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51. 发明授权

US4491585A Combating pests with novel phenoxypyridylmethyl esters 失效
标题翻译：用新的苯氧基吡啶甲基酯来防治害虫
公开(公告)号：US4491585A
公开(公告)日：1985-01-01
申请号：US355044
申请日：1982-03-05
申请人： Rainer Fuchs , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N53/04 , A01N43/40 , A01N53/00 , A01N53/08 , C07D213/64 , C07D213/643 , C07D213/647
CPC分类号： C07D213/643 , A01N43/40 , A01N53/00 , C07D213/647
摘要： New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description andR represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formulaR--COOH (II)wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.
摘要翻译：新颖的通式（I）的苯氧基吡啶甲基酯其中R1，R2和R3具有说明书中给出的含义，R代表基团，其中R4和R5具有说明书中给出的含义，并且表示基团其中R6和R7具有说明书中给出的含义，通过其中R具有以前给出的含义或这些酸的反应性衍生物的通式为R-COOH（II）的羧酸为与式（III）的苯氧基吡啶醇反应，其中R 1，R 2和R 3具有上述含义，或与这些醇的活性衍生物反应，如果合适，在酸受体存在下，如果合适的话，在催化剂存在下并在适当的情况下在稀释剂存在下进行。式（I）的新的苯氧基吡啶基甲基酯的特征在于高杀虫性，特别是杀虫和杀虫活性。

52. 发明授权

US4276310A Combating pests with N-(4-substituted-phenyl)-N'-(2-substituted-benzoyl)-thioureas 失效
标题翻译：与N-（4-取代 - 苯基）-N' - （2-取代 - 苯甲酰基） - 硫脲相结合的害虫
公开(公告)号：US4276310A
公开(公告)日：1981-06-30
申请号：US67246
申请日：1979-08-16
申请人： Wilhelm Sirrenberg , Erich Klauke , Ingeborg Hammann , Ingomar Krehan , Peter Kraus , Wilhelm Stendel
发明人： Wilhelm Sirrenberg , Erich Klauke , Ingeborg Hammann , Ingomar Krehan , Peter Kraus , Wilhelm Stendel
IPC分类号： A01N47/34 , C07C67/00 , C07C325/00 , C07C335/26 , C07C157/12 , A01N47/30
CPC分类号： C07C335/26 , A01N47/34
摘要： N-(4-Substituted-phenyl)-N'-(2-substituted-benzoyl)-thioureas of the formula ##STR1## in which R.sup.1 represents halogen,R.sup.2 represents hydrogen or halogen,R.sup.3 represents hydrogen, halogen or halogenoalkyl,R.sup.4 represents halogen, halogenoalkyl, halogenoalkoxy, halogenoalkylthio or halogenoalkylsulphonyl, with the proviso that R.sup.3 represents halogenoalkyl if R.sup.4 represents halogen, andR.sup.5 represents hydrogen or halogen,which possess arthropodicidal, fungicidal and bactericidal properties.
摘要翻译：其中R 1表示卤素，R 2表示氢或卤素，R 3表示氢，卤素或卤代烷基，R 4表示氢，卤素或卤代烷基，卤素，卤代烷基，卤代烷氧基，卤代烷硫基或卤代烷基磺酰基，条件是如果R 4表示卤素，R 3表示卤代烷基，并且R 5表示氢或卤素，其具有杀节细菌，杀真菌和杀菌性质。

53. 发明授权

US4276306A Combating arthropods with 3-phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates 失效
标题翻译：将节肢动物与2,2-二甲基-3-乙烯基 - 环丙烷羧酸3-苯氧基苄酯反应
公开(公告)号：US4276306A
公开(公告)日：1981-06-30
申请号：US916163
申请日：1978-06-16
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C61/39 , A01N53/00 , A01N53/08 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/10 , C07C67/14 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/55 , C07C69/75 , C07C121/75
CPC分类号： A01N53/00
摘要： 3-Phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates of the formula ##STR1## in which R, R.sup.1 and R.sup.2 each independently is hydrogen or halogen,R.sup.3 is phenyl, phenylthio, or phenyl or phenylthio carrying at least one alkyl group or halogen atom,Y is hydrogen or cyano,n is 1, 2, 3, 4 or 5, andm is 1, 2, 3 or 4,which possess arthropodicidal properties.
摘要翻译：其中R 1，R 2和R 2各自独立地为氢或卤素，R 3为苯基，苯硫基或苯基或苯硫基，其具有至少一个烷基基团或卤原子，Y为氢或氰基，n为1,2,3,4或5，m为1,2,3或4，具有节肢动物学特性。

