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51. 发明申请

US20140291572A1 METHOD FOR PREPARING ALKALI METAL AND TRANSITION METAL FLUOROSULFATES 有权
标题翻译：制备碱金属和过渡金属氟化物的方法
公开(公告)号：US20140291572A1
公开(公告)日：2014-10-02
申请号：US13697573
申请日：2011-05-11
申请人： Jean-Marie Tarascon , Mohamed Ati , Michel Armand , Nadir Recham
发明人： Jean-Marie Tarascon , Mohamed Ati , Michel Armand , Nadir Recham
IPC分类号： C01D15/06 , C01D5/00
CPC分类号： C01D15/06 , C01D5/00 , C01G49/009 , C01G49/14 , C01G51/006 , C01G51/10 , C01G53/006 , C01G53/10 , C01P2002/54 , C01P2002/72 , C01P2002/85 , C01P2002/88 , C01P2004/03 , C01P2006/40 , H01M4/5825
摘要： The invention relates to a method for preparing an alkali metal and transition metal fluorosulfate that is useful as an electrode material in an electrochemical battery that operates by alkali ion exchange. The method includes a first step that involves: preparing a mixture of precursors of elements making up fluorosulfate, placing said mixture in contact with a solid polymer at ambient temperature, subjecting the reaction medium to a heat treatment that aims to melt the polymer, and subsequently reacting the precursors with one another. Said polymer is one that is solid at ambient temperature, has a melting point lower than the reaction temperature of the precursors, is stable at least up to the reaction temperature of the precursors, and is soluble in a nonpolar aprotic organic solvent.
摘要翻译：本发明涉及一种制备碱金属和过渡金属氟硫酸盐的方法，其可用作通过碱离子交换操作的电化学电池中的电极材料。该方法包括第一步骤，其包括：制备构成氟硫酸盐的元素的前体的混合物，将所述混合物与环境温度下的固体聚合物接触，使反应介质经受热处理，其目的是熔化聚合物，随后使前体彼此反应。所述聚合物是在环境温度下为固体的聚合物，其熔点低于前体的反应温度，至少稳定至前体的反应温度，并且可溶于非极性非质子有机溶剂。

52. 发明申请

US20080212160A1 Electronically Controlled Device With Variable Optical And/Or Power Properties And Power Supply Method Therefor 审中-公开
标题翻译：具有可变光学和/或功率特性的电子控制器件及其电源方法
公开(公告)号：US20080212160A1
公开(公告)日：2008-09-04
申请号：US11817685
申请日：2006-03-01
申请人： Xavier Fanton , Cecile Rocaniere , Jean-Marie Tarascon , Aline Rougier , Samuel Dubrenat , Emmanuel Gourba , Jean-Christophe Giron
发明人： Xavier Fanton , Cecile Rocaniere , Jean-Marie Tarascon , Aline Rougier , Samuel Dubrenat , Emmanuel Gourba , Jean-Christophe Giron
IPC分类号： G02F1/153 , G02F1/163
CPC分类号： B32B17/1077 , B32B17/10036 , B32B17/10513 , G02F1/1525 , G02F1/163
摘要： Electrically controllable system having variable optical/energy properties in transmission or reflection, comprising at least one carrier substrate provided with a multilayer allowing the migration of active species, especially an electrochromic multilayer comprising at least two active layers that are separated by at least one layer having an electrolyte function, said multilayer being placed between two electronic conductors connected respectively to current leads, namely lower and upper leads respectively, characterized in that the layer having an electrolyte function incorporates at least one hybrid layer based on a metal layer and on a passivation layer for passivating the same metal as that of the metal layer.
摘要翻译：在透射或反射中具有可变光学/能量特性的电控系统包括至少一个载体衬底，该载体衬底具有允许活性物质迁移的多层载体，特别是包含至少两层活性层的电致变色多层，所述至少两层活性层被至少一层分离，电解质功能，所述多层被放置在分别连接到电流引线（即下引线和上引线）的两个电子导体之间，其特征在于具有电解质功能的层结合至少一个基于金属层的复合层和钝化层用于钝化与金属层相同的金属。

