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    • 44. 发明申请
    • In-drum pyrolysis system
    • 鼓内热解系统
    • US20080039674A1
    • 2008-02-14
    • US11717970
    • 2007-03-14
    • J. Mason
    • J. Mason
    • A62D3/00
    • G21F9/32B01D53/75C10B47/46F23G5/006F23G5/0276F23G2201/301F23G2209/18F23G2900/50205F23G2900/54401F23J2217/10F23J2219/10F23J2219/60
    • An apparatus and method for processing hazardous wastes directly from 55-gallon drums through the use of pyrolysis and steam reforming. The method is based on a pyrolyzer using heat to vaporize organics that are present in the hazardous wastes. The waste is heated in the original drums to avoid the bulk handling of alpha radionuclides and to ensure criticality control. At pyrolysis temperatures, all liquids and organics in the drums will evaporate and volatize. The resulting waste in the drums is a dry, inert, inorganic matrix with carbon char containing radioactive metals. The off-gas produced by pyrolysis mainly consists of water vapor, volatized organics, and acid gases from the decomposition of various plastics and other organics present in the waste drums. The off-gas produced by the pyrolysis is then collected and fed into an off-gas treatment system that is in fluid communication with pyrolyzer operated under oxidizing conditions.
    • 通过使用热解和蒸汽重整从55加仑桶直接加工危险废物的设备和方法。 该方法基于使用热量蒸发危险废物中存在的有机物的热解器。 废弃物在原始鼓中加热,以避免大量处理α放射性核素并确保临界控制。 在热解温度下,鼓中的所有液体和有机物将蒸发并挥发。 在鼓中产生的废物是具有含有放射性金属碳的干燥,惰性的无机基质。 由热解产生的废气主要由水蒸汽,挥发的有机物和来自废弃桶中存在的各种塑料和其它有机物的酸性气体组成。 然后通过热解产生的废气被收集并进料到在氧化条件下操作的热解器流体连通的废气处理系统中。
    • 45. 发明授权
    • Process for non-incineration decontamination of hazardous agents
    • 非焚烧除害危险品的方法
    • US07309808B1
    • 2007-12-18
    • US10677954
    • 2003-10-01
    • John A. ScottJames Osterloh
    • John A. ScottJames Osterloh
    • A62D3/00
    • A62D3/20A62D2101/02
    • A process for the low temperature, non-incineration decontamination of contaminated materials, such as chemical weapon components containing residual quantities of chemical warfare agents. The process includes the steps of (a) contacting the contaminated materials with steam at substantially ambient pressure in a substantially dry first heated vessel for a period of at least about 15 minutes, the steam being at a temperature of at least about 560° C., (b) removing condensible and non-condensible gases from the first heated vessel and heating them in a second vessel at substantially ambient pressures to temperatures of at least about 500° C. for a period of at least about one second in an atmosphere containing steam, and (c) catalytically treating non-condensible gases from the second vessel in the presence of oxygen so as to reduce the concentration of chemical warfare agents to less than about 1.0 mg/m3 at standard temperature and pressure.
    • 一种对受污染物质进行低温,非焚烧净化的过程,如含有剩余量的化学战剂的化学武器成分。 该方法包括以下步骤:(a)将基本环境压力下的受污染物质与基本上干燥的第一加热容器中的蒸汽接触至少约15分钟,蒸汽处于至少约560℃的温度。 ,(b)从第一加热容器中除去可冷凝和不可冷凝的气体,并将其在基本环境压力下在第二容器中加热至至少约500℃的温度至少约1秒的时间, 蒸汽,和(c)在氧气存在下催化处理来自第二容器的不可冷凝气体,以便在标准温度下将化学战剂的浓度降低至小于约1.0mg / m 3 和压力。
    • 46. 发明授权
    • Method of removing heavy metals from silicate sources during silicate manufacturing
    • US07297318B2
    • 2007-11-20
    • US11282059
    • 2005-11-17
    • Yung-Hui HuangJohn V. Offidani
    • Yung-Hui HuangJohn V. Offidani
    • A62D3/00C01B33/30
    • C01B33/32C01B33/20
    • Methods for the removal of lead from a metal silicate during the process of manufacturing of such a material are provided. With the reliance upon lower cost starting silicon dioxide starting materials that are known to exhibit elevated amounts of heavy metal therein for the purpose of producing metal silicates (such as sodium silicate, as one example), it has been realized that removal of significant amounts of such heavy metals is necessary to comply with certain regulatory requirements in order to provide a finished material that exhibits the same low level of heavy metal contamination as compared with finished materials that are made from more expensive, purer starting silicon dioxides. Two general methods may be followed for such decontamination purposes. One entails the introduction of a calcium phosphate material, such as dicalcium phosphate, tricalcium phosphate, and/or hydroxyapatite, to a formed metal silicate solution but prior to filtering. The other requires the introduction of calcium phosphate material (again, hydroxyapatite, tricalcium phosphate, and/or dicalcium phosphate) in a silicon dioxide, caustic, and water slurry with said dicalcium phosphate thus present throughout the overall reaction steps of metal silicate formation and is removed by filtering. In each situation, the hydroxyapatite, tricalcium phosphate, or dicalcium phosphate actually aids in rendering immobile the heavy metals therein, such as lead, cadmium, and the like, thereby preventing release of high amounts of bioavailable amounts of such heavy metals from products for which the target metal silicates are considered reactants. Thus, the heavy metal-containing metal silicates may then be utilized to produce precipitated silicas, as one example, that exhibit much lower levels of bioavailable heavy metals as compared with the original silicon dioxide source.