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41. 发明授权

US09126884B2 Method for controlling 2-phenyl isomer content of linear alkylbenzene and catalyst used in the method 有权
标题翻译：用于控制线性烷基苯的2-苯基异构体含量的方法和用于该方法的催化剂
公开(公告)号：US09126884B2
公开(公告)日：2015-09-08
申请号：US14053226
申请日：2013-10-14
申请人： UOP LLC
发明人： Mark G. Riley , Deng-Yang Jan , Stephen W. Sohn
IPC分类号： B01J29/06 , B01J29/80 , C07C2/66 , B01J29/08 , B01J29/18 , B01J29/50 , B01J29/60 , B01J29/70 , B01J37/00
CPC分类号： C07C2/66 , B01J29/085 , B01J29/088 , B01J29/18 , B01J29/50 , B01J29/60 , B01J29/70 , B01J29/7007 , B01J29/7034 , B01J29/7038 , B01J29/80 , B01J37/0009 , B01J2229/42 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/80 , C07C15/107
摘要： A method for controlling 2-isomer content in linear alkylbenzene obtained by alkylating benzene with olefins and catalyst used in the method.
摘要翻译：通过在该方法中使用烯烃和催化剂使苯烷基化而获得的直链烷基苯中2-异构体含量的控制方法。

42. 发明授权

US09011815B2 Organotemplate-free synthetic process for the production of a zeolitic material 有权
标题翻译：用于生产沸石材料的无机合成方法
公开(公告)号：US09011815B2
公开(公告)日：2015-04-21
申请号：US13654074
申请日：2012-10-17
申请人： Feng-Shou Xiao , Bin Xie , Ulrich Mueller , Bilge Yilmaz
发明人： Feng-Shou Xiao , Bin Xie , Ulrich Mueller , Bilge Yilmaz
IPC分类号： C01B39/46 , B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , B01J29/88 , B01J35/00 , B01J35/04 , B01J35/10 , C10G11/05 , C10G11/18 , B01D53/02 , B01D53/94 , B01J29/18 , B01J37/00
CPC分类号： B01J29/7007 , B01D53/02 , B01D53/94 , B01D53/9413 , B01D2251/2062 , B01D2251/2067 , B01D2255/20738 , B01D2255/502 , B01D2257/402 , B01D2257/404 , B01D2257/406 , B01D2257/702 , B01D2257/80 , B01J29/18 , B01J29/7415 , B01J29/7615 , B01J29/7815 , B01J29/88 , B01J35/002 , B01J35/04 , B01J35/1019 , B01J35/1023 , B01J37/0009 , C01B39/46 , C10G11/05 , C10G11/18 , C10G2300/405 , Y02C20/10 , Y02P20/153
摘要： The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO2; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X2O3, the mixture according to step (1) comprises at least one source for X2O3, and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
摘要翻译：本发明涉及一种用于生产具有包含YO 2和任选地包含X 2 O 3的BEA骨架结构的沸石材料的无机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种和至少一种来源为YO2; 和（2）使混合物结晶; 其中Y是四价元素，X是三价元素，其中沸石材料任选地包含至少一种碱金属M，其中当BEA骨架另外包含X 2 O 3时，根据步骤（1）的混合物包含至少一种源 X 2 O 3，并且其中所述晶种包含具有BEA骨架结构的沸石材料，优选沸石β。

