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    • 58. 发明授权
    • Process for polymerization in the presence of alpha olefins
    • 在α-烯烃存在下进行聚合的方法
    • US06184315B2
    • 2001-02-06
    • US09252869
    • 1999-02-18
    • Alain ForestiereFrançois Hugues
    • Alain ForestiereFrançois Hugues
    • C08F200
    • C08F6/003C08F6/006C08F210/16C08L23/08C08F210/14
    • The polymerization process is carried out starting from a monomer that is introduced via pipe (1) and a comonomer that is introduced via pipe (2); the comonomer that is used, which is an alpha-olefin, is introduced into polymerization reactor P in the form of an approximately pure compound. The polymerization effluent is then separated in separator S1 into two fractions: a heavy fraction that is evacuated via pipe (5) and that contains at least one polymer, and a light fraction that is evacuated via pipe (4) and that comprises the monomer that has not reacted, the comonomer that has not reacted, as well as isomers of this comonomer. At least a portion of the light fraction is then treated during an ethenolysis stage E in the presence of an addition of fresh ethylene that is introduced via line (9). The effluent that is produced in the ethenolysis stage is subjected to at least two separations in separation train S2. After the fraction that contains the light olefins and the fraction that contains the heavy compounds have been separated, the fraction that comprises the comonomer is recycled via pipe (10) toward polymerization zone P.
    • 从通过管(1)引入的单体和通过管(2)引入的共聚单体开始聚合过程; 将所使用的共聚单体(其为α-烯烃)以近纯化合物的形式引入聚合反应器P中。 然后将聚合流出物在分离器S1中分离成两部分:通过管道(5)抽真空并且含有至少一种聚合物的重馏分和通过管道(4)抽空的轻馏分,并且包含单体, 没有反应,未反应的共聚单体,以及该共聚单体的异构体。 然后在乙烯溶解阶段E中,在加入通过管线(9)引入的新鲜乙烯的存在下,至少部分轻馏分处理。 在乙烯分解阶段中产生的流出物在分离系S2中进行至少两次分离。 在含有轻质烯烃的馏分和含有重质化合物的馏分已经分离后,包含共聚单体的馏分通过管道(10)再循环到聚合区域P.