of catalyst, of a polyester. For the preparation of polyether-polyols, the new improved catalysts have significantly shortened induction times and at the same time a greatly increased activity.
摘要翻译：本发明涉及新的改进的双金属氰化物（DMC）催化剂，用于通过将环氧烷烃加成到含有活性氢原子的起始化合物上制备聚醚多元醇，催化剂包含双金属氰化物化合物，有机络合配体和 5-80重量％基于催化剂量的聚酯。对于聚醚多元醇的制备，新的改进的催化剂具有显着缩短的诱导时间，同时活性大大增加。

54. 发明授权

US06569981B1 Crystallizing polyether polyols, a method for producing them and use of the same 有权
标题翻译：结晶聚醚多元醇，其制备方法和用途
公开(公告)号：US06569981B1
公开(公告)日：2003-05-27
申请号：US10030489
申请日：2001-10-25
申请人： Walter Schäfer , Jörg Hofmann , Pramod Gupta , Pieter Ooms
发明人： Walter Schäfer , Jörg Hofmann , Pramod Gupta , Pieter Ooms
IPC分类号： C08G1848
CPC分类号： C08G65/269 , C08G18/48 , C08G2101/00 , C08G2250/00
摘要： This invention relates to crystallizing polyether polyols which can be produced firstly by the reaction of propylene oxide and polyhydroxy compounds in the presence of an alkoxy compound which contains zinc and/or aluminium atoms to form a crystallizing polyether polyol with an average molecular weight Mn from 500 to 5000, followed by the further reaction of the crystallizing polyether polyol which is thus obtained with 10 to 90% by weight, with respect to the amount of crystallizing polyol, of an epoxide in the presence of a catalyst which does not polymerize propylene oxide stereospecifically, to form a crystallizing polyether polyol with an average molecular weight Mn from 1000 to 20,000. The invention further relates to a method for the production thereof and to the use thereof for the production of polyurethane materials, particularly polyurethane foams, polyurethane elastomers and polyurethane coatings.
摘要翻译：本发明涉及结晶聚醚多元醇，其可首先通过环氧丙烷和多羟基化合物在含有锌和/或铝原子的烷氧基化合物的存在下反应生成平均分子量Mn为500的结晶聚醚多元醇至5000，然后在不使立构特异性环氧丙烷聚合的催化剂存在下，将由此得到的结晶性聚醚多元醇进一步反应，其结晶多元醇相对于结晶多元醇的量为10〜90重量％形成平均分子量Mn为1000〜20,000的结晶性聚醚多元醇。本发明还涉及其生产方法及其用于生产聚氨酯材料，特别是聚氨酯泡沫，聚氨酯弹性体和聚氨酯涂料的用途。

55. 发明授权

US06492565B2 Process for the preparation of polyether polyols 失效
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US06492565B2
公开(公告)日：2002-12-10
申请号：US09827655
申请日：2001-04-06
申请人： Uwe Denninger , Jörg Hofmann , Pramod Gupta
发明人： Uwe Denninger , Jörg Hofmann , Pramod Gupta
IPC分类号： C07C4103
CPC分类号： C08G65/2654 , B01J31/0211 , B01J31/0227 , B01J31/0228 , B01J31/0252 , B01J31/0255 , B01J31/0257 , B01J2231/48 , C07F5/069
摘要： The present invention relates to a process for the preparation of polyether polyols by the reaction of alkylene oxides and compounds containing active hydrogens, in the presence of specific Lewis acid metal compounds as catalysts, novel bis(perfluoroalkylsulfonic acid) compounds of Group 13 of the Periodic Table of the Elements, and to a process for the preparation thereof and the use thereof as catalysts for ring-opening polymerization of cyclic ethers.
摘要翻译：本发明涉及在特定的路易斯酸金属化合物作为催化剂的存在下，通过环氧烷和含有活性氢的化合物的反应制备聚醚多元醇的方法，所述周期的第13族的新的双（全氟烷基磺酸）化合物表格，以及其制备方法及其作为环醚开环聚合的催化剂的用途。