53. 发明申请

US20080131773A1 Flexible, Aqueous, Controlled Emission Electrochemical Cell 有权
标题翻译：柔性，水性，受控发射电化学电池
公开(公告)号：US20080131773A1
公开(公告)日：2008-06-05
申请号：US11793105
申请日：2005-12-19
申请人： Valerie Lucas , Lionel Beluze , Mathieu Morcrette , Jean-Marie Tarascon
发明人： Valerie Lucas , Lionel Beluze , Mathieu Morcrette , Jean-Marie Tarascon
IPC分类号： H01M10/36 , H01M4/00
CPC分类号： G02F1/15
摘要： The invention concerns an electrochemical cell in thin films and aqueous electrolyte, with an emissivity that varies as a function of an applied control voltage. It is formed of the following flexible elements, superimposed and respectively in intimate contact:a first current collector (11) in electrically conducting material and intended to be connected to a first potential of the control voltage,a porous counter electrode (12) formed of a mixture of PVDF-HFP, PEO and a powder of a compound comprising complementary ions of an insertion material,a porous separator (13) formed of a mixture of PVDF-HFP and PEO,a second current collector (14) in electrically conducting material, intended to be connected to a second potential of the control voltage and capable of being traversed by ions,a porous electronic conduction layer (15) formed of a mixture of PVDF-HFP, PEO and a powder of an electrically conducting material,a porous active layer (16) formed of a mixture of PVDF-HFP, PEO and a powder of an insertion material.
摘要翻译：本发明涉及薄膜和含水电解质中的电化学电池，发射率随施加的控制电压而变化。它由以下柔性元件形成，叠加并分别紧密接触：导电材料中的第一集电体（11）并且旨在连接到控制电压的第一电位;多孔对电极（12）由 PVDF-HFP，PEO和包含插入材料的互补离子的化合物的粉末的混合物，由PVDF-HFP和PEO的混合物形成的多孔隔膜（13），导电材料中的第二集电体（14），旨在连接到控制电压的第二电位并能够被离子穿过;由PVDF-HFP，PEO和导电材料的粉末的混合物形成的多孔电子传导层（15），多孔活性层（16）由PVDF-HFP，PEO和插入材料的粉末的混合物形成。

54. 发明申请

US20050191558A1 Lithium cell battery 审中-公开
标题翻译：锂电池
公开(公告)号：US20050191558A1
公开(公告)日：2005-09-01
申请号：US10517875
申请日：2003-06-16
申请人： Lucas Sannier , Sylvie Grugeon , Stephane Lascaud , Jean-Marie Tarascon
发明人： Lucas Sannier , Sylvie Grugeon , Stephane Lascaud , Jean-Marie Tarascon
IPC分类号： H01M2/16 , H01M4/131 , H01M4/1391 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0585 , H01M10/36 , H01M10/40 , H01M10/04
CPC分类号： H01M10/052 , H01M2/1653 , H01M2/1686 , H01M4/131 , H01M4/1391 , H01M10/0525 , H01M10/0565 , H01M10/0585 , Y02E60/122 , Y02P70/54 , Y02T10/7011 , Y10T29/49115
摘要： The invention concerns an electrochemical lithium cell battery (10; 12; 14) comprising at least one positive electrode (5, 6), at least one liquid electrolyte including at least one lithium salt, and at least one negative electrode (1, 2) Said cell battery (10; 12; 14) is characterized in that it comprises at least one layer (3, 13) of a gelled separator (SG) comprising at least one polymer (PG), capable of being gelled by the liquid electrolyte, which is at least partly gelled by the liquid electrolyte, in contact with the negative electrode (1, 2), and in that it comprises at least a layer (4) of a plasticized separator (SP), including at least one polymer (PP) capable of being plasticized by the liquid electrolyte, at least partly in contact with the separator layer (SG). The invention is particularly applicable to hybrid and/or electric vehicles or portable appliances.
摘要翻译：本发明涉及一种包括至少一个正电极（5,6），至少一种包含至少一种锂盐的液体电解质和至少一种负电极（1,2）的电化学锂电池（10; 12; 14）所述电池单元（10; 12; 14）的特征在于，其包括至少一层（3,13）凝胶分离器（SG），其包含至少一种聚合物（PG），能够被液体电解质凝胶化，其至少部分地被液体电解胶凝胶化，与负极（1,2）接触，并且其至少包括塑化分离器（SP）的层（4），其包括至少一种聚合物（PP））能够被液体电解质塑化，至少部分地与分离层（SG）接触。本发明特别适用于混合动力和/或电动车辆或便携式装置。

