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    • 44. 发明授权
    • Catalyst for preparing unsaturated nitriles
    • 用于制备不饱和硝酸盐的催化剂
    • US3847831A
    • 1974-11-12
    • US7643870
    • 1970-09-29
    • STAMICARBON
    • SLOT HGEUS J
    • B01J23/28B01J23/31B01J23/34B01J23/88B01J23/881B01J23/887B01J11/22
    • C07C253/26B01J23/28B01J23/31B01J23/34B01J23/88B01J23/881B01J23/8876Y02P20/52C07C255/08
    • 1. A PROCESS FOR THE PREPARATION OF A CATALYST SYSTEM CONTAINING OXIDES OF BISMUTH, MOLYBDENUM AND IRON WHICH CONSISTS ESSENTIALLY IN CARRYING OUT THE STEPS OF: (A) FORMING AN AQUEOUS ACID SOLUTION CONTAINING IONS OF BISMUTH, AND IONS OF IRON IN AN ATOMIC RATIO NO GREATER THAN 0.4:1 RELATIVE TO SAID BISMUTH IONS, AND AN AQUEOUS ALKALINE SOLUTION, INJECTING ONE OF SAID SOLUTIONS INTO THE OTHER WHILE MAINTAINING THE PH OF THE RESULTING AQUEOUS SOLUTION AT A VIRTUALLY CONSTANT VALUE OF AT LEAST ABOUT 7 WHEREBY A PRECIPITATE OF COMPOUNDS OF SAID IONS IS FORMED, AND SEPARATING SAID PRECIPITATE FROM SAID RESULTING AQUEOUS SOLUTION; (B) FORMING A SUSPENSION OF SAID PRECIPITATE IN AN AQUEOUS MEDIUM, ADJUSTING THE PH OF SAID SUSPENSION TO A VALUE OF BETWEEN ABOUT 2.5 AND 7, AND WHILE HEATING AND AGITATING SAID SUSPENSION, AND MAINTAINING THE PH OF SAID SUSPENSION AT A VALUE OF GREATER THAN ABOUT 2.5, INTRODUCING AN AQUEOUS SOLUTION OF AMMONIUM MOLYBDATE INTO SAID SUSPENSION IN AN AMOUNT IN EXCESS OF A MOLYBDENUM TO BISMUTH ATOMIC RATIO OF ABOUT 1:1 BY AN AMOUNT OF MOLYBDENUM STOICHIOMETRICALLY EQUIVALENT TO THE QUANTITY OF IRON PRECIPITATED IN STEP (A), AND AT A RATE NO GREATER THAN 0.1 GRAM MOLE OF MOO4 PER LITER OF SUSPENSION PER HOUR, THEREAFTER HEATING SAID SUSPENSION AT OR NEAR THE BOILING TEMPERATURE FOR A PERIOD OF AT LEAST 6 HOURS WHEREBY SUBSTANTIALLY ALL OF SAID MOLYBDENUM IS TAKEN UP BY SAID PRECIPITATE.
    • 46. 发明授权
    • Method for preparation of olefin oxidation catalyst
    • 烯烃氧化催化剂的制备方法
    • US3844981A
    • 1974-10-29
    • US25992972
    • 1972-06-05
    • EXXON RESEARCH ENGINEERING CO
    • CUSUMANO J
    • B01J23/48B01J23/50B01J23/68B01J23/70B01J23/89B01J11/08B01J11/22
    • B01J23/8926B01J23/48B01J23/50B01J23/688B01J23/70B01J23/89B01J23/8946
    • A method for preparing an olefin oxidation catalyst, which comprises impregnating silver oxide or a water-insoluble silver salt, e.g. silver carbonate, silver carboxylates (having from 1 to 10 carbon atoms), silver chloride, etc., having a surface area of from 20 to 40 m2/g, preferably from 25 to 35 m2/g, with a solution containing a decomposable salt, selected from the group consisting of salts of Groups VII-B, I-B, or the iron group of Group VIII of the Periodic Table of the Elements, drying said impregnated salt, and activating by contacting with a reducing environment. Preferably the silver compound is silver oxide and said decomposable salt is selected from the group consisting of gold, copper, rhenium, manganese, and iron salts. The catalysts prepared by the instant method are especially effective in the oxidation of ethylene to ethylene oxide.
    • 一种制备烯烃氧化催化剂的方法,其包括将氧化银或不溶于水的银盐浸渍在其中。 表面积为20〜40m2 / g,优选为25〜35m2 / g的碳酸银,羧酸银(具有1〜10个碳原子),氯化银等,与含有可分解盐的溶液 ,选自元素周期表第VII-B族,第IB族或第VIII族的铁族的组,干燥所述浸渍的盐,并通过与还原环境的接触进行活化。 优选地,银化合物是氧化银,并且所述可分解盐选自金,铜,铼,锰和铁盐。 通过本方法制备的催化剂在乙烯氧化成环氧乙烷方面特别有效。