54. 发明授权

US4163059A Pesticidally active 4,5-dichloro-3-substituted-phenylimino-1,2-dithiolenes 失效
标题翻译：杀虫活性的4,5-二氯-3-取代苯基亚氨基-1,2-二硫杂环戊烯
公开(公告)号：US4163059A
公开(公告)日：1979-07-31
申请号：US824940
申请日：1977-08-15
申请人： Edgar Enders , Ingeborg Hammann , Wilhelm Brandes , Peter Kraus , Wilhelm Stendel
发明人： Edgar Enders , Ingeborg Hammann , Wilhelm Brandes , Peter Kraus , Wilhelm Stendel
IPC分类号： A01N43/26 , C07D339/04 , A61K31/385 , C07D339/02
CPC分类号： A01N43/26 , C07D339/04
摘要： 4,5-Dichloro-3-substituted-phenylimino-1,2-dithiolenes of the formula ##STR1## in which R is optionally chlorine-substituted or methoxy-substituted phenyl which carries at least one substituent selected independently from fluorine, bromine, iodine, cyano, thiocyanato, nitro, alkyl, cycloalkyl, halogenoalkyl, aryl, alkoxy with 2-6 carbon atoms, aryloxy, alkylthio, arylthio, acylamino, dialkylamino, alkoxycarbonyl, alkycarbonyl, aminocarbonyl, alkysulphonyl, alkoxysulphonyl, aryloxysulphonyl, aminosulphonyl and N-containing heterocyclic rings, or represents phenyl which is monosubstituted, disubstituted or trisubstituted by chlorine in the 2-, 3-, 2,3-, 2,6-, 3,5-, 2,5-, 3,4,5-, 2,4,6- or 2,4,5-positions, andM is 1 or 2, which possess arthropodicidal, nematicidal and fungicidal properties.
摘要翻译：其中R是任选被氯取代或甲氧基取代的苯基，其具有至少一个独立地选自氟，溴，碘的取代基的苯基亚氨基-1,2-二硫代烯氰基，氰硫基，硝基，烷基，环烷基，卤代烷基，芳基，具有2-6个碳原子的烷氧基，芳氧基，烷硫基，芳硫基，酰氨基，二烷基氨基，烷氧基羰基，羰基羰基，氨基羰基，烷磺酰基，烷氧基磺酰基，芳基磺酰基，氨基磺酰基和含N 或表示在2-，3-，2,3-，2,6-，3,5-，2,5-，3,4,5-三甲基苯中被氯单取代，二取代或三取代的苯基， 2,4,6或2,4,5-位，以及M IS 1 OR 2，其具有抗坏血酸，神经和杀真菌性质。

55. 发明授权

US4140792A Combating arthropods with 1-(substituted-phenylcarbamoyl)-3-halophenyl-2-pyrazolines 失效
标题翻译：将节肢动物与1-（取代的 - 苯基氨基甲酰基）-3-卤代苯基-2-吡唑啉酮相结合
公开(公告)号：US4140792A
公开(公告)日：1979-02-20
申请号：US861042
申请日：1977-12-15
申请人： Wilhelm Sirrenberg , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
发明人： Wilhelm Sirrenberg , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N47/38 , C07D231/06 , A01N9/22
CPC分类号： C07D231/06 , A01N47/38
摘要： 1-(Substituted-phenylcarbamoyl)-3-halophenyl-2-pyrazolines of the forumla ##STR1## in which R represents hydrogen or alkyl,R.sup.1 represents hydrogen or halogenophenyl,R.sup.2 represents hydrogen, halogenoalkoxy or halogenoalkylthio,R.sup.3 represents hydrogen, halogen, halogenoalkoxy or halogenoalkylthio andR.sup.4 represents halogen,With the proviso that one of the radicals R.sup.2 and R.sup.3 must represent halogenoalkoxy or halogenoalkylthio, which possess arthropodicidal properties.
摘要翻译：其中R表示氢或烷基，R1表示氢或卤代苯基，R2表示氢，卤代烷氧基或卤代烷硫基，R3表示氢，卤素，卤代烷氧基的1-（取代的苯基氨基甲酰基）-3-卤代苯基-2-吡唑啉酮或卤代烷硫基，R 4表示卤素，其中R 2和R 3之一必须表示具有节肢动物特性的卤代烷氧基或卤代烷硫基。

