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51. 发明授权

US5162358A Halogenoalkyl-azolyl derivatives 失效
标题翻译：异恶唑烷基衍生物
公开(公告)号：US5162358A
公开(公告)日：1992-11-10
申请号：US737619
申请日：1991-07-30
申请人： Manfred Jautelat , Jurgen Scherkenbeck , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler , Harl-Heinz Kuck
发明人： Manfred Jautelat , Jurgen Scherkenbeck , Klaus Stroech , Stefan Dutzmann , Heinz-Wilhelm Dehne , Gerd Hanssler , Harl-Heinz Kuck
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： New halogenoalkyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl or optionally substituted cycloalkyl,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen,n represents 0 or 1 andY represents nitrogen or a CH group,and acid addition salts and metal salt complexes thereofare very effective for combating undesired microorganisms in plant protection and in the preservation of materials.
摘要翻译：式（I）的新的卤代烷基 - 唑基衍生物，其中R 1表示任选取代的烷基，任选取代的烯基或任选取代的环烷基，R 2表示氢，烷基，烯基，酰基或芳烷基，X 1表示卤素， n表示0或1，Y表示氮或CH基，其酸加成盐和金属盐络合物对于防止植物保护和材料保存中的不希望的微生物非常有效。

52. 发明授权

US5143932A Microbicidal halogenoallyl-azolyl derivatives 失效
标题翻译：微生物卤代烷基衍生物
公开(公告)号：US5143932A
公开(公告)日：1992-09-01
申请号：US645951
申请日：1991-01-25
申请人： Manfred Jautelat , Klaus Stroech , Gerd Hanssler , Stefan Dutzmann , Karl-Heinz Kuck , Wilhelm Brandes
发明人： Manfred Jautelat , Klaus Stroech , Gerd Hanssler , Stefan Dutzmann , Karl-Heinz Kuck , Wilhelm Brandes
IPC分类号： A01N43/50 , A01N43/653 , B27K3/34 , C07D233/60 , C07D233/64 , C07D249/08 , C07D521/00
CPC分类号： C07D249/08 , A01N43/50 , A01N43/653 , C07D231/12 , C07D233/56
摘要： Microbicidal halogenoallyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents a radical of the formula ##STR2## R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl, X.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogen andY represents nitrogen or a CH group,and addition products thereof with acids and metal salts.
摘要翻译：式（I）的杀微生物卤代烯丙基 - 唑基衍生物，其中R 1表示下式的基团：其中R 1表示下式的基团：

53. 发明授权

US5122532A Microbicidal halogenoallyl-azolyl derivatives 失效
标题翻译：微生物卤代烷基衍生物
公开(公告)号：US5122532A
公开(公告)日：1992-06-16
申请号：US645936
申请日：1991-01-25
申请人： Manfred Jautelat , Klaus Stroech , Gerd Hanssler , Stefan Dutzmann , Karl-Heinz Kuck , Wilhelm Brandes
发明人： Manfred Jautelat , Klaus Stroech , Gerd Hanssler , Stefan Dutzmann , Karl-Heinz Kuck , Wilhelm Brandes
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D233/64 , C07D249/08 , C07D401/06 , C07D403/06 , C07D405/06 , C07D409/06 , C07D521/00
CPC分类号： C07D249/08 , A01N43/50 , A01N43/653 , C07D231/12 , C07D233/56
摘要： A microbicidal halogenoallyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents halogenoallyl, propargyl, substituted cycloalkyl or optionally substituted heteroaryl, or represents a radical of the formula ##STR2## where R.sup.3 represents hydrogen, halogen, or phenyl which is optionally substituted by halogen, phenoxy which is optionally substituted by halogen or phenoxymethyl which is optionally substituted by halogen,R.sup.4 represents hydrogen or halogen, andR.sup.5 represents iso-propyl, or phenyl which is optionally substituted by halogen or phenoxy which is optionally substituted by halogen or phenoxy which is optionally substituted by halogen,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogen andY represents nitrogen or a CH group,and addition products thereof with acids and metal salts.
摘要翻译：式（I）的杀微生物卤代烯丙基 - 唑基衍生物，其中R 1表示卤代烯丙基，炔丙基，取代的环烷基或任选取代的杂芳基，或表示下式的基团，其中R 3表示氢，卤素或苯基，任选被卤素取代的苯氧基或任选被卤素取代的苯氧基甲基，R 4代表氢或卤素，R 5代表异丙基，或任选被卤素或苯氧基取代的苯基，任选被卤素或苯氧基任意地被卤素或苯氧基，其任选被卤素取代，R 2表示氢，烷基，烯基，酰基或芳烷基，X 1表示卤素，X 2表示卤素，X 3表示氢或卤素，Y表示氮或CH基团，和金属盐。