43. 发明授权

US08945309B2 Catalyst for cellulose hydrolysis and/or reduction of cellulose hydrolysis products and method of producing sugar alcohols from cellulose 有权
标题翻译：用于纤维素水解和/或还原纤维素水解产物的催化剂和由纤维素生产糖醇的方法
公开(公告)号：US08945309B2
公开(公告)日：2015-02-03
申请号：US12224433
申请日：2007-03-01
申请人： Atsushi Fukuoka , Paresh Laxmikant Dhepe
发明人： Atsushi Fukuoka , Paresh Laxmikant Dhepe
IPC分类号： C08B30/00 , C08B37/00 , C13K1/02 , B01J29/00 , B01J29/18 , B01J21/00 , B01J23/42 , B01J23/40 , B01J29/068 , B01J29/44 , B01J29/12 , B01J35/00 , B01J29/03 , C07C29/141 , B01J29/74 , B01J23/46 , B01J29/22 , B01J21/06 , B01J21/04 , B01J23/70 , B01J35/02 , B01J23/48 , B01J21/18 , B01J21/12
CPC分类号： B01J23/42 , B01J21/04 , B01J21/063 , B01J21/066 , B01J21/12 , B01J21/18 , B01J23/40 , B01J23/462 , B01J23/48 , B01J23/70 , B01J29/0325 , B01J29/068 , B01J29/126 , B01J29/22 , B01J29/44 , B01J29/7415 , B01J35/0066 , B01J35/026 , B01J2229/18 , C07C29/141 , Y02P20/584 , Y02P20/588 , C07C31/26 , C07C31/24
摘要： A catalyst for cellulose hydrolysis and/or the reduction of hydrolysis products, in which a transition metal of group 8 to 11 is supported on a solid support. A method of producing sugar alcohols comprising: hydrolyzing cellulose in the presence of the catalyst in a hydrogen-containing atmosphere with pressurization; and reducing the hydrolysis product of cellulose. Provided are a catalyst for use in the production of sugar alcohols by the hydrolysis and hydrogenation of cellulose that affords easy separation of catalyst and product, and that does not require pH adjustment, acid or alkali neutralization, or activation of the catalyst during reuse, and a method of producing sugar alcohols from cellulose employing this catalyst.
摘要翻译：用于纤维素水解和/或还原水解产物的催化剂，其中第8至11族的过渡金属负载在固体载体上。一种制备糖醇的方法，包括：在含氢气氛中在催化剂存在下水解纤维素，同时加压; 并减少纤维素的水解产物。提供了通过纤维素的水解和氢化生产糖醇的催化剂，其提供催化剂和产物的容易分离，并且不需要pH调节，酸或碱中和或在再利用期间活化催化剂，使用该催化剂从纤维素制备糖醇的方法。

44. 发明授权

US08877670B2 Fibrous substrate-based hydroprocessing catalysts and associated methods 有权
标题翻译：基于纤维底物的加氢处理催化剂及相关方法
公开(公告)号：US08877670B2
公开(公告)日：2014-11-04
申请号：US13960935
申请日：2013-08-07
申请人： UOP LLC
发明人： Antoine Negiz , Hui Wang
IPC分类号： B01J37/00 , C01B37/08 , B01J29/70 , B01J35/06 , C01B39/40 , B01J29/06 , B01J29/18 , C01B39/04 , B01J29/08 , C01B37/02 , C01B37/06 , C01B39/54 , B01J29/40
CPC分类号： B01J29/7007 , B01J29/06 , B01J29/084 , B01J29/18 , B01J29/40 , B01J35/06 , B01J2229/64 , C01B37/02 , C01B37/06 , C01B37/08 , C01B39/04 , C01B39/40 , C01B39/54 , C10G47/16
摘要： Catalysts are disclosed comprising fibrous substrates having silica-containing fibers with diameters generally from about 1 to about 50 microns, which act effectively as “micro cylinders.” Such catalysts can dramatically improve physical surface area, for example per unit length of a reactor or reaction zone. At least a portion of the silica, originally present in the silica-containing fibers of a fibrous material used to form the fibrous substrate, is converted to a zeolite (e.g., having a SiO2/Al2O3 ratio of at least about 150) that remains deposited on these fibers. The fibrous substrates possess important properties, for example in terms of acidity, which are useful in hydroprocessing (e.g., hydrotreating or hydrocracking) applications.
摘要翻译：公开了包含具有通常为约1至约50微米直径的含二氧化硅的纤维的纤维基材的催化剂，其有效地作为“微型气瓶”起作用。这样的催化剂可显着改善物理表面积，例如每单位长度的反应器或反应区。最初存在于用于形成纤维基材的纤维材料的含二氧化硅的纤维中的二氧化硅的至少一部分转化成保持沉积的沸石（例如，具有至少约150的SiO 2 / Al 2 O 3比例）在这些纤维上。纤维基质具有重要的性质，例如在酸性方面，其可用于加氢处理（例如加氢处理或加氢裂化）应用。

