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    • 49. 发明申请
    • FLASH SPINNING PROCESS
    • 闪纺纺纱工艺
    • US20160362816A1
    • 2016-12-15
    • US15172753
    • 2016-06-03
    • E I DU PONT DE NEMOURS AND COMPANY
    • CORNEILLE SCHMITZJAN VAN MEERVELDOREST SKOPLYAKSERGE REBOUILLAT
    • D01F6/06D01F1/10D01D11/00D01D5/11D01D1/02
    • D01F6/06D01D1/02D01D5/11D01D11/00D01F1/10
    • A process for the preparation of plexifilamentary film-fibril strands of polymer. The process includes the steps of generating a spin fluid containing (a) 5 to 30 wt. % containing one or more polymer types, (b) a primary spin agent selected from the group consisting of dichloromethane, cis-1,2-dichloroethylene and trans-1,2-dichloroethylene, and (c) a co-spin agent comprising 1H,6H-perfluorohexane or 1H-perfluorohexane or 1H-perfluoroheptane. The spin fluid is flash-spun at a pressure that is greater than the autogenous pressure of the spin fluid into a region of lower pressure to form plexifilamentary film-fibril strands of the polymer. The co-spin agent is present in the spin fluid in an amount sufficient to form an azeotrope-like composition with the primary spin agent in the presence of the one or more polymer types. The polymer may be selected from the group consisting of high density polyethylene, polypropylene, polybutene-1, polymethylpentene, polyvinylidene fluoride, poly (ethylene tetrafluoroethylene), and blends of the foregoing.
    • 制备聚合物丛状薄膜 - 原纤维股线的方法。 该方法包括以下步骤:产生含有(a)5-30wt。 含有一种或多种聚合物类型的(%)(b)选自二氯甲烷,顺式-1,2-二氯乙烯和反式-1,2-二氯乙烯的初级旋转剂,和(c)包含1H ,6H-全氟己烷或1H-全氟己烷或1H-全氟庚烷。 旋转流体在大于旋转流体进入低压区域的自生压力的压力下闪蒸,以形成聚合物的有丝纤维膜 - 原纤维股线。 共旋转剂存在于旋转流体中,其量足以在一种或多种聚合物类型的存在下与主旋转剂形成类共沸组合物。 聚合物可以选自高密度聚乙烯,聚丙烯,聚丁烯-1,聚甲基戊烯,聚偏二氟乙烯,聚(乙烯四氟乙烯)和上述的共混物。