56. 发明授权

US06482993B1 Method for producing long chain polyether polyols without reprocessing 有权
标题翻译：不再加工生产长链聚醚多元醇的方法
公开(公告)号：US06482993B1
公开(公告)日：2002-11-19
申请号：US09673583
申请日：2000-10-18
申请人： Jörg Hofmann , Pramod Gupta
发明人： Jörg Hofmann , Pramod Gupta
IPC分类号： C07C4311
CPC分类号： B01J31/0227 , B01J2231/48 , C08G65/2642 , C08G65/266
摘要： This invention relates to a process for the production of long-chain polyether polyols without working up, in which oligomeric, alkoxylated starter compounds having molecular weights of 200 to 1000 are first obtained by catalysis with perfluoroalkylsulfonates of the metals of group III A of the periodic system of elements (in accordance with the IUPAC convention of 1970) from low molecular weight starters by reaction with alkylene oxides at reaction temperatures of 80 to 200° C. and catalyst concentrations of 5 to 200 ppm, which oligomeric, alkoxylated starter compounds are then converted without working up and removal of the catalyst by means of highly active DMC catalysts at a catalyst concentration of 30 ppm or below, relative to the quantity of polyether polyol to be produced, by reaction with alkylene oxides into higher molecular weight, long-chain polyether polyols.
摘要翻译：本发明涉及一种不加工的长链聚醚多元醇的制备方法，其中分子量为200〜1000的低聚烷氧基化起始化合物首先通过周期性的IIIA族金属的全氟烷基磺酸盐的催化而得到在低分子量起始化合物的反应温度为80〜200℃，催化剂浓度为5〜200ppm的条件下，通过与环氧烷烃反应，从低分子量起始剂中分离出元素系统（按照IUPAC惯例）通过高活性DMC催化剂处理和除去催化剂，催化剂浓度为30ppm或更低，相对于待生产的聚醚多元醇的量，通过与烯化氧反应成较高分子量的长链聚醚多元醇。

57. 发明授权

US09120894B2 Method for producing polyether polyols 有权
标题翻译：聚醚多元醇的制备方法
公开(公告)号：US09120894B2
公开(公告)日：2015-09-01
申请号：US14131977
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G85/00 , C08G65/00 , C08G65/26 , C08G64/34
CPC分类号： C08G65/2663 , C08G64/34 , C08G65/2603
摘要： The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, wherein (α) the H-functional starter substance or a mixture of at least two H-functional starter substances is initially introduced into the reaction vessel, (β) for the activation, a part amount (based on the total amount of the amount of alkylene oxides employed in steps (β) and (γ)) of one or more alkylene oxides is added to the mixture resulting from step (α), it also being possible for step (β) to be carried out several times for the activation, (γ) one or more alkylene oxides and carbon dioxide are metered continuously into the mixture resulting from step (β) (“copolymerization”), the alkylene oxides employed for the copolymerization being identical to or different from the alkylene oxides employed in step (β), characterized in that in step (γ) the carbon dioxide is passed into the mixture by (i) gassing the reaction mixture in the reactor from the bottom, (ii) using a hollow shaft stirrer, (iii) a combination of the metering operations according to (i) and (ii), and/or (iv) gassing over the surface of the liquid by using stirrer units configured in several stages.
摘要翻译：本发明涉及在双金属氰化物催化剂存在下由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳制备聚醚碳酸酯多元醇的方法，其中（α）H官能团起始物质或至少两种H功能性起始物质的混合物最初被引入反应容器（（bgr））中用于活化，部分量（基于步骤（bgr）中使用的环氧烷烃的总量（γ））和（γ））加入到由步骤（α）得到的混合物中，对于活化，（γ）一个或多个步骤（＆bgr）可以进行几次，更多的环氧烷和二氧化碳被连续地计量到由步骤（（bgr））（“共聚”）得到的混合物中，用于共聚的烯化氧与步骤（bgr）中使用的环氧烷烃相同或不同，其特征在于在步骤（γ）中，二氧化碳通过以下步骤进入混合物：（i）从底部将反应混合物放入反应器中，（ii）使用中空轴搅拌器，（iii）根据至（i）和（ii），和/或（iv）通过使用在几个阶段中配置的搅拌器单元在液体的表面上放气。