45. 发明授权

US08865121B2 Organotemplate-free synthetic process for the production of a zeolitic material 有权
标题翻译：用于生产沸石材料的无机合成方法
公开(公告)号：US08865121B2
公开(公告)日：2014-10-21
申请号：US12486983
申请日：2009-06-18
申请人： Feng-Shou Xiao , Bin Xie , Ulrich Mueller , Bilge Yilmaz
发明人： Feng-Shou Xiao , Bin Xie , Ulrich Mueller , Bilge Yilmaz
IPC分类号： C01B39/46 , C10G11/18 , B01J29/70 , B01J29/76 , B01J35/04 , B01J35/10 , B01J29/74 , B01J29/88 , B01J35/00 , B01J29/78 , C10G11/05 , B01D53/94 , B01D53/02 , B01J37/00 , B01J29/18
CPC分类号： B01J29/7007 , B01D53/02 , B01D53/94 , B01D53/9413 , B01D2251/2062 , B01D2251/2067 , B01D2255/20738 , B01D2255/502 , B01D2257/402 , B01D2257/404 , B01D2257/406 , B01D2257/702 , B01D2257/80 , B01J29/18 , B01J29/7415 , B01J29/7615 , B01J29/7815 , B01J29/88 , B01J35/002 , B01J35/04 , B01J35/1019 , B01J35/1023 , B01J37/0009 , C01B39/46 , C10G11/05 , C10G11/18 , C10G2300/405 , Y02C20/10 , Y02P20/153
摘要： The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO2; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X2O3; the mixture according to step (1) comprises at least one source for X2O3, and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
摘要翻译：本发明涉及一种用于生产具有包含YO 2和任选地包含X 2 O 3的BEA骨架结构的沸石材料的无机模板合成方法，其中所述方法包括以下步骤：（1）制备包含晶种和至少一种来源为YO2; 和（2）使混合物结晶; 其中Y是四价元素，X是三价元素，其中沸石材料任选地包含至少一种碱金属M，其中当BEA骨架另外包含X 2 O 3时; 根据步骤（1）的混合物包含至少一种X 2 O 3源，并且其中所述晶种包含具有BEA骨架结构的沸石材料，优选沸石β。

46. 发明申请

US20130336863A1 SCR CATALYTIC CONVERTER HAVING IMPROVED HYDROCARBON RESISTANCE 有权
标题翻译：具有改善耐油性能的SCR催化转化器
公开(公告)号：US20130336863A1
公开(公告)日：2013-12-19
申请号：US14002581
申请日：2012-03-01
申请人： Nicola Soeger , Katja Adelmann , Michael Seyler , Thomas R. Pauly , Gerald Jeske
发明人： Nicola Soeger , Katja Adelmann , Michael Seyler , Thomas R. Pauly , Gerald Jeske
IPC分类号： B01J29/80 , B01J29/78 , B01D53/94 , B01J29/46 , B01J29/12 , B01J29/18 , B01J29/76
CPC分类号： B01J29/126 , B01D53/9418 , B01D2251/2062 , B01D2255/206 , B01D2255/50 , B01D2255/9022 , B01D2255/9205 , B01D2258/012 , B01J29/068 , B01J29/072 , B01J29/076 , B01J29/185 , B01J29/46 , B01J29/65 , B01J29/7615 , B01J29/7838 , B01J29/80 , B01J33/00 , B01J35/023 , B01J37/0244 , B01J37/0246 , F01N3/2066 , F01N2610/02 , Y02T10/24 , Y10S502/52712
摘要： A catalyst for the selective catalytic reduction of nitrogen oxides in diesel engine exhaust gases using ammonia or a precursor compound decomposable to ammonia is described. The catalyst comprises two superposed coatings applied to a support body, of which the first coating applied directly to the support body comprises a transition metal-exchanged zeolite and/or a transition metal-exchanged zeolite-like compound, and effectively catalyzes the SCR reaction. The second coating has been applied to the first coating so as to cover it on the exhaust gas side. It is configured so as to prevent the contact of hydrocarbons having at least three carbon atoms present in the exhaust gas with the layer beneath, without blocking the passage of nitrogen oxides and ammonia to the first coating. The second coating may be formed from small-pore zeolites and/or small-pore zeolite-like compounds, and from suitable oxides, especially silicon dioxide, germanium dioxide, aluminum oxide, titanium dioxide, tin oxide, cerium oxide, zirconium dioxide and mixtures thereof. As well as the catalyst, routes for production thereof are described.
摘要翻译：描述了使用氨或可分解成氨的前体化合物来选择性催化还原柴油机废气中的氮氧化物的催化剂。催化剂包括施加到支撑体上的两个重叠的涂层，其中直接施加到支撑体上的第一涂层包括过渡金属交换的沸石和/或过渡金属交换的沸石样化合物，并有效地催化SCR反应。已经将第二涂层施加到第一涂层上以便将其覆盖在排气侧。它被构造成防止废气中存在的至少三个碳原子的烃与下面的层接触，而不阻挡氮氧化物和氨通到第一涂层。第二涂层可以由小孔沸石和/或小孔沸石类化合物形成，并且可以由合适的氧化物，特别是二氧化硅，二氧化锗，氧化铝，二氧化钛，氧化锡，氧化铈，二氧化锆和混合物形成其中。除了催化剂之外，还描述了生产途径。

