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51. 发明申请

US20110124885A1 MULTILAYER CATALYST HAVING VANADIUM ANTIMONATE IN AT LEAST ONE CATALYST LAYER FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE HAVING A LOW HOT SPOT TEMPERATURE 审中-公开
标题翻译：用于制备碳羧酸和/或羧酸酐的至少一种催化剂层中的抗氧化剂的多层催化剂和用于制备具有低热点温度的苯基氢醌的方法
公开(公告)号：US20110124885A1
公开(公告)日：2011-05-26
申请号：US12950140
申请日：2010-11-19
申请人： STEFAN ALTWASSER , Jürgen Zühlke , Frank Rosowski , Cornelia Katharina Dobner
发明人： STEFAN ALTWASSER , Jürgen Zühlke , Frank Rosowski , Cornelia Katharina Dobner
IPC分类号： C07D307/89 , B01J23/22
CPC分类号： C07D307/89 , B01J23/002 , B01J23/22 , B01J35/0006 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/53 , B01J2523/55
摘要： The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides, which system comprises a plurality of superposed catalyst layers arranged in a reaction tube, where vanadium antimonate is introduced into the active material in at least one of the catalyst layers. The present invention further relates to a process for gas-phase oxidation, in which a gaseous stream comprising at least one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers and the maximum hot spot temperature is below 425° C.
摘要翻译：本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂体系，该系统包括布置在反应管中的多个重叠的催化剂层，其中锑酸锑在至少一个催化剂层中被引入到活性材料中。本发明还涉及一种用于气相氧化的方法，其中包含至少一种烃和分子氧的气流通过多个催化剂层，最大热点温度低于425℃。

52. 发明申请

US20110034707A1 METHOD FOR STARTING A GAS-PHASE OXIDATION REACTOR 有权
标题翻译：启动气相氧化反应器的方法
公开(公告)号：US20110034707A1
公开(公告)日：2011-02-10
申请号：US12936807
申请日：2009-04-07
申请人： Hagen Wilmer , Zürgen Zühike , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Katharina Dobner
发明人： Hagen Wilmer , Zürgen Zühike , Thomas Lautensack , Hans-Martin Allmann , Frank Rosowski , Cornelia Katharina Dobner
IPC分类号： C07D307/89
CPC分类号： C07C51/265 , C07D307/89
摘要： What is described is a process for starting up a gas phase oxidation reactor for oxidation of o-xylene to phthalic anhydride, said reactor comprising at least one catalyst layer and being temperature-controllable by means of a heat carrier medium, wherein a) the catalyst layer is interrupted by a moderator layer which is less catalytically active than the catalyst layer or is catalytically inactive, b) a gas stream is passed through the reactor with an initial loading of o-xylene and at an initial temperature of the heat transfer medium, c) the loading of the gas stream is increased to a target loading and, in parallel, the temperature of the heat transfer medium is lowered to an operating temperature. The introduction of the moderator layer allows the loading to be increased more rapidly and the startup time to be shortened.
摘要翻译：描述的是用于启动用于将邻二甲苯氧化成邻苯二甲酸酐的气相氧化反应器的方法，所述反应器包括至少一个催化剂层，并且可通过热载体介质温度控制，其中a）催化剂层被催化剂层催化活性较低或催化无活性的中间体层中断，b）气流以邻二甲苯的初始负荷和传热介质的初始温度通过反应器， c）将气流的负载增加到目标负载，并且并联地将传热介质的温度降低到工作温度。调节器层的引入允许加载更快速并且启动时间被缩短。