55. 发明授权

US06181545B2 Supercapacitor structure 失效
标题翻译：超级电容器结构
公开(公告)号：US06181545B2
公开(公告)日：2001-01-30
申请号：US09159557
申请日：1998-09-24
申请人： Glenn G. Amatucci , Aurelien DuPasquier , Jean-Marie Tarascon
发明人： Glenn G. Amatucci , Aurelien DuPasquier , Jean-Marie Tarascon
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G4/30 , H01G11/72 , H01M6/181 , H01M10/4264 , H01M16/00 , Y02E60/13 , Y10T29/417
摘要： Supercapacitor cell electrode and separator elements formulated as membranes of plasticized polymeric matrix compositions are laminated with electrically conductive current collector elements to form flexible, unitary supercapacitor structures. The matrix plasticizer component is extracted from the laminate with polymer-inert solvent and replaced with electrolyte solution to activate the supercapacitor. Various arrangements of cell structure elements provide parallel and series cell structures which yield improved specific energy capacity and increased voltage output for utilization demands. The supercapacitor elements may also be laminated with similar polymeric rechargeable battery cell structures to provide hybrid devices capable of delivering both high energy and high power as needed in electronic systems.
摘要翻译：配制为增塑聚合物基质组合物的膜的超级电容器电极和隔离元件与导电集电器元件层叠以形成柔性的单一超级电容器结构。用聚合物惰性溶剂从层压体中提取基质增塑剂组分，并用电解质溶液代替以激活超级电容器。电池结构元件的各种布置提供并联和串联电池结构，其产生改进的比能量容量和增加的电压输出用于利用需求。超级电容器元件也可以与类似的聚合物可再充电电池单元结构层压，以提供能够在电子系统中根据需要传送高能量和高功率的混合设备。

56. 发明授权

US5700598A Method for preparing mixed amorphous vanadium oxides and their use as electrodes in reachargeable lithium cells 失效
标题翻译：混合无定形钒氧化物的制备方法及其作为可伸缩锂电池电极的用途
公开(公告)号：US5700598A
公开(公告)日：1997-12-23
申请号：US678210
申请日：1996-07-11
申请人： Sophie Denis , Francois Orsini , Jean-Marie Tarascon , Marcel Touboul
发明人： Sophie Denis , Francois Orsini , Jean-Marie Tarascon , Marcel Touboul
IPC分类号： C01G31/00 , C01G51/00 , C01G53/00 , H01M4/48 , H01M4/485
CPC分类号： H01M4/485 , C01G31/00 , C01G51/006 , C01G53/006 , C01P2002/02 , C01P2002/72 , C01P2006/12 , C01P2006/40
摘要： A method for preparing an amorphous ternary lithiated vanadium metal oxide of the formula Li.sub.x M.sub.y V.sub.z O.sub.(x+5z+ny)/2, where M is a metal, 0
摘要翻译：一种制备式LixMyVzO（x + 5z + ny）/ 2的无定形三元锂化钒金属氧化物的方法，其中M是金属，0

57. 发明授权

US5695887A Chelation treatment for reduced self-discharge in Li-ion batteries 失效
标题翻译：锂离子电池减少自放电的螯合处理
公开(公告)号：US5695887A
公开(公告)日：1997-12-09
申请号：US645018
申请日：1996-05-09
申请人： Glenn G. Amatucci , Alexandra Blyr , Jean-Marie Tarascon
发明人： Glenn G. Amatucci , Alexandra Blyr , Jean-Marie Tarascon
IPC分类号： H01M2/16 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/50 , H01M4/505 , H01M4/62 , H01M10/0525 , H01M10/058 , H01M10/36 , H01M2/14
CPC分类号： H01M4/131 , H01M10/0525 , H01M4/505 , H01M4/623 , H01M10/058 , H01M2/166 , H01M4/133 , H01M4/1391 , Y02P70/54 , Y10T29/49115
摘要： The extent of self-discharge of rechargeable Li-ion secondary batteries is significantly reduced by treatment of LiMn.sub.2 O.sub.4 intercalation compound electrode material with a chelating agent, such as acetylacetone. This treatment decreases the incidence of non-coordinated Mn-ion sites which can lead to battery electrolyte decomposition and resulting loss of battery capacity. The treatment, which also includes annealing at about 400.degree. C. to 800.degree. C., further prevents such decomposition by varying the surface area and topography of the potentially catalytic electrode material.
摘要翻译：通过用螯合剂如乙酰丙酮处理LiMn2O4插层复合电极材料，可充电锂离子二次电池的自放电程度显着降低。这种处理降低了不协调的Mn离子位点的发生，这可能导致电池电解质分解并导致电池容量的损失。还包括在约400℃至800℃退火的处理，通过改变潜在催化电极材料的表面积和形貌进一步防止这种分解。