47. 发明申请

US20130267748A1 Catalyst Regeneration Process 有权
标题翻译：催化剂再生过程
公开(公告)号：US20130267748A1
公开(公告)日：2013-10-10
申请号：US13811403
申请日：2011-07-20
申请人： James H. Beech, JR. , Julia E. Steinheider , Doron Levin , Selma S. Lawrence
发明人： James H. Beech, JR. , Julia E. Steinheider , Doron Levin , Selma S. Lawrence
IPC分类号： C07C2/12 , B01J29/08 , B01J29/40 , B01J29/18 , B01J29/70
CPC分类号： C07C2/12 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/7034 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J29/90 , B01J37/18 , B01J37/20 , B01J38/14 , B01J38/16 , B01J38/20 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/08
摘要： This disclosure relates to a process for regenerating a catalyst composition to improve the aging rate in subsequent cycles.
摘要翻译：本公开涉及一种用于再生催化剂组合物以改善随后循环中的老化速率的方法。

48. 发明申请

US20120108415A1 METHOD FOR FORMING AN ALUMINOSILICATE-ZEOLITE LAYER ON A METAL SUBSTRATE, THE COATED SUBSTRATE AND THE USE THEREOF 有权
公开(公告)号：US20120108415A1
公开(公告)日：2012-05-03
申请号：US13254057
申请日：2010-03-01
申请人： Ralph Herrmann , Wilhelm Schwieger , Jurgen Bauer
发明人： Ralph Herrmann , Wilhelm Schwieger , Jurgen Bauer
IPC分类号： B01J20/18 , B01J20/32 , B01J29/08 , B01J37/08 , B01J29/06 , B01J29/18
CPC分类号： C23C18/1212 , B01J20/165 , B01J20/3238 , B01J29/06 , C23C18/1241 , C23C22/66
摘要： A method is described for forming an aluminosilicate-zeolite layer on an aluminium-containing substrate which is transferred into an aqueous reaction dispersion containing silicon and optionally aluminium as network-forming elements, wherein, irrespective of whether or not aluminium is present in the aqueous reaction dispersion, the molar ratio of the aluminium in the aqueous reaction dispersion, optionally 0, to the sum of the designated network-forming elements contained in the aqueous reaction dispersion ranges between 0 and about 0.4, the aqueous reaction dispersion containing the aluminium-containing substrate is heated, and aluminium is extracted from the aluminium-containing substrate for the aluminosilicate-zeolite formation process, and the layer of an aluminosilicate-zeolite is formed on the aluminium-containing substrate by in situ direct crystallization. This method is characterized in that a layer of an aluminium-rich aluminosilicate-zeolite having an Si/Al ratio of lower than 5 is formed on the aluminium-containing substrate by introducing into the aqueous reaction dispersion a Si source in an amount sufficient for forming the Si/Al ratio of lower than 5, and an Al source that meets the requirement of the molar substoichiometric value, and the aluminium-containing metal substrate, wherein the pH value of the aqueous reaction dispersion is alkalinized and the layer of the aluminium-rich aluminosilicate-zeolite is crystallized onto the aluminium-containing metal substrate.Advantageous coatings of an aluminium-rich aluminosilicate-zeolite on an aluminium-containing metal substrate are obtained by this method. This product can be provided for advantageous applications, especially in sorption-based fields of application, such as for heterogeneous catalysis, in separation and cleaning processes, in sorption heat pumps, in conjunction with immobilized catalysts and in microreaction technology.

