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51. 发明授权

US5026950A Hydrotreatment-isomerization without hydrogen recycle 失效
标题翻译：无氢循环的加氢处理异构化
公开(公告)号：US5026950A
公开(公告)日：1991-06-25
申请号：US530142
申请日：1990-05-29
申请人： Robert J. Schmidt , Robert S. Haizmann
发明人： Robert J. Schmidt , Robert S. Haizmann
IPC分类号： C07C5/27 , C10G49/00 , C10G65/04
CPC分类号： C10G65/043 , C07C5/2724 , C10G49/007
摘要： A combined process for hydrotreating and isomerizing a C.sub.4 -C.sub.7 feedstock is simplified and made more efficient by the use of a common hydrogen source and low hydrogen to hydrocarbon ratio in both the hydrotreating and isomerization steps of the invention. The method supplies hydrogen to a combined hydrotreatment and isomerization process for the isomerization of a feed stream comprising C.sub.4 -C.sub.7 hydrocarbons. The hydrocarbon feed stream contains sulfur and oxygen contaminants and is combined with a hydrogen-containing stream in an amount that produces a maximum hydrogen to hydrocarbon ratio of 0.9 stdm.sup.3 m.sup.3 (50 SCFB). The hydrotreater feed is contacted in a hydrotreater reactor with a catalyst comprising a Group VIB metal and a Group VIII metal on an alumina support. Effluent from the hydrotreater passes to a first separator that separates the effluent into a first gas stream comprising hydrogen, hydrogen sulfide and water and a treated stream comprising hydrocarbons having from 4-7 carbon atoms. The first gas stream is rejected from the process. The treated stream is mixed with a second hydrogen-containing stream in a proportion that produces a hydrogen to hydrocarbon ratio of from 6.3 to 18 stdm.sup.3 m.sup.3 (350 to 1000 SCFB) to form an isomerization zone feed. The isomerization feed is contacted in an isomerization reaction zone with an isomerization catalyst comprising a crystalline alumino-silicate and a Group VIII metal at isomerization conditions. The effluent from the reaction zone enters a stabilizer where it is separated into a product stream of C.sub.4 -C.sub.7 hydrocarbons and a second gas stream which is removed from the process. The common hydrogen supply source and the low hydrogen to hydrocarbon ratios permit operation of the process without hydrogen recycle facilities between the hydrotreatment and isomerization steps and downstream of the isomerization reactor.
摘要翻译：通过在本发明的加氢处理和异构化步骤中使用普通的氢源和低的氢气与烃的比例，简化了加氢处理和异构化C4-C7原料的组合方法。该方法向组合的加氢处理和异构化方法提供氢气，用于使包含C4-C7烃的进料流异构化。烃进料流含有硫和氧污染物，并且与含氢物流合并，其产生最大氢烃比为0.9stdm3m3（50SCFB）。加氢处理器进料在加氢处理器反应器中与氧化铝载体上含有VIB族金属和VIII族金属的催化剂接触。来自加氢处理器的流出物流入第一分离器，其将流出物分离成包含氢气，硫化氢和水的第一气流以及包含具有4-7个碳原子的烃的处理流。第一个气流从该过程中被拒绝。将经处理的流与第二含氢流以与6.3至18stdm3m3（350至1000SCFB）的氢烃比例形成异构化区进料的比例混合。异构化进料在异构化反应区与异构化催化剂接触，异构化催化剂在异构化条件下包含结晶铝硅酸盐和Ⅷ族金属。来自反应区的流出物进入稳定剂，在其中将其分离成C4-C7烃的产物流和从该方法中除去的第二气流。普通的氢气供应源和低的氢气与烃的比例允许在加氢处理和异构化步骤之间没有氢循环设施的操作，而异构化反应器的下游。