53. 发明授权

US07851398B2 Catalytic titanium dioxide mixtures, catalysts and catalyst systems containing the same, processes for making the same, and uses therefor 有权
标题翻译：催化二氧化钛混合物，催化剂和含有其的催化剂体系，其制备方法及其用途
公开(公告)号：US07851398B2
公开(公告)日：2010-12-14
申请号：US11719422
申请日：2005-11-16
申请人： Samuel Neto , Sebastian Storck , Jürgen Zühlke , Frank Rosowski
发明人： Samuel Neto , Sebastian Storck , Jürgen Zühlke , Frank Rosowski
IPC分类号： B01J27/198 , B01J21/06
CPC分类号： B01J21/063 , B01J23/002 , B01J23/22 , B01J35/0006 , B01J35/1014 , B01J37/0232 , B01J2523/00 , C07C51/265 , C07C51/313 , C07C63/16 , B01J2523/53 , B01J2523/55 , B01J2523/15 , B01J2523/47 , B01J2523/51
摘要： Catalytic titanium dioxide mixtures comprising: a first anatase titanium dioxide having a BET surface area greater than 15 m2/g and a hydrogen uptake for the reduction of Ti4+ to Ti3+ of from 5 to 20 μmol/m2; and a second anatase titanium dioxide having a BET surface area less than or equal to 15 m2/g and a hydrogen uptake for the reduction of Ti4+ to Ti3+ of from 0.6 to 7 μmol/m2, processes for preparing catalysts containing the same, catalysts containing active compositions including such titanium dioxide mixtures on support materials, and catalyst systems using the same.
摘要翻译：催化二氧化钛混合物，其包含：BET表面积大于15m 2 / g的第一锐钛型二氧化钛和用于还原Ti 4+至Ti 3+的氢吸收为5至20μmol/ m 2; 和BET表面积小于或等于15m 2 / g的第二锐钛矿型二氧化钛和用于还原Ti 4+至Ti 3+的氢吸收为0.6〜7μmol/ m 2，制备含有该催化剂的催化剂，含有包含载体材料上的这种二氧化钛混合物的活性组合物和使用其的催化剂体系。

54. 发明授权

US07687425B2 Three-layered or four-layered catalyst systems for producing phthalic anhydride 有权
标题翻译：用于生产邻苯二甲酸酐的三层或四层催化剂体系
公开(公告)号：US07687425B2
公开(公告)日：2010-03-30
申请号：US10557993
申请日：2004-05-15
申请人： Sebastian Storck , Jürgen Zühlke , Samuel Neto , Frank Rosowski
发明人： Sebastian Storck , Jürgen Zühlke , Samuel Neto , Frank Rosowski
IPC分类号： B01J31/36
CPC分类号： C07C51/313 , B01J23/002 , B01J23/22 , B01J27/198 , B01J35/0006 , B01J35/10 , B01J35/1009 , B01J35/1014 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/51
摘要： Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.
摘要翻译：通过邻二甲苯和/或萘的气相氧化制备邻苯二甲酸酐的催化剂体系，以及使用催化剂体系制备邻苯二甲酸酐的方法。

55. 发明授权

US07592294B2 Gas phase oxidation catalyst with defined vanadium oxide particle size distribution 有权
标题翻译：气相氧化催化剂具有规定的氧化钒粒度分布
公开(公告)号：US07592294B2
公开(公告)日：2009-09-22
申请号：US10573481
申请日：2004-09-24
申请人： Sebastian Storck , Jürgen Zühlke , Samuel Neto , Frank Rosowski , Wolfgang Rummel
发明人： Sebastian Storck , Jürgen Zühlke , Samuel Neto , Frank Rosowski , Wolfgang Rummel
IPC分类号： B01J23/22 , B01J21/06
CPC分类号： C07C51/313 , B01J23/002 , B01J23/22 , B01J27/198 , B01J35/023 , B01J37/0219 , B01J37/0221 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/53 , B01J2523/55
摘要： A process is described for producing a catalyst for gas-phase oxidations, in which a suspension of TiO2 and V2O5 particles is applied to a fluidized inert support, wherein at least 90% by volume of the V2O5 particles have a diameter of 20 μm or less and at least 95% by volume of the V2O5 particles have a diameter of 30 μm or less. The defined particle size distribution of the V2O5 allows a high coating efficiency.
摘要翻译：描述了一种制备用于气相氧化的催化剂的方法，其中将TiO 2和V 2 O 5颗粒的悬浮液施加到流化惰性载体上，其中至少90体积％的V 2 O 5颗粒的直径为20μm或更小并且至少95体积％的V 2 O 5颗粒的直径为30μm或更小。 V2O5的定义的粒度分布允许高涂层效率。