54. 发明授权

US4871484A Process for the preparation of 2,2-bis-chloro-methylalkanecarboxylic acid chlorides 失效
标题翻译：制备2,2-双氯 - 甲基链烷羧酸氯化物的方法
公开(公告)号：US4871484A
公开(公告)日：1989-10-03
申请号：US50993
申请日：1987-05-15
申请人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
发明人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
IPC分类号： C07C53/50 , C07C51/00 , C07C51/58 , C07C51/60 , C07C51/62 , C07C67/00
CPC分类号： C07C51/58
摘要： A process for the preparation of a 2,2-bis-chloro-methyl-alkanecarboxylic acid of the formula ##STR1## in which R is hydrogen, alkyl, cycloalkyl or optionally substituted phenyl,which comprises reacting an oxetane-3-carboxylic acid of the formula ##STR2## or a salt thereof, with an inorganic acid chloride at a temperature between 20.degree. C. and the boiling point of the reaction mixture. The products are known intermediates for fungicides and herbicides.
摘要翻译：一种制备式“IMAGE”的2,2-双氯 - 甲基 - 链烷羧酸的方法，其中R是氢，烷基，环烷基或任选取代的苯基，其中包括使氧杂环丁烷-3-羧酸式中的“IMAGE”或其盐与无机酰氯在20℃和反应混合物的沸点之间。该产品是用于杀真菌剂和除草剂的已知中间体。

55. 发明授权

US4824975A Process for the preparation of oxetane-3-carboxylic acids 失效
标题翻译：氧杂环丁烷-3-羧酸的制备方法
公开(公告)号：US4824975A
公开(公告)日：1989-04-25
申请号：US49749
申请日：1987-05-13
申请人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
发明人： Helmut Fiege , Manfred Jautelat , Dieter Arlt
IPC分类号： C07B61/00 , B01J23/00 , B01J23/42 , B01J23/44 , C07C53/50 , C07D305/08
CPC分类号： C07C53/50 , C07D305/08
摘要： A process for the preparation of an oxetane-3-carboxylic acid of the formula ##STR1## in which R represents hydrogen, alkyl, cycloalkyl or optionally substitute phenyl, comprising reacting a 3-hydroxymethyl-oxetane of the formula ##STR2## with oxygen in an aqueous alkaline medium at a temperature between about 0.degree. C. and the boiling point of the reaction mixture on a palladium and/or platinum catalyst. The product is an intermediate for known fungicides and herbicides.
摘要翻译：制备式“IMAGE”的氧杂环丁烷-3-羧酸的方法，其中R表示氢，烷基，环烷基或任选取代的苯基，包括使式“IMAGE”的3-羟甲基 - 氧杂环丁烷与氧反应在约0℃的温度和钯和/或铂催化剂上的反应混合物的沸点之间的碱性水溶液。该产品是已知杀真菌剂和除草剂的中间体。

