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    • 41. 发明申请
    • PROCESS TO PREPARE BIAXIALLY ORIENTED FILM
    • US20170327653A1
    • 2017-11-16
    • US15525639
    • 2015-11-12
    • DSM IP ASSETS B.V.
    • Hao CHENAlexander Antonius Marie STROEKSRoman STEPANYAN
    • C08J5/18B29C47/00
    • C08J5/18B29C48/146C08J2377/02C08J2477/06
    • The invention relates to a process for preparing a biaxially oriented film, comprising the following steps: a) Melting a composition comprising at least 50 wt % with respect to the total amount of the composition of a copolyamide comprising: i. At least 75 wt % monomeric units derived from caprolactam, and further monomeric units derived from diamines X and/or diacids Y and/or aminoacids Z in a summed amount of between 0.2 to 25 wt %; or ii. At least 75 wt % monomeric units derived from hexamethylene diamine and adipic acid, and further monomeric units derived from diamines X and/or diacids Y and/or aminoacids Z in a summed amount of between 0.2 to 25 wt %; into a polymer melt; b) Casting the polymer melt through a planar die to form a film of at least one layer and subsequently quenching the film to a temperature of below Tg of the copolyamide; c) Stretching the film obtained after quenching in a direction parallel