56. 发明授权

US4139615A O-alkyl-S-alkyl-O-(4-trifluoromethylthio-phenyl)-(thiono)-thiol-phos phoric acid esters and pesticidal compositions and methods 失效
标题翻译： O-烷基-S-烷基-O-（4-三氟甲硫基 - 苯基） - （硫醇） - 硫醇 - 磷酸酯和杀虫组合物和方法
公开(公告)号：US4139615A
公开(公告)日：1979-02-13
申请号：US798746
申请日：1977-05-19
申请人： Hellmut Hoffmann , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
发明人： Hellmut Hoffmann , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N57/14 , C07F9/18 , A01N9/36 , C07F9/165
CPC分类号： A01N57/14 , C07F9/18
摘要： O-Alkyl-S-alkyl-O-(4-trifluoromethylthiophenyl)-(thiono)-thiol-phosphoric acid esters of the formula ##STR1## in which R and R.sup.1 each independently is alkyl,R.sup.2 is hydrogen or alkyl, andX is oxygen or sulphur,Which possess insecticidal, acaricidal and nematicidal properties.
摘要翻译：式（I）的O-烷基-S-烷基-O-（4-三氟甲硫基苯基） - （硫醇） - 硫醇 - 磷酸酯，其中R和R 1各自独立地为烷基，R 2为氢或烷基， X是氧或硫，具有杀菌，杀虫和非特异性。