56. 发明授权

US4681952A Intermediates in the preparation of 2,2-dimethyl-3-aryl-cyclopropanecarboxylic acids and esters 失效
标题翻译：中间体制备2,2-二甲基-3-芳基 - 环丙烷羧酸和酯
公开(公告)号：US4681952A
公开(公告)日：1987-07-21
申请号：US669182
申请日：1984-11-07
申请人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
发明人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
IPC分类号： C07C69/753 , C07C45/00 , C07C45/63 , C07C45/65 , C07C45/68 , C07C49/223 , C07C49/587 , C07C49/657 , C07C49/683 , C07C49/697 , C07C49/753 , C07C51/00 , C07C61/39 , C07C61/40 , C07C67/00 , C07C201/00 , C07C205/55 , C07C227/00 , C07C227/02 , C07C229/46 , C07C253/00 , C07C255/56 , C07C255/57 , C07C313/00 , C07C315/04 , C07C317/24 , C07C317/44 , C07C319/20 , C07C323/62 , C07D307/46 , C07D307/54 , C07D307/56 , C07D307/68 , C07D307/70 , C07D333/24 , C07D333/28 , C07D333/38 , C07D333/42 , C07F7/08 , C07D307/02 , C07D333/16
CPC分类号： C07D307/56 , C07C45/63 , C07C45/65 , C07C45/68 , C07C49/223 , C07C49/657 , C07C49/683 , C07C49/697 , C07C49/753 , C07C51/00 , C07D307/68 , C07D307/70 , C07D333/28 , C07D333/38 , C07D333/42
摘要： A process for the preparation of 2,2-dimethyl-3-arylcyclopropanecarboxylic acid or ester of the formula ##STR1## in which Ar is naphthyl or the radical ##STR2## R.sup.1 is H or C.sub.1 -C.sub.4 -alkyl, Z is oxygen, sulphur, or 1,2-ethenediyl, andR.sup.2 represents hydrogen, halogen, cyano, nitro or trialkylsilyl or a radical, which is optionally substituted by halogen, from the series comprising alkyl, cycloalkyl, alkenyl, alkoxy, alkylenedioxy, alkylthio, alkylsulphinyl, alkylsulphonyl, dialkylamino, phenyl and phenoxy,comprising reacting a 1-aryl-1-halogeno-2,2-dimethyl-3-butanone of the formula ##STR3## in which X.sup.1 is chlorine or bromine, with a base in the presence of a diluent at a temperature between about -20.degree. and +150.degree. C., thereby to form a 2,2-dimethyl-3-arylcyclobutanone of the formula ##STR4## and reacting such 2,2-dimethyl-3-arylcyclobutanone with chlorine or bromine in the presence of an inert diluent at a temperature between about -30.degree. and +50.degree. C., reacting such 2,2-dimethyl-3-arylcyclobutanone with chlorine or bromine in the presence of an inert diluent at a temperature between about -30.degree. and +150.degree. C., thereby to form a 2,2-dimethyl-3-aryl-4-halogenocyclobutanone of the formula ##STR5## and reacting such 2,2-dimethyl-3-aryl-4-halogenocyclobutanone with an alkali metal alcoholate in the presence of an organic solvent or with an alkali metal or alkaline earth metal hydroxide or carbonate in the presence of water and an organic solvent, at a temperature between about -20.degree. and +100.degree. C. The various intermediates are new and the end product is a known intermediate for known insecticides.
摘要翻译：制备2,2-二甲基-3-芳基环丙烷羧酸或其中Ar为萘基或R 1为R 1的式“IMAGE”的酯的方法为H或C 1 -C 4 - 烷基，Z为氧，硫或1,2-乙烯二基，R 2代表氢，卤素，氰基，硝基或三烷基甲硅烷基或任选被卤素取代的基团，包括烷基，环烷基，烯基，烷氧基，亚烷基二氧基，烷硫基，烷基亚磺酰基，烷基磺酰基，二烷基氨基，苯基和苯氧基，包括使X1为氯或溴的式“IMAGE”的1-芳基-1-卤代-2,2-二甲基-3-丁酮与碱在稀释剂存在下反应在约-20℃至+ 150℃之间的温度下，由此形成下式的2,2-二甲基-3-芳基环丁酮，并使这种2,2-二甲基-3-芳基环丁酮与氯或溴反应在惰性稀释剂存在下，在-30℃〜+ 50℃的温度下，使这样的2,2-二甲基-3-芳基氯丁酮与氯或溴在惰性稀释剂存在下，在约-30℃至+ 150℃之间的温度下反应，由此形成下式的“2,2-二甲基-3-芳基-4-卤代环丁酮” 并在有机溶剂或碱金属或碱土金属氢氧化物或碳酸盐存在下，在水和有机溶剂的存在下，使这种2,2-二甲基-3-芳基-4-卤代环丁酮与碱金属醇盐反应，在约-20℃至+ 100℃之间的温度下。各种中间体是新的，最终产物是已知杀虫剂的已知中间体。