49. 发明申请

US20110172482A1 CATALYST BASED ON A CRYSTALLIZED MATERIAL WITH HIERARCHIZED AND ORGANIZED POROSITY AND ITS USE IN OLIGOMERIZATION OF LIGHT OLEFINS 失效
标题翻译：基于结晶化材料的催化剂，具有分层和组织的孔隙度，并且用于轻质烯烃的低分子化
公开(公告)号：US20110172482A1
公开(公告)日：2011-07-14
申请号：US12994194
申请日：2009-04-28
申请人： Amandine Cabiac , Alexandra Chaumonnot , Laurent Simon
发明人： Amandine Cabiac , Alexandra Chaumonnot , Laurent Simon
IPC分类号： C07C2/02 , B01J21/06 , B01J35/10 , B01J29/04 , B01J29/18 , B01J29/65 , B01J29/70 , B01J21/02 , B01J21/04 , B01J21/16 , B01J21/14 , B01J27/182 , B01J21/18
CPC分类号： C07C2/12 , B01J29/041 , B01J29/06 , B01J29/40 , B01J29/7007 , B01J35/023 , B01J37/0009 , B01J37/0045 , B01J2229/42 , C07C2529/40 , C07C2529/70 , C10G50/00
摘要： A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.
摘要翻译：描述了一种催化剂，其包含至少一种粘合剂和至少一种在微孔和中孔性的领域中具有分级和有组织的孔隙率的结晶材料，由此所述结晶材料由至少两个基本球形颗粒组成，每个所述颗粒包含介孔结构的硅基于氧化物的基质，其中孔直径在1.5至30nm之间，并且具有厚度在1至60nm之间的微孔和结晶壁，由此所述基本球形颗粒的最大直径为200微米。所述催化剂用于含有每分子具有2至12个碳原子的烃分子的烯烃原料低聚的方法。

50. 发明申请

US20110047988A1 CATALYST AND METHOD OF MANUFACTURE 有权
标题翻译：催化剂及其制造方法
公开(公告)号：US20110047988A1
公开(公告)日：2011-03-03
申请号：US12550970
申请日：2009-08-31
申请人： Larry Neil Lewis , Benjamin Hale Winkler , Dan Hancu , Daniel George Norton , Ashish Balkrishna Mhadeshwar
发明人： Larry Neil Lewis , Benjamin Hale Winkler , Dan Hancu , Daniel George Norton , Ashish Balkrishna Mhadeshwar
IPC分类号： F01N3/10 , B01J23/50 , B01J31/02 , B01J29/04 , B01J29/40 , B01J29/18
CPC分类号： B01J35/0006 , B01D53/9418 , B01D53/945 , B01D53/9477 , B01D2251/208 , B01D2255/104 , B01D2255/20707 , B01D2255/2073 , B01D2255/20776 , B01J21/04 , B01J23/50 , B01J29/061 , B01J29/072 , B01J35/1061 , B01J37/0215 , F01N3/2807 , F01N3/36 , F01N13/009 , F01N2240/30 , Y02T10/20 , Y02T10/22
摘要： A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.
摘要翻译：一种催化剂体系，其包含第一催化剂组合物，其包含设置在金属无机载体上的第一催化材料; 其中所述金属无机载体具有孔; 和至少一种促进金属。催化剂体系还包括第二催化剂组合物，其包含（i）沸石，或（ii）设置在第一基材上的第一催化材料，所述第一催化材料包含选自钨，钛和钒的元素。催化剂体系还可包含第三催化组合物。催化剂体系还可以包括配置成递送还原剂和任选的共还原剂的递送系统。还提供了包含第一催化组合物，第二催化组合物和第三催化组合物的催化剂体系。还提供了包括本文所述的催化剂体系的排气系统。

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