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    • 48. 发明授权
    • High overbased metal sulfurized alkyphenates
    • 高碱性金属硫化烷基酚盐
    • US5759966A
    • 1998-06-02
    • US722734
    • 1996-10-01
    • Curtis B. Campbell
    • Curtis B. Campbell
    • C10M159/22C10N10/04C10N30/04C10N30/12C10N40/25C10N60/00C10N70/00C10M135/02
    • C10M159/22
    • Process for preparing high overbased metal sulfurized alkylphenates, wherein a majority of the alkalinity is provided by at least a stoichiometric excess of metal. The process is characterized by a sulfurization reaction using a promoter, followed by overbasing with carbon dioxide, a polyamine, and additional metal base in the presence of an alkylene glycol under reactive conditions at temperatures in the range of about from 150.degree. C. to 190.degree. C. The process affords a metal sulfurized phenate product which is substantially insensitive to overcarbonation, which exhibits low corrosive wear, and which exhibits high rates of acid neutralization. These compositions are useful in the formulation of marine cylinder lubricants.
    • 制备高碱性金属硫化烷基酚盐的方法,其中大部分碱度由至少化学计量过量的金属提供。 该方法的特征在于使用促进剂的硫化反应,随后在反应条件下在约150℃至190℃的温度范围内在亚烷基二醇存在下,用二氧化碳,多胺和另外的金属碱进行高碱性化 该方法提供对过度碳酸化基本上不敏感的金属硫化酚盐产物,其表现出低腐蚀性磨损,并且其表现出高的酸中和速率。 这些组合物可用于制备船用润滑油。
    • 49. 发明授权
    • Lubricant additives
    • 润滑添加剂
    • US5756433A
    • 1998-05-26
    • US652276
    • 1996-05-22
    • Clemens AuschraHorst Pennewiss
    • Clemens AuschraHorst Pennewiss
    • C08F290/00C08F290/04C10M145/14C10M149/06C10M149/10C10N30/02C10N30/04
    • C10M149/06C10M145/14C10M149/10C10M2209/084C10M2217/024C10M2217/028C10M2217/06
    • A composition comprising a carrier and a comb copolymer made by copolymerizing a polyalkyl (meth)acrylate macromonomer, present in an amount of 10-90 wt %, with the following monomers in a total amount of 90-10 wt %: (a) 0-90 wt % of C.sub.6 -C.sub.30 alkyl (meth)acrylates, (b) 0-60 wt % of nonfunctionalized comonomers selected form the group consisting of C.sub.1 -C.sub.5 alkyl (meth)acrylates, styrene, C.sub.1 -C.sub.4 alkyl styrenes, and vinyl esters of C.sub.2 -C.sub.12 carboxylic acids, and (c) 0-40 wt % of functionalized comonomers selected from the group consisting of functionalized (meth)acrylic acid esters and amides, and vinyl heterocyclic compounds, all of the above amounts based on the weight of the graft copolymer. The composition is especially useful as a lubricating oil additive with viscosity index-improving effect.
    • 通过以10-90重量%的量聚合(甲基)丙烯酸烷基酯大分子单体与总量为90-10重量%的以下单体共聚制得的载体和梳状共聚物组合物:(a)0 -90重量%的(甲基)丙烯酸C 6 -C 30烷基酯,(b)0-60重量%的选自以下的非官能化共聚单体:(甲基)丙烯酸C 1 -C 5烷基酯,苯乙烯,C 1 -C 4烷基苯乙烯和乙烯基 C2-C12羧酸的酯,和(c)0-40重量%的选自官能化的(甲基)丙烯酸酯和酰胺的官能化共聚单体和乙烯基杂环化合物,所有上述量基于重量 的接枝共聚物。 该组合物特别适用于具有粘度指数提高效果的润滑油添加剂。