57. 发明授权

US4711905A 2,4-dihalogenobenzoyl-(thio)urea insecticides 失效
标题翻译： 2,4-二卤代苯甲酰 - （硫）脲类杀虫剂
公开(公告)号：US4711905A
公开(公告)日：1987-12-08
申请号：US746554
申请日：1985-06-19
申请人： Wilhelm Sirrenberg , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
发明人： Wilhelm Sirrenberg , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N47/34 , C07C67/00 , C07C275/54 , C07C309/66 , C07C313/00 , C07C317/42 , C07C323/20 , C07C323/44 , C07C325/00 , C07C335/26 , C07D317/46 , C07D319/08 , C07D319/20 , C07C127/22
CPC分类号： C07D319/08 , A01N47/34 , C07C275/54 , C07C309/66 , C07C317/42 , C07C323/20 , C07C323/44 , C07D317/46 , C07D319/20
摘要： A 2,4-dihalogenobenzoyl-(thio)urea of the formula ##STR1## in which X represents sulphur or oxygen,X.sup.1 and X.sup.2 are identical or different and represent fluorine, chlorine, bromine or iodine,R.sup.1 represents hydrogen, halogen or optionally substituted radicals from the series comprising alkyl, alkoxy and alkylthio,R.sup.2 represents hydrogen, halogen, cyano, nitro, or optionally substituted radicals from the series comprising alkyl, alkylthio, alkylsulphonyl, alkoxy, aryloxy, alkylcarbonyl, alkoxycarbonyl, alkoxycarbonylalkyl and alkoxycarbonylalkylthio, orR.sup.1 and R.sup.2 together represent an optionally substituted alkylenedioxy radical or --CF.sub.2 --O--CF.sub.2 --O--,R.sup.3 represents hydrogen, halogen or an optionally substituted alkyl, alkoxy or aryloxy radical, andR.sup.4 represents hydrogen, halogen, or optionally substituted radicals from the series comprising alkyl, alkylthio and alkoxy, with the exception of those cases in which X represents oxygen, X.sup.1 andX.sup.2 represent chlorine and (a) R.sup.1 represents chlorine, R.sup.2 represents OCF.sub.2 CHFCl and R.sup.3 andR.sup.4 represent hydrogen, or (b) R.sup.1 represents chlorine, R.sup.2 represents OCF.sub.3 and R.sup.3 and R.sup.4 represent hydrogen, or (c) R.sup.1 represents chlorine,R.sup.2 represents SCF.sub.3 and R.sup.3 and R.sup.4 represent hydrogen, or (d) R.sup.1 represents OCF.sub.3 and R.sup.2,R.sup.3 and R.sup.4 represent hydrogen, or (e) R.sup.2 represent OCF.sub.3 and R.sup.1, R.sup.3 and R.sup.4 represent hydrogen.
摘要翻译：其中X表示硫或氧，X 1和X 2的式（I）的2,4-二卤代苯甲酰基（硫代）脲相同或不同，表示氟，氯，溴或碘，R 1表示氢，卤素或烷基，烷硫基，烷基磺酰基，烷氧基，芳氧基，烷基羰基，烷氧基羰基，烷氧基羰基烷基和烷氧基羰基烷基硫基的系列中的R 2表示氢，卤素，氰基，硝基或任选取代的基团，或R 1和R 2一起表示任选取代的亚烷基二氧基或-CF 2 -O-CF 2 -O-，R 3表示氢，卤素或任选取代的烷基，烷氧基或芳氧基，且R 4表示氢，卤素或任选取代的基团，该系列包括烷基，烷硫基和烷氧基，但X表示氧的情况除外，X1和X2表示氯，（a）R1表示氯，R2表示OCF2CHFCl，R3和R4表示氢，或（b）R1表示氯，R2表示OCF3，R3和R4表示氢，或（c）R1表示氯，R2表示SCF3，R3和R4表示氢，或（d ）R1表示OCF3和R2，R3和R4表示氢，或（e）R2表示OCF3，R1，R3和R4表示氢。

58. 发明授权

US4470934A Preparation of cyanoalkylphosphoric acid ester chlorides 失效
标题翻译：氰基烷基磷酸酯氯化物的制备
公开(公告)号：US4470934A
公开(公告)日：1984-09-11
申请号：US475274
申请日：1983-03-14
申请人： Bernd-Wieland Kr/u/ ger , Hans-Joachem Riebel , Ingeborg Hammann , Berhard Homeyer , Wilhelm Stendel
发明人： Bernd-Wieland Kr/u/ ger , Hans-Joachem Riebel , Ingeborg Hammann , Berhard Homeyer , Wilhelm Stendel
IPC分类号： C07F9/14 , C07F9/165 , C07F9/20 , C07F9/26 , C07F9/40 , C07F9/42 , C07F9/146
CPC分类号： C07F9/425 , C07F9/14 , C07F9/1651 , C07F9/20 , C07F9/26 , C07F9/4075
摘要： New cyanoalkylphosphoric acid ester chlorides of the general formula ##STR1## in which R represents a hydrogen atom, an optionally substituted radical selected from alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl, or an optionally substituted heterocyclic radical,R.sup.1 represents an optionally substituted radical selected from alkyl, alkenyl, alkinyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, alkenylthio, alkinylthio, arylthio, aralkylthio, alkylamino (monoalkylamino or dialkylamino), arylamino or aralkylaminoand X represents oxygen or sulphurare obtained by the reaction of a phosphoric acid dichloride of the general formula ##STR2## with an aldehyde of the general formulaR--CHO (III)in the presence of an approximately equimolar quantity of a water-soluble cyanide. The compounds of the formula (I) can be used as intermediate products for the preparation of insecticides.
摘要翻译：通式为“IMAGE”的新的氰基烷基磷酸酯氯化物，其中R表示氢原子，任选取代的选自烷基，烯基，炔基，环烷基，环烯基，芳烷基，芳烯基和芳基或任选取代的杂环基的基团，R1 表示选自烷基，烯基，炔基，芳基，芳烷基，烷氧基，芳氧基，芳烷氧基，烷硫基，烯硫基，炔基硫基，芳硫基，芳烷硫基，烷基氨基（单烷基氨基或二烷基氨基），芳基氨基或芳烷基氨基，X表示氧或硫的任选取代基通过在通式R-CHO（III）的醛与大约等摩尔量的水溶性氰化物的存在下，使通式为“IMAGE”（II）的磷酸二氯化物反应得到。式（I）的化合物可用作制备杀虫剂的中间产物。