56. 发明申请

US20090198073A1 PREPARATION OF PHTHALIC ANHYDRIDE BY GAS PHASE OXIDATION OF O-XYLENE 有权
标题翻译：气相氧化制备邻苯二甲酸二异氰酸酯
公开(公告)号：US20090198073A1
公开(公告)日：2009-08-06
申请号：US12301352
申请日：2007-05-18
申请人： Thomas Mackewitz , Frank Rosowski , Andreas Tenten
发明人： Thomas Mackewitz , Frank Rosowski , Andreas Tenten
IPC分类号： C07D317/46
CPC分类号： C07D307/89 , C07C51/265 , C07C63/16
摘要： A process is described for preparing phthalic anhydride by catalytic gas phase oxidation of o-xylene. In, in a main reactor, a gaseous mixture of o-xylene and an oxygenous gas is passed through at least two reaction zones whose temperature can be controlled independently, and converted to a gaseous intermediate reaction product which comprises unconverted o-xylene, phthalic anhydride underoxidation products and phthalic anhydride, and the intermediate reaction product is introduced into a postreactor, wherein the temperature of the reaction zones in the main reactor is regulated in such a way that the concentration of unconverted o-xylene in the intermediate reaction product is at least 0.5% by weight. The process allows an increase in the overall yield of phthalic anhydride without or without significant deterioration in the product quality.
摘要翻译：描述了通过邻二甲苯的催化气相氧化制备邻苯二甲酸酐的方法。在主反应器中，邻二甲苯和氧气的气态混合物通过至少两个反应区，其温度可独立控制，并转化成气态中间反应产物，其包含未转化的邻二甲苯，邻苯二甲酸酐未反应产物和邻苯二甲酸酐，并将中间反应产物引入后反应器中，其中主反应器中反应区的温度调节为使中间反应产物中未转化的邻二甲苯的浓度至少为 0.5重量％。该方法允许邻苯二甲酸酐的总产率提高，而不会产生质量的显着劣化。

57. 发明申请

US20090163726A1 CATALYST SYSTEM FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES 审中-公开
标题翻译：用于制备羧酸和/或羧酸类的催化剂体系
公开(公告)号：US20090163726A1
公开(公告)日：2009-06-25
申请号：US12301420
申请日：2007-05-14
申请人： Hagen Wilmer , Cornelia Dobner , Frank Rosowski , Sebastian Storck , Jürgen Zühlke
发明人： Hagen Wilmer , Cornelia Dobner , Frank Rosowski , Sebastian Storck , Jürgen Zühlke
IPC分类号： C07D307/77 , B01J23/04 , B01J27/198
CPC分类号： B01J23/002 , B01J23/22 , B01J27/198 , B01J35/0006 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/51
摘要： The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides which has at least four catalyst layers arranged one on top of another in the reaction tube, the ratio of the bed lengths of the more selective catalyst layers to the bed lengths of the more active catalyst layers being between 1.4 and 2. The present invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises a hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the ratio of the bed lengths of the more selective catalyst layers to the bed lengths of the more active catalyst layers being between 1.4 and 2.
摘要翻译：本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂体系，其具有在反应管中一个在另一个上排列的至少四个催化剂层，更多选择性催化剂层的床长与床的比例更活泼的催化剂层的长度在1.4和2之间。本发明还涉及一种用于气相氧化的方法，其中包含烃和分子氧的气流通过多个催化剂层，更多选择性催化剂层的床长比更活泼的催化剂层的床长在1.4和2之间。

58. 发明申请

US20080200685A1 Method for Preforming Oxidation Catalysts 审中-公开
标题翻译：预氧化催化剂的方法
公开(公告)号：US20080200685A1
公开(公告)日：2008-08-21
申请号：US11916731
申请日：2006-05-31
申请人： Samuel Neto , Frank Rosowski , Sebastian Storck , Jurgen Zuhlke , Hans-Martin Allmann , Thomas Lautensack , Rainer Steeg
发明人： Samuel Neto , Frank Rosowski , Sebastian Storck , Jurgen Zuhlke , Hans-Martin Allmann , Thomas Lautensack , Rainer Steeg
IPC分类号： B01J37/08 , C07C51/16 , C07D307/34 , C07D307/89 , C07D211/00
CPC分类号： B01J37/0018 , B01J23/22 , B01J37/0219 , B01J37/0221 , B01J37/14 , C07C51/265 , C07C63/16
摘要： Processes comprising providing a catalyst precursor, and heating the catalyst precursor to a temperature of at least 350° C. in an atmosphere comprising air, wherein air is fed into the atmosphere at a rate of 0.05 to 4.0 standard m3/h, and wherein the catalyst precursor is activated at a temperature of at least 350° C. for more than 9 hours are described along with catalysts formed thereby and uses for such catalysts.
摘要翻译：方法包括提供催化剂前体，并将催化剂前体在包含空气的气氛中加热到至少350℃的温度，其中空气以0.05至4.0标准m 3的速率进料到大气中， SUP> / h，并且其中催化剂前体在至少350℃的温度下活化超过9小时，以及由此形成的催化剂被描述并用于这种催化剂。