52. 发明授权

US4783575A Isomerization with cyclic hydrocarbon conversion 失效
标题翻译：异构化与环烃转化
公开(公告)号：US4783575A
公开(公告)日：1988-11-08
申请号：US134622
申请日：1987-12-17
申请人： Robert J. Schmidt , Laurence O. Stine
发明人： Robert J. Schmidt , Laurence O. Stine
IPC分类号： B01J27/13 , C07B61/00 , C07C1/00 , C07C5/13 , C07C5/22 , C07C5/27 , C07C67/00 , C10G35/09 , C10G45/62 , C10G47/14
CPC分类号： C07C5/226 , C07C2521/04 , C07C2523/42 , Y10S585/94
摘要： A C.sub.4 -C.sub.6 feed to an isomerization zone containing substantial amounts of cyclic hydrocarbons is contacted with a high chloride, platinum alumina catalyst to simultaneously open cyclic hydrocarbon rings and isomerize paraffins to more highly branched paraffins. The process can operate at relatively low severity conditions that provide favorable equilibrium conditions for isoparaffin conversion. The ring opening is also obtained without excessive generation of light hydrocarbons. Multiple stage reaction zones may be used to operate the first stage at slightly higher severity than the second stage to maximize ring opening and obtain favorable equilibrium of iso to normal paraffins.

53. 发明授权

US4697039A Xylene producing process having staged catalytic conversion of ethylbenzene 失效
标题翻译：二苯乙烯生产方法分阶段催化转化乙苯
公开(公告)号：US4697039A
公开(公告)日：1987-09-29
申请号：US012401
申请日：1987-02-09
申请人： Robert J. Schmidt
发明人： Robert J. Schmidt
IPC分类号： C07C15/08 , C07C5/22
CPC分类号： C07C15/08
摘要： A process is disclosed for the production of a desired xylene isomer, preferably paraxylene, and high quality benzene. The desired isomer is recovered from the feed and recycle streams in a xylene separation zone. The net effluent or raffinate from the separation zone is passed into a catalytic xylene isomerization zone. The isomerization zone effluent stream is passed into a high severity transalkylation zone. Ethylbenzene in the feed stream is subjected to staged conversion in the two catalytic reaction zones and thereby converted to both xylenes and benzene.
摘要翻译：公开了用于生产所需二甲苯异构体，优选对二甲苯和优质苯的方法。在二甲苯分离区中从进料和再循环流中回收所需的异构体。来自分离区的净流出物或萃余液通入催化二甲苯异构化区。异构化区流出物流进入高度严格的烷基转移区。进料流中的乙苯在两个催化反应区中进行分段转化，从而转化为二甲苯和苯。

54. 发明授权

US4469903A Process for the production of isopropyl alcohol 失效
标题翻译：异丙醇生产工艺
公开(公告)号：US4469903A
公开(公告)日：1984-09-04
申请号：US534226
申请日：1983-09-21
申请人： Robert J. Schmidt
发明人： Robert J. Schmidt
IPC分类号： C07C29/04 , C07C29/86 , C07C29/80
CPC分类号： C07C29/86 , C07C29/04
摘要： A process is disclosed for the production of aliphatic alcohol by the direct hydration of an olefinic hydrocarbon. The process is directed to the production of isopropyl alcohol. The process includes the recovery of the alcohol from a water-rich hydration zone effluent stream by countercurrent liquid-liquid extraction against a paraffinic solvent. The solvent is derived from paraffins originally admixed with the olefin-containing feed stream, and the raffinate stream comprises water which is recycled in the process. Expensive product fractionation is eliminated in the production of a fuel grade isopropyl alcohol.
摘要翻译：公开了通过直接水合烯烃制备脂族醇的方法。该方法涉及异丙醇的生产。该方法包括通过逆向液相萃取与石蜡溶剂从富水水合物流出物流中回收醇。溶剂源自原来与含烯烃的进料流混合的链烷烃，萃余液流包括在该方法中再循环的水。在燃料级异丙醇的生产中消除了昂贵的产品分馏。