59. 发明授权

US4316913A Arthropodicidally active styrylcyclopropanecarboxylic acid esters 失效
标题翻译：节肢动物活性苯乙烯基环丙烷羧酸酯
公开(公告)号：US4316913A
公开(公告)日：1982-02-23
申请号：US136023
申请日：1980-03-31
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C67/08 , A01N53/00 , A01N53/08 , A01N53/10 , B01J31/00 , C07B61/00 , C07C62/34 , C07C67/00 , C07C69/743 , C07C69/757 , C07C253/00 , C07C255/39 , C07C255/53 , C07C313/00 , C07C323/62 , C07D317/46 , C07D317/60 , C07D319/20 , C07F9/40 , C07C121/75
CPC分类号： C07F9/4056 , A01N53/00 , C07C323/00 , C07C62/34 , C07D317/46 , C07D317/60 , C07D319/20
摘要： Substituted styrylcyclopropanecarboxylic acid esters of the formula ##STR1## in which R represents C.sub.1-4 -alkyl or an alcohol radical customary in pyrethroids,R.sup.1 represents alkoxy or alkylthio, either of which is optionally substituted by halogen andR.sup.2 represents hydrogen or alkoxy, orR.sup.1 and R.sup.2 together represent optionally halogen-substituted alkylenedioxy, andR.sup.3 represents hydrogen or chlorine,exhibit arthropodicidal activity. A novel synthesis is shown involving reaction of ##STR2## in the presence of an alkali metal cyanide to produce an end product wherein R is an .alpha.-cyano-3-phenoxybenzyl ester. ##STR3## is reacted with ##STR4## in the presence of a base to produce certain novel intermediates.
摘要翻译：取代的苯甲酰基环丙烷羧酸酯，其中R表示C1-4烷基或拟除虫菊酯中通常的醇基，R1表示烷氧基或烷硫基，其任一个任选被卤素取代，R 2表示氢或烷氧基，或R 1 并且R 2一起代表卤素取代的亚烷基二氧基，并且R 3表示氢或氯，表现出节肢动物杀伤活性。显示了一种新的合成，其涉及在碱金属氰化物存在下的反应，以产生最终产物，其中R是α-氰基-3-苯氧基苄基酯。在一个碱的存在下，与反应产生某些新的中间体。

60. 发明授权

US4215141A Combating insects and acarids with 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters 失效
标题翻译：用4,4,5,5-四氯-2,2-二甲基 - 异丙基-1-羧酸3-苯氧基 - 苄基酯与昆虫和螨虫相结合
公开(公告)号：US4215141A
公开(公告)日：1980-07-29
申请号：US41222
申请日：1979-05-21
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C69/753 , A01N53/00 , A01N53/08 , C07C61/15 , C07C67/00 , C07C253/00 , C07C255/39 , A01N9/20 , A01N9/24 , C07C69/74 , C07C121/66
CPC分类号： C07C61/15 , A01N53/00
摘要： 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters of the formula ##STR1## in which R and R.sup.1 each independently is hydrogen or halogen, andR.sup.2 is hydrogen, cyano or ethynyl,which possess insecticidal and acaricidal properties.
摘要翻译：具有式“IMAGE”的4,4,5,5-四氯-2,2-二甲基 - 异丙烷-1-羧酸3-苯氧基 - 苄基酯，其中R和R 1各自独立地是氢或卤素，R 2是氢，氰基或乙炔基，其具有杀虫和杀螨性质。

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