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    • 43. 发明申请
    • THERMOPLASTIC POLYMER MICROFIBERS, NANOFIBERS AND COMPOSITES
    • 热塑性聚合物微胶囊,纳米纤维和复合材料
    • US20100233458A1
    • 2010-09-16
    • US12310612
    • 2007-08-31
    • Gang SunDong Wang
    • Gang SunDong Wang
    • B32B5/02D01D5/00B29C47/06D02G3/00
    • D01F6/92D01F2/28D01F6/46D01F8/02D01F8/14D01F8/18Y10T428/249924Y10T428/298
    • The present invention provides methods of making micron, submicron or nanometer dimension thermoplastic polymer microfibrillar composites and fibers, and methods of using the thermoplastic polymer microfibers and nanofibers in woven fabrics, biocidal textiles, biosensors, membranes, filters, protein support and organ repairs. The methods typically include admixing a thermoplastic polymer and a matrix material to form a mixture, where the thermoplastic and the matrix are thermodynamically immiscible, followed by extruding the mixture under conditions sufficient to form a microfibrillar composite containing a plurality of the thermoplastic polymer microfibers and/or nanofibers embedded in the matrix material. The microfibers and/or nanofibers are isolated by removing the surrounding matrix. In one embodiment, the microfibrillar composite formed is further extended under conditions sufficient to form a drawn microfibrillar and/or nanofibrillar composite with controlled diameters.
    • 本发明提供制造微米级,亚微米级或纳米级热塑性聚合物微原纤维复合材料和纤维的方法,以及在机织织物,杀生物杀菌纺织品,生物传感器,膜,过滤器,蛋白质载体和器官修复中使用热塑性聚合物微纤维和纳米纤维的方法。 所述方法通常包括混合热塑性聚合物和基质材料以形成混合物,其中热塑性和基质是热力学上不混溶的,随后在足以形成含有多种热塑性聚合物微纤维和/ 或嵌入基质材料中的纳米纤维。 通过除去周围的基质来分离微纤维和/或纳米纤维。 在一个实施方案中,形成的微原纤维复合材料在足以形成具有受控直径的拉伸微原纤维和/或纳米纤维复合材料的条件下进一步延伸。
    • 45. 发明授权
    • Process of making lyocell fibre or film
    • 制作莱赛尔纤维或薄膜的方法
    • US06258304B1
    • 2001-07-10
    • US09380951
    • 1999-09-10
    • Hardev Singh Bahia
    • Hardev Singh Bahia
    • B29C6720
    • C08J5/18C08J2301/02D01F2/00D01F8/02D01F8/06D01F8/12D01F8/14
    • Lyocell fibres contain elongated domains of polyester, polyamide or an olefin copolymer, the domains having an aspect ratio at least 1.5 and being aligned substantially parallel to the axis of the fibre. A process for the preparation of lyocell fibre or film by extruding a solution of cellulose in amine oxide through a spinneret or film die at elevated temperature via an air gap into an aqueous precipitation bath is characterised in that 0.1 to 60 wt % based on cellulose of a thermoplastic low-melting polymer is incorporated into the cellulose solution. A process for the preparation of a bicomponent fibre by extruding two polymers through a spinneret in side-by-side relationship at elevated temperature is characterised in that one of the polymers is a solution of cellulose in amine oxide and the other polymer is a molten thermoplastic polymer having a melting point above 25° C. but below the extrusion temperature.
    • Lyocell纤维包含聚酯,聚酰胺或烯烃共聚物的细长结构域,所述畴的纵横比至少为1.5,并且基本上平行于纤维的轴线排列。 通过将纤维素在氧化胺中的溶液通过喷丝头或薄膜模具在高温下通过空气间隙挤出到水性沉淀浴中来制备莱赛尔纤维或薄膜的方法,其特征在于基于纤维素的0.1-60重量% 将热塑性低熔点聚合物掺入纤维素溶液中。 通过在高温下以并列关系通过喷丝头挤出两种聚合物制备双组分纤维的方法的特征在于,一种聚合物是纤维素在氧化胺中的溶液,另一种聚合物是熔融热塑性塑料 聚合物的熔点高于25℃但低于挤出温度。
    • 47. 发明授权
    • Readily fibrillatable fiber
    • 易纤维纤维
    • US6048641A
    • 2000-04-11
    • US237810
    • 1999-01-27
    • Akio OhmoryHayami YoshimochiTomoyuki SanoSatoru KobayashiSyunpei NaramuraMasahiro Satoh
    • Akio OhmoryHayami YoshimochiTomoyuki SanoSatoru KobayashiSyunpei NaramuraMasahiro Satoh
    • D01F8/02D01F8/10H01M2/16
    • D01F8/10D01F8/02
    • A fiber of sea-islands phase separation wherein the sea component comprises a vinyl alcohol based polymer with high orientation and great crystallinity and the islands component comprises a water-insoluble cellulose based polymer with excellent absorptivity of alkaline solutions, thermal resistance and heat fusion resistance, and wherein the size of the islands is 0.03 to 10 .mu.m and the strength is 3 g/d or more, is readily disintegrated into a fibril of a diameter of 0.05 to 8 .mu.m when a mechanical stress is imposed onto the fiber wet in water. From the fibril with good hydrophilicity, high strength, great particle captivity and excellent reinforcing performance, and additionally with good absorptivity of alkaline solutions and great thermal resistance and heat fusion resistance, none of the fiber components therein is solubilized during fibrillation. Neither a beating process nor a beating solution causes foaming or environmental pollution. The fibril is extremely useful for use in separator sheets for alkaline batteries, reinforcing fibers of cement slate plates, reinforcing fibers of frictional materials and the like.
    • 海岛相分离纤维,其中海组分包含具有高取向和高结晶度的乙烯醇基聚合物,岛组分包括具有优异的碱溶液吸收性,耐热性和耐热熔性的水不溶性纤维素基聚合物, 并且其中岛的尺寸为0.03〜10μm,强度为3g / d以上时,当对纤维进行机械应力湿润时,容易分解成直径为0.05〜8μm的原纤维 水。 从具有良好亲水性,高强度,巨大的颗粒俘获和优异的增强性能的原纤维,另外具有良好的碱溶液吸收性和高耐热性和耐热熔性,其中纤维成分在原纤维化过程中不溶解。 打浆过程和打浆液都不会引起起泡或环境污染。 原纤维非常适用于碱性电池用隔板,水泥板状板的增强纤维,摩擦材料的增强纤维等。