55. 发明申请

US20100292519A1 AROMATIC ALKYLATION PROCESS WITH REDUCED BYPRODUCT FORMATION 有权
标题翻译：具有减少产物形成的芳香烷基化方法
公开(公告)号：US20100292519A1
公开(公告)日：2010-11-18
申请号：US12467622
申请日：2009-05-18
申请人： Patrick J. Bullen , Steven P. Lankton , Robert J. Schmidt
发明人： Patrick J. Bullen , Steven P. Lankton , Robert J. Schmidt
IPC分类号： C07C2/00
CPC分类号： C07C6/126 , C07C7/1485 , C07C2521/04 , C07C2521/08 , C07C2529/08 , C07C2529/70 , C07C15/073 , C07C15/085 , C07C15/02
摘要： Byproduct formation in aromatic alkylation processes is reduced when different polyalkylated aromatic compounds are first fractionated into separate streams enriched in these respective polyalkylated aromatic compounds, and the separate streams are sent to different transalkylation reaction zones, which may or may not be in the same reactor. The different transalkylation reaction zones allow for greater control of the transalkylation of the respective polyalkylated aromatic compounds, such as diisopropylbenzene (DIPB) and triisopropylbenzene (TIPB) that accompany the alkylation of benzene with propylene in a process for cumene production.
摘要翻译：当将不同的多烷基化芳族化合物首先分馏成富含这些各自的多烷基化芳族化合物的分离的流中时，芳族烷基化方法中的副产物形成降低，并且将分离的物流送入不同的烷基转移反应区，其可以是或不在同一个反应器中。不同的烷基转移反应区可以更好地控制各种多烷基化芳族化合物如二异丙基苯（DIPB）和三异丙基苯（TIPB）在烷基化反应过程中伴随苯与丙烯烷基化反应的烷基转移。

56. 发明申请

US20100183606A1 MONOCYCLIC HETEROCYCLES AS KINASE INHIBITORS 有权
标题翻译：单克隆杂合物作为激酶抑制剂
公开(公告)号：US20100183606A1
公开(公告)日：2010-07-22
申请号：US12727534
申请日：2010-03-19
申请人： ROBERT M BORZILLERI , Lyndon A.M. Cornelius , Robert J. Schmidt , Gretchen M. Schroeder , Kyoung S. Kim
发明人： ROBERT M BORZILLERI , Lyndon A.M. Cornelius , Robert J. Schmidt , Gretchen M. Schroeder , Kyoung S. Kim
IPC分类号： A61K39/395 , A61K31/4409 , A61K31/505 , A61K31/5377 , A61K31/4439 , A61K31/4427 , A61K31/496 , A61K31/4545 , A61K31/454 , A61K31/444 , A61K31/44 , A61K31/517 , A61P35/00
CPC分类号： C07D213/82 , C07D213/68 , C07D213/73 , C07D213/74 , C07D213/75 , C07D213/81 , C07D213/89 , C07D239/34 , C07D239/42 , C07D239/47 , C07D401/06 , C07D401/12 , C07D401/14 , C07D417/12
摘要： The present invention is directed to compounds having the formula and methods for using them for the treatment of cancer.
摘要翻译：本发明涉及具有下式的化合物及其用于治疗癌症的方法。

57. 发明授权

US07714138B2 Monocyclic heterocycles as kinase inhibitors 有权
标题翻译：单环杂环作为激酶抑制剂
公开(公告)号：US07714138B2
公开(公告)日：2010-05-11
申请号：US12253491
申请日：2008-10-17
申请人： Robert M. Borzilleri , Lyndon A. M. Cornelius , Robert J. Schmidt , Gretchen M. Schroeder , Kyoung S. Kim
发明人： Robert M. Borzilleri , Lyndon A. M. Cornelius , Robert J. Schmidt , Gretchen M. Schroeder , Kyoung S. Kim
IPC分类号： C07D211/72 , A61K31/44
CPC分类号： C07D213/82 , C07D213/68 , C07D213/73 , C07D213/74 , C07D213/75 , C07D213/81 , C07D213/89 , C07D239/34 , C07D239/42 , C07D239/47 , C07D401/06 , C07D401/12 , C07D401/14 , C07D417/12
摘要： The present invention is directed to compounds having the formula and methods for using them for the treatment of cancer.
摘要翻译：本发明涉及具有下式的化合物及其用于治疗癌症的方法。