59. 发明授权

US07402288B2 Reactor for testing catalyst systems 失效
标题翻译：用于测试催化剂体系的反应器
公开(公告)号：US07402288B2
公开(公告)日：2008-07-22
申请号：US10478684
申请日：2002-06-05
申请人： Gerhard Olbert , Torsten Mattke , Matthias Kummer , Thomas Ruehl , Frank Rosowski
发明人： Gerhard Olbert , Torsten Mattke , Matthias Kummer , Thomas Ruehl , Frank Rosowski
IPC分类号： B01J19/24 , F27B15/14 , F28D7/16 , G01N31/10
CPC分类号： G01N31/10 , B01J8/067 , B01J2208/00168 , B01J2208/00221 , B01J2208/0023 , B01J2208/00256 , B01J2208/021 , B01J2219/00009 , B01J2219/00745 , B01J2219/00747 , B01J2219/00777 , C40B30/08 , C40B40/18 , F28D7/0066 , F28D7/0091
摘要： A reactor for testing catalyst systems which has a plurality of catalyst tubes (2) which are arranged parallel to one another in the interior space of the reactor and whose ends are welded into tube plates and also has caps (3) at each end of the reactor which each bound a cap space (4), with a fluid reaction medium (5) being fed via one cap space (4) into the catalyst tubes (2), flowing through the catalyst tubes (2) and being discharged via the other cap space (4), and is also provided with a heat exchange medium circuit in which the heat exchange medium (6) is fed in at one end of the reactor, flows through the intermediate space between the catalyst tubes (2) and flows out at the other end of the reactor, wherein the catalyst tubes (2) are arranged in two or more catalyst tube regions (7) which are thermally separate from one another, is proposed.
摘要翻译：一种用于测试催化剂体系的反应器，其具有多个催化剂管（2），所述多个催化剂管（2）在所述反应器的内部空间中彼此平行地布置，并且其端部被焊接到管板中，并且在所述反应器的每一端具有盖（3）反应器，每个反应器结合盖空间（4），流体反应介质（5）经由一个盖空间（4）进入催化剂管（2），流过催化剂管（2）并经由另一个排出盖子空间（4），并且还设置有热交换介质回路，其中热交换介质（6）在反应器的一端进料，流过催化剂管（2）之间的中间空间并流出在反应器的另一端，其中催化剂管（2）布置在彼此热分离的两个或更多个催化剂管区域（7）中。

60. 发明授权

US07371893B2 Production of aldehydes, carboxylic acids and/or carboxylic acid anhydrides by means of catalysts containing vanadium oxide, titanium dioxide, and antimony oxide 有权
标题翻译：通过含有氧化钒，二氧化钛和氧化锑的催化剂生产醛，羧酸和/或羧酸酐
公开(公告)号：US07371893B2
公开(公告)日：2008-05-13
申请号：US10557791
申请日：2004-05-21
申请人： Sebastian Storck , Jürgen Zühlke , Samuel Neto , Frank Rosowski
发明人： Sebastian Storck , Jürgen Zühlke , Samuel Neto , Frank Rosowski
IPC分类号： C07C51/16 , C07D307/89
CPC分类号： C07C51/265 , C07C51/313 , C07C63/16
摘要： A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V2O5, to antimony, calculated as Sb2O3, in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 μm. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.
摘要翻译：给出了制备醛，羧酸和/或羧酸酐，特别是邻苯二甲酸酐的方法的描述，其中包含芳族烃和分子氧的气流在升高的温度下通过第一催化剂的床和床，其由比第一催化剂高的活性的第二催化剂组成，并且位于气流的流动方向上位于第一催化剂的下游，其中第一催化剂的催化活性组合物至少包含氧化钒，钛二氧化锑和氧化锑，以V 2 O 5 5计算的钒与锑的比例计算为Sb 2 O 3 在第一催化剂中为3.5:1至5:1。用于第一催化剂的氧化锑的来源优选是平均粒径为0.5-5微米的颗粒状三氧化锑。该方法允许在较长时间内以高产率获得所需的氧化产物。

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