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    • 52. 发明申请
    • SELECTIVE ETCH OF SILICON BY WAY OF METASTABLE HYDROGEN TERMINATION
    • 通过可转化氢终止方式选择性硅
    • US20130089988A1
    • 2013-04-11
    • US13439079
    • 2012-04-04
    • Anchuan WangJingchun ZhangNitin K. IngleYoung S. Lee
    • Anchuan WangJingchun ZhangNitin K. IngleYoung S. Lee
    • H01L21/3065
    • H01L21/3065H01J37/32357H01L21/3081H01L21/32137
    • Methods of etching exposed silicon on patterned heterogeneous structures is described and includes a remote plasma etch formed from a fluorine-containing precursor and a hydrogen-containing precursor. Plasma effluents from the remote plasma are flowed into a substrate processing region where the plasma effluents react with the exposed regions of silicon. The plasmas effluents react with the patterned heterogeneous structures to selectively remove silicon while very slowly removing other exposed materials. The silicon selectivity results, in part, from a preponderance of hydrogen-containing precursor in the remote plasma which hydrogen terminates surfaces on the patterned heterogeneous structures. A much lower flow of the fluorine-containing precursor progressively substitutes fluorine for hydrogen on the hydrogen-terminated silicon thereby selectively removing silicon from exposed regions of silicon. The methods may be used to selectively remove silicon far faster than silicon oxide, silicon nitride and a variety of metal-containing materials.
    • 描述了在图案化的异质结构上蚀刻暴露的硅的方法,并且包括由含氟前体和含氢前体形成的远程等离子体蚀刻。 来自远程等离子体的等离子体流出物流入衬底处理区域,其中等离子体流出物与暴露的硅区域反应。 等离子体流出物与图案化的异质结构反应以选择性地除去硅,同时非常缓慢地除去其它暴露的材料。 硅选择性部分地导致远离等离子体中含氢前体的优势,氢终止在图案化异质结构上的表面。 含氟前体的流速要低得多,在氢封端的硅上逐渐取代氟氢,从而从硅的暴露区域选择性除去硅。 这些方法可用于选择性地除去硅比氧化硅,氮化硅和各种含金属材料更快的硅。
    • 53. 发明申请
    • SELECTIVE SUPPRESSION OF DRY-ETCH RATE OF MATERIALS CONTAINING BOTH SILICON AND OXYGEN
    • 选择性抑制含有硅和氧的材料的干蚀速率
    • US20130052827A1
    • 2013-02-28
    • US13449543
    • 2012-04-18
    • Yunyu WangAnchuan WangJingchun ZhangNitin K. IngleYoung S. Lee
    • Yunyu WangAnchuan WangJingchun ZhangNitin K. IngleYoung S. Lee
    • H01L21/308
    • H01L21/31116H01J37/32357H01L21/3065H01L21/32137
    • A method of suppressing the etch rate for exposed silicon-and-oxygen-containing material on patterned heterogeneous structures is described and includes a two stage remote plasma etch. Examples of materials whose selectivity is increased using this technique include silicon nitride and silicon. The first stage of the remote plasma etch reacts plasma effluents with the patterned heterogeneous structures to form protective solid by-product on the silicon-and-oxygen-containing material. The plasma effluents of the first stage are formed from a remote plasma of a combination of precursors, including a nitrogen-containing precursor and a hydrogen-containing precursor. The second stage of the remote plasma etch also reacts plasma effluents with the patterned heterogeneous structures to selectively remove material which lacks the protective solid by-product. The plasma effluents of the second stage are formed from a remote plasma of a fluorine-containing precursor.
    • 描述了抑制图案化异质结构上暴露的含硅和氧的材料的蚀刻速率的方法,并且包括两级远程等离子体蚀刻。 使用该技术提高其选择性的材料的实例包括氮化硅和硅。 远程等离子体蚀刻的第一阶段使等离子体流出物与图案化的异质结构反应,以在含硅和氧的材料上形成保护性固体副产物。 第一级的等离子体流出物由包括含氮前体和含氢前体的前体组合的远程等离子体形成。 远程等离子体蚀刻的第二阶段还使等离子体流出物与图案化的异质结构反应,以选择性地去除缺乏保护性固体副产物的材料。 第二级的等离子体流出物由含氟前体的远程等离子体形成。
    • 56. 发明授权
    • Remote plasma clean process with cycled high and low pressure clean steps
    • 远程等离子清洁工艺,循环高低压清洁步骤
    • US07967913B2
    • 2011-06-28
    • US12508381
    • 2009-07-23
    • Zhong Qiang HuaSanjay KamathYoung S. LeeEllie Y. YiehHien-Minh Huu LeAnjana M. PatelSudhir R. Gondhalekar
    • Zhong Qiang HuaSanjay KamathYoung S. LeeEllie Y. YiehHien-Minh Huu LeAnjana M. PatelSudhir R. Gondhalekar
    • B08B6/00
    • B08B7/0035C23C16/4405
    • A remote plasma process for removing unwanted deposition build-up from one or more interior surfaces of a substrate processing chamber after processing a substrate disposed in the substrate processing chamber. In one embodiment, the substrate is transferred out of the substrate processing chamber and a flow of a fluorine-containing etchant gas is introduced into a remote plasma source where reactive species are formed. A continuous flow of the reactive species from the remote plasmas source to the substrate processing chamber is generated while a cycle of high and low pressure clean steps is repeated. During the high pressure clean step, reactive species are flown into the substrate processing chamber while pressure within the substrate processing chamber is maintained between 4-15 Torr. During the low pressure clean step, reactive species are flown into the substrate processing chamber while reducing the pressure of the substrate processing chamber by at least 50 percent of a high pressure reached in the high pressure clean step.
    • 一种远程等离子体处理,用于在处理设置在基板处理室中的基板之后从基板处理室的一个或多个内表面去除不需要的沉积物。 在一个实施例中,将衬底转移出衬底处理室,并且将含氟蚀刻剂气体的流引入形成反应性物质的远程等离子体源中。 产生反应物质从远程等离子体源到基底处理室的连续流动,同时重复高低压清洁步骤的循环。 在高压清洁步骤期间,反应性物质流入基板处理室,同时基板处理室内的压力保持在4-15Torr之间。 在低压清洁步骤期间,将反应性物质流入基板处理室,同时将基板处理室的压力降低至高压清洁步骤达到的至少50%的高压。