58. 发明授权

US5473105A Process for concurrently producing diisopropyl ether and isoproyl ethyl ether 失效
标题翻译：同时生产二异丙醚和异丙基乙醚的方法
公开(公告)号：US5473105A
公开(公告)日：1995-12-05
申请号：US317448
申请日：1994-10-04
申请人： Terry L. Marker , Robert J. Schmidt , Richard E. Marinangeli , Allyn T. Gilbert
发明人： Terry L. Marker , Robert J. Schmidt , Richard E. Marinangeli , Allyn T. Gilbert
IPC分类号： C07C41/05 , C07C41/06
CPC分类号： C07C41/06 , C07C41/09
摘要： A process for concurrently producing diisopropyl ether and isopropyl ethyl ether from water, ethanol from an independent source, and propylene, has been developed. The product mixture may be used as a high octane number booster due mainly to the presence of the diisopropyl ether and to a lesser extent, the isopropyl ethyl ether. Furthermore, the product mixture, upon blending with gasoline, incorporates a renewable resource into the gasoline since the isopropyl ethyl ether is produced from ethanol. Optionally, the product mixture may be passed through an acid removal zone to remove acid, if present, before being recycled or further processed. A portion of the product mixture is recycled to the reaction zone to increase the conversion of reactants to products.
摘要翻译：已经开发了一种从水中独立制备二异丙基醚和异丙基乙醚，独立来源的乙醇和丙烯的方法。产物混合物可以用作高辛烷值助剂，主要是由于二异丙醚的存在和少量的异丙基乙醚。此外，与汽油混合后的产物混合物将可再生资源掺入汽油中，因为异丙基乙醚由乙醇生产。任选地，如果存在的话，产物混合物可以通过酸去除区以除去酸，然后再循环或进一步处理。将一部分产物混合物再循环到反应区，以增加反应物向产物的转化率。

59. 发明授权

US5135639A Production of reformulated gasoline 失效
标题翻译：生产重整汽油
公开(公告)号：US5135639A
公开(公告)日：1992-08-04
申请号：US528403
申请日：1990-05-24
申请人： Robert J. Schmidt , Srikantiah Raghuram
发明人： Robert J. Schmidt , Srikantiah Raghuram
IPC分类号： C10G59/02 , C10L1/06
CPC分类号： C10L1/06 , C10G59/02
摘要： A process combination is disclosed to reduce the aromatics content of a key component of gasoline blends. Paraffins contained in catalytic reformates are conserved and upgraded by separation and isomerization, reducing the reforming severity required to achieve a given product octane with concomitant reduction in paraffin aromatization and cracking. Light reformate may be separated and isomerized, and heavier paraffins are separated from the reformate by solvent extraction or adsorption and isomerized. A gasoline component having a reduced aromatics content relative to reformate of the same octane number is blended from the net products of the separation and isomerization steps.
摘要翻译：公开了一种方法组合以降低汽油混合物的关键组分的芳族化合物含量。包含在催化重整产物中的石蜡通过分离和异构化被保存和升级，降低了获得给定产物辛烷值同时降低链烷烃芳构化和开裂所需的重整严重性。轻质重整物可以分离和异构化，并且较重的链烷烃通过溶剂萃取或吸附与重整产物分离并异构化。从分离和异构化步骤的净产物中混合相对于相同辛烷值的重整产物具有降低的芳族化合物含量的汽油组分。

60. 发明授权

US4886928A Hydrocarbon dehydrogenation process 失效
标题翻译：烃脱氢过程
公开(公告)号：US4886928A
公开(公告)日：1989-12-12
申请号：US249057
申请日：1988-09-26
申请人： Tamotsu Imai , Robert J. Schmidt
发明人： Tamotsu Imai , Robert J. Schmidt
IPC分类号： B01J23/62 , B01J23/63 , C07C5/32 , C07C5/333
CPC分类号： B01J23/63 , B01J23/622 , C07C5/325 , C07C5/3337 , Y02P20/52
摘要： A novel dehydrogenation process is disclosed which utilizes a catalyst comprising a platinum group component, a component selected from the group comprising scandium, yttrium, lanthanum, and actinium, a component selected from the group comprising tin, lead, and germanium, less than 0.3 wt. % of a halogen component, and an optional Group IA or IIA component, all on a refractory inorganic oxide support.
摘要翻译：公开了一种新的脱氢方法，其使用包含铂族组分，选自钪，钇，镧和锕的组分的催化剂，选自锡，铅和锗的组分，小于0.3重量％。％的卤素组分和任选的IA或IIA组分，全部在耐火无机氧化物载体上。

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