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    • 41. 发明授权
    • Composite particle dispersions
    • 复合颗粒分散体
    • US4997864A
    • 1991-03-05
    • US301052
    • 1989-01-24
    • Julian A. Waters
    • Julian A. Waters
    • B01J13/04B01J13/00C08J3/00C08J3/21C09D5/00
    • C08J3/005C08J3/212
    • A process for the preparation of composite particle dispersons is disclosed. The composite particles have a core particle 1 surrounded by a second material 2. Normally a core shell particle will be formed and the second material which forms the shell will be a polymer material.The composite particles are formed by mixing a dispersion of polymer particles with pre-formed core material particles. The polymer particles are stabilized relative to one another, and the core material particles are destabilized in the dispersion so that they are able to make contact with the surfaces of the polymer particles. The process takes place at a temperature above the operative glass transition temperature of the polymer, and in the process the polymer spreads over the surface of the core particle so that the core particle is encapsulated.The process will proceed, and composite particles will be formed, when the interfacial energies of the three interfaces (core/polymer: core/liquid: polymer/liquid) and the relative volumes of the core particles and polymer particles are related to one another in accordance with an equation which is set out in the specification.
    • 42. 发明授权
    • Pigment composition and preparation process thereof
    • 颜料组合物及其制备方法
    • US4713411A
    • 1987-12-15
    • US869325
    • 1986-06-02
    • Kazuo KanouTakamitu ShinodaYukio Kanbara
    • Kazuo KanouTakamitu ShinodaYukio Kanbara
    • C08L33/00C08J3/21C08L33/02C08L33/10C09B67/08C09B67/20C08J3/04
    • C08J3/212C09B67/0013C09B67/0063
    • A pigment composition is composed of an intimate mixture of an organic pigment and a polymer. The content of the organic pigment is 75-95 wt. % based on the whole pigment composition. Monomers which form the polymer include 0-40 wt. % of styrene, 20-70 wt. % of a methacrylic ester and 20-50 wt. % of methacrylic acid. The total proportion of styrene, the methacrylic ester and methacrylic acid is at least 85 wt. % of the entire monomers. The pigment composition is prepared by mixing the organic pigment with an aqueous alkaline solution, which contains the polymer and an alkali metal salt, alkali metal hydroxide, lower amine or ammonium, to form an aqueous dispersion. The organic pigment and polymer are then subjected to coprecipitation, preferably, by lowering the pH of the aqueous dispersion beyond 7.0.
    • 颜料组合物由有机颜料和聚合物的紧密混合物组成。 有机颜料的含量为75-95wt。 基于整个颜料组成的%。 形成聚合物的单体包括0-40wt。 %的苯乙烯,20-70wt。 %的甲基丙烯酸酯和20-50wt。 %甲基丙烯酸。 苯乙烯,甲基丙烯酸酯和甲基丙烯酸的总比例至少为85wt。 %的整个单体。 通过将有机颜料与含有聚合物和碱金属盐,碱金属氢氧化物,低级胺或铵的碱性水溶液混合以形成水分散体来制备颜料组合物。 然后将有机颜料和聚合物进行共沉淀,优选通过将水分散体的pH降低至7.0以上。