58. 发明授权

US5425932A Method for synthesis of high capacity Li.sub.x Mn.sub.2 O.sub.4 secondary battery electrode compounds 失效
标题翻译：合成大容量LixMn2O4二次电池电极化合物的方法
公开(公告)号：US5425932A
公开(公告)日：1995-06-20
申请号：US64247
申请日：1993-05-19
申请人： Jean-Marie Tarascon
发明人： Jean-Marie Tarascon
IPC分类号： C01G45/12 , C01G45/00 , H01M4/50 , H01M4/505 , H01M4/62 , H01M10/052 , H01M10/36
CPC分类号： C01G45/1242 , H01M10/052 , H01M4/505 , C01P2002/77 , C01P2002/88 , C01P2006/40 , H01M4/621
摘要： Lithium intercalation compounds suitable for use in high capacity secondary battery electrodes are prepared by reacting together at a temperature in the range of about 800.degree. to 900.degree. C. lithium and manganese compounds in a stoichiometric ratio resulting in a Li.sub.x Mn.sub.2 O.sub.4 compound wherein x is within the range of about 1.00 to 1.20. The resulting compound is annealed at a temperature in excess of about 800.degree. C. and cooled to at least about 500.degree. C. at the rate less than about 10.degree. C. per hour before being finally cooled to ambient working temperature. Intercalation electrodes comprising these lithiated compounds are used in secondary batteries to yield stable, extended capacities in excess of 110 AHr/Kg.
摘要翻译：适合用于大容量二次电池电极的锂嵌入化合物通过在约800-900℃的温度范围内以化学计量比在一个温度范围内的锂和锰化合物反应来制备，得到LixMn2O4化合物，其中x在范围约1.00〜1.20。所得化合物在超过约800℃的温度下退火，并以小于约10℃/小时的速率冷却至至少约500℃，最后冷却至环境温度。包含这些锂化合物的插层电极用于二次电池中以产生超过110Hhr / Kg的稳定的扩展容量。

59. 发明授权

US5211933A Method for preparation of LiCoO.sub.2 intercalation compound for use in secondary lithium batteries 失效
标题翻译：用于二次锂电池的LiCoO2插层化合物的制备方法
公开(公告)号：US5211933A
公开(公告)日：1993-05-18
申请号：US876880
申请日：1992-04-30
申请人： Philippe Barboux , Frough K. Shokoohi , Jean-Marie Tarascon
发明人： Philippe Barboux , Frough K. Shokoohi , Jean-Marie Tarascon
IPC分类号： C01G45/00 , H01M4/131 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525
CPC分类号： H01M4/485 , C01G45/1242 , C01G51/42 , H01M4/131 , H01M4/505 , H01M4/525 , C01P2002/32 , C01P2006/40
摘要： Methods are described for the low temperature preparation of the spinel LiMn.sub.2 O.sub.4 and layered LiCoO.sub.2 phases which are intercalable compounds of interest for use in lithium secondary batteries. These phases can be prepared in bulk or thick film form at temperatures less than 400.degree. C. using acetate precursors.
摘要翻译：描述了用于锂二次电池的尖晶石LiMn 2 O 4和层状LiCoO 2相的低温制备方法，这些相是可感兴趣的化合物。这些相可以使用乙酸酯前体在小于400℃的温度下以体积或厚膜形式制备。

60. 发明授权

US5194341A Silica electrolyte element for secondary lithium battery 失效
标题翻译：二次锂电池二氧化硅电解液元件
公开(公告)号：US5194341A
公开(公告)日：1993-03-16
申请号：US801038
申请日：1991-12-03
申请人： Brian G. Bagley , Jean-Marie Tarascon
发明人： Brian G. Bagley , Jean-Marie Tarascon
IPC分类号： H01M2/16 , H01M10/05
CPC分类号： H01M10/05 , H01M2/1646 , H01M2/1673
摘要： A film of linear organosilsesquioxane polymer, or "ladder" organosiloxane, coated upon the surface of a LiMn.sub.2 O.sub.4 secondary battery electrode 19 and cured to a glassy layer is subjected to plasma oxidation to remove pendant organic groups comprising the coated polymer. The resulting ultrathin silica separator layer 17 is replete with minute pores which take up and retain by capillarity a typical LiClO.sub.4 electrolyte solution. A counter-electrode 15 placed in intimate contact with the silica electrolyte element completes a secondary battery structure 10 in which lithium ions readily migrate through the electrolyte during repeated discharge/charge cycles without loss of element integrity or efficacy.
摘要翻译：将涂覆在LiMn 2 O 4二次电池电极19的表面上并固化至玻璃质层的线性有机倍半硅氧烷聚合物或“梯子”有机硅氧烷膜进行等离子体氧化以除去包括涂覆的聚合物的侧面有机基团。所得到的超薄二氧化硅分离器层17充满了微细孔，其通过毛细管吸收和保持典型的LiClO 4电解质溶液。与二氧化硅电解质元件紧密接触的对置电极15完成了二次电池结构10，其中锂离子在反复放电/充电循环期间容易地迁移通过电解质，而不损失元件完整性或功效。

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