57. 发明授权

US4663465A Preparation of 2,2-dimethyl-3-aryl-cyclopropanecarboxylic acid and esters and new intermediates therefor 失效
标题翻译：制备2,2-二甲基-3-芳基 - 环丙烷羧酸和酯及其新的中间体
公开(公告)号：US4663465A
公开(公告)日：1987-05-05
申请号：US805502
申请日：1985-12-04
申请人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
发明人： Reinhard Lantzsch , Dieter Arlt , Manfred Jautelat
IPC分类号： C07C69/743 , C07C45/00 , C07C45/63 , C07C45/68 , C07C49/20 , C07C49/223 , C07C49/233 , C07C49/235 , C07C49/237 , C07C49/255 , C07C51/00 , C07C61/39 , C07C61/40 , C07C62/30 , C07C67/00 , C07C69/753 , C07C201/00 , C07C205/55 , C07C225/22 , C07C227/00 , C07C227/02 , C07C229/46 , C07C253/00 , C07C255/56 , C07C255/57 , C07C313/00 , C07C315/04 , C07C317/44 , C07C319/20 , C07C323/62 , C07D307/54 , C07D333/24 , C07D327/00 , C07D307/02 , C07D307/48 , C07D409/00
CPC分类号： C07D333/24 , C07C45/63 , C07C45/68 , C07C49/223 , C07C49/235 , C07C49/237 , C07C49/255 , C07C51/00 , C07D307/54
摘要： 2,2-Dimethyl-3-arylcyclopropanecarboxylic acids and esters, suitable as insecticide intermediates, of the formula ##STR1## in which Ar is naphthyl or substituted furyl, thienyl or phenyl, andR.sup.1 is hydrogen or alkyl, are produced by subjecting ##STR2## to radical polymerization to produce ##STR3## reacting that with chlorine or bromine to produce ##STR4## and reacting that with an alkali metal or alkaline earth metal hydroxide or carbonate. Various intermediates II and III are new.
摘要翻译：其中Ar为萘基或取代的呋喃基，噻吩基或苯基，R1为氢或烷基的式（Ⅰ）中适合作为杀虫剂中间体的2,2-二甲基-3-芳基环丙烷羧酸和酯由（IV）进行自由基聚合以产生与氯或溴反应产生（II）并与碱金属或碱土金属氢氧化物或碳酸酯反应的反应（III）。各种中间体II和III是新的。

58. 发明授权

US4426529A Preparation of 2-(2-2-dimethyl-3-buten-1-yl)-2-oxaxolines 失效
标题翻译： 2-（2-2-二甲基-3-丁烯-1-基）-2-恶唑啉的制备
公开(公告)号：US4426529A
公开(公告)日：1984-01-17
申请号：US342276
申请日：1982-01-25
申请人： Manfred Jautelat , Dieter Arlt
发明人： Manfred Jautelat , Dieter Arlt
IPC分类号： C07D263/04 , C07D263/12 , C07D263/10
CPC分类号： C07D263/04 , C07D263/12
摘要： A process comprising reacting a 2-methyloxazoline with a 3-methyl-2-buten-1-yl derivative of the formula ##STR1## in which X is halide, sulphonate or phosphate thereby to produce a 2-methyl-3-(3-methyl-2-butenyl)-2-oxazolinium salt of the formula ##STR2## reacting the oxazolinium salt with an alcoholate of the formulaR.sup.5 --O--M (V)in which M is one equivalent of an alkali metal or alkaline earth metal cation, to produce an oxazolidine of the formula ##STR3## pyrolyzing the oxazolidine to produce a 2-methyl-3-(3-methyl-2-butenyl)-oxazolindine of the formula ##STR4## and heating the 2-methylene-3-(3-methyl-2-butenyl)-oxazolidine to produce a 2-(2,2-dimethyl-3-buten-1-yl)-2-oxazoline.
摘要翻译：一种方法，包括使2-甲基恶唑啉与式（VII）的3-甲基-2-丁烯-1-基衍生物反应，其中X为卤化物，磺酸盐或磷酸盐，从而产生2-甲基-3- （Ⅳ）的（3-甲基-2-丁烯基）-2-恶唑啉盐（Ⅳ）使恶唑啉盐与式为R5-OM（Ⅴ）的醇化物反应，其中M为1当量的碱金属或碱土金属阳离子，以产生式（III）的恶唑烷，式（III）热解恶唑烷以产生式“IMAGE”的2-甲基-3-（3-甲基-2-丁烯基） - 恶唑啉并加热 2-亚甲基-3-（3-甲基-2-丁烯基） - 恶唑烷，得到2-（2,2-二甲基-3-丁烯-1-基）-2-恶唑啉。