58. 发明申请

US20140228537A1 METHOD FOR ACTIVATING DOUBLE METAL CYANIDE CATALYSTS FOR PRODUCING POLYETHER POLYOLS 有权
标题翻译：用于生产聚醚多元醇的双金属氰化物催化剂的活化方法
公开(公告)号：US20140228537A1
公开(公告)日：2014-08-14
申请号：US14232015
申请日：2012-07-17
申请人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
发明人： Thomas Ernst Müller , Christoph Gürtler , Matthias Wohak , Jörg Hofmann , Muhammad Afzal Subhani , Maurice Cosemans , Walter Leitner
IPC分类号： C08G64/32
CPC分类号： C08G64/323 , C08G64/34 , C08G65/2603 , C08G65/2663
摘要： The present invention relates to a process for the activation of double metal cyanide (DMC) catalysts and to a process for the preparation of polyethercarbonate polyols from one or more H-functional starter compounds, one or more alkylene oxides and carbon dioxide in the presence of a double metal cyanide catalyst, characterized in that (α) (α1) the DMC catalyst and one or more H-functional starter compounds are placed in a reactor, (α2) an inert gas, an inert gas/carbon dioxide mixture or carbon dioxide is passed through the reactor at a temperature of 50 to 200° C. and at the same time a reduced pressure (absolute) of 10 mbar to 800 mbar is established in the reactor by removal of the inert gas or carbon dioxide, (β) under an atmosphere of inert gas/carbon dioxide mixture or under a pure carbon dioxide atmosphere, alkylene oxide is added to the mixture from step (α) at temperatures of 50 to 200° C., and (γ) one or more alkylene oxides and carbon dioxide are metered into the mixture resulting from step (β).
摘要翻译：本发明涉及一种活化双金属氰化物（DMC）催化剂的方法，以及一种由一种或多种H官能起始化合物，一种或多种环氧烷和二氧化碳在存在下制备聚醚碳酸酯多元醇的方法一种双金属氰化物催化剂，其特征在于将（α）（α1）DMC催化剂和一种或多种H官能起始化合物置于反应器中，（α2）惰性气体，惰性气体/二氧化碳混合物或二氧化碳在50至200℃的温度下通过反应器，同时通过除去惰性气体或二氧化碳，在反应器中建立10毫巴至800毫巴的减压（绝对）（绝对）。）在惰性气体/二氧化碳混合物的气氛下或在纯二氧化碳气氛下，在步骤（α）的混合物中，在50〜200℃的温度下加入环氧烷，（γ）一种或多种环氧烷烃并将二氧化碳计量加入由（步骤（bgr））产生的混合物。

59. 发明授权

US06878661B1 Bimetallic-cyanide catalysts used for preparing polyether polyols 失效
标题翻译：用于制备聚醚多元醇的双金属氰化物催化剂
公开(公告)号：US06878661B1
公开(公告)日：2005-04-12
申请号：US09744357
申请日：1999-07-20
申请人： Pieter Ooms , Jörg Hofmann , Pramod Gupta , Walter Schäfer
发明人： Pieter Ooms , Jörg Hofmann , Pramod Gupta , Walter Schäfer
IPC分类号： C08G65/10 , C08G65/26 , B01J31/00
CPC分类号： B01J27/26 , C08G65/10 , C08G65/2663
摘要： The invention relates to novel double metal cyanide (DMC) catalysts for the preparation of polyether polyols by polyaddition of alkylene oxides to starter compounds containing active hydrogen atoms, wherein the catalyst contains a) double metal cyanide compounds, b) organic complex ligands other than c), and c) complex ligands formed by introduction of a glycidyl ether into the catalyst. The catalysts according to the invention have greatly increased activity in the preparation of polyether polyols.
摘要翻译：本发明涉及用于制备聚醚多元醇的新型双金属氰化物（DMC）催化剂，其通过将环氧烷加成到含有活性氢原子的起始化合物中，其中催化剂含有a）双金属氰化物化合物，b）除c以外的有机络合物配体），和c）通过将缩水甘油醚引入催化剂而形成的复合配位体。根据本发明的催化剂在制备聚醚多元醇中的活性大大增加。

60. 发明授权

US06858655B1 High-resilient polyurethane foams produced from polyether polyols 有权
标题翻译：由聚醚多元醇生产的高弹性聚氨酯泡沫
公开(公告)号：US06858655B1
公开(公告)日：2005-02-22
申请号：US10018332
申请日：2000-06-06
申请人： Jörg Hofmann , Pramod Gupta , Manfred Dietrich , Hansjürgen Rabe , Jürgen Grönen , Pieter Ooms
发明人： Jörg Hofmann , Pramod Gupta , Manfred Dietrich , Hansjürgen Rabe , Jürgen Grönen , Pieter Ooms
IPC分类号： C08G18/48 , C08G65/26 , C08G101/00 , C08G18/28
CPC分类号： C08G65/2663 , C08G18/4845 , C08G18/485 , C08G18/4866 , C08G2101/0008 , C08G2101/0083
摘要： Flexible polyurethane foams are produced from a polyisocyanate and a polyether polyol which has been alkoxylated in the presence of a double metal cyanide catalyst and that has at least one ethylene oxide-propylene oxide mixed block.
摘要翻译：柔性聚氨酯泡沫由多异氰酸酯和聚醚多元醇生产，所述多异氰酸酯和聚醚多元醇在双金属氰化物催化剂存在下被烷氧基化，并且具有至少一个环氧乙烷 - 环氧丙烷混合嵌段。

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