59. 发明授权

US4191712A Process for the preparation of 1,1-dihalo-4-methyl-1,3-pentadiene compounds 失效
标题翻译：制备1,1-二卤代-4-甲基-1,3-戊二烯化合物的方法
公开(公告)号：US4191712A
公开(公告)日：1980-03-04
申请号：US964216
申请日：1978-11-27
申请人： Dieter Arlt , Manfred Jautelat
发明人： Dieter Arlt , Manfred Jautelat
IPC分类号： C07C17/00 , C07C17/25 , C07C17/361 , C07C21/06 , C07C21/19 , C07C67/00 , C07C17/24
CPC分类号： C07C17/361
摘要： Process for making 1,1-dihalo-4-methyl-1,3-pentadiene compounds which process comprises reacting a 2-2-dimethyl-3,5,5,5-tetrahelogenopent-1-yl derivative of the formula ##STR1## in which Hal.sup.1 is defined as above,Hal.sup.2 is halogen, andR is hydrogen or alkanoyl of up to 5 carbon atoms with a substance having a basic reaction in a temperature range from 20.degree. to 160.degree. C. Certain intermediates produced in such process can also be used as the initial starting material.
摘要翻译：制备1,1-二卤代-4-甲基-1,3-戊二烯化合物的方法包括使下式的图像形式的2-二甲基-3,5,5,5-四脱木酸-1-基衍生物：（I），其中Hal1如上所定义，Hal2是卤素，R是氢或具有至多5个碳原子的烷酰基，物质在20至160℃的温度范围内具有碱性反应。产生某些中间产物在这种过程中也可以用作初始起始材料。

60. 发明授权

US06559317B2 Method for production of a triazolinethione derivative 有权
标题翻译：三唑啉硫酮衍生物的制备方法
公开(公告)号：US06559317B2
公开(公告)日：2003-05-06
申请号：US10149933
申请日：2002-06-14
申请人： Achim Hupperts , Michael Ruther , Manfred Jautelat
发明人： Achim Hupperts , Michael Ruther , Manfred Jautelat
IPC分类号： C07D24912
CPC分类号： C07D249/12
摘要： According to a novel process, the triazolinethione derivative of the formula can be prepared by a) reacting the oxirane of the formula with hydrazine hydrate in the presence of specific diluents, followed by introduction of hydrogen chloride or extraction with aqueous hydrochloric acid, b) treating the resulting hydrazine hydrochloride derivative of the formula with alkali metal hydroxide in the presence of water and further specific diluents, followed by successive reaction with formaldehyde and thiocyanate of the formula X—SCN (IV) in the presence of certain solvents and finally c) reacting the triazolidine derivative of the formula with iron(III) chloride in the presence of aqueous hydrochloric acid.
摘要翻译：根据新方法，公式的三唑啉酮衍生物可通过以下方法制备：a）在特定稀释剂存在下使式的环氧乙烷与水合肼反应，然后加入氯化氢或用盐酸水溶液萃取，b）肼盐酸盐衍生物与碱金属氢氧化物在水和其它特定稀释剂的存在下反应，随后在某些溶剂存在下与下式的甲醛和硫氰酸酯连续反应，最后c）将式的三唑烷衍生物与铁反应 III）氯化物在盐酸水溶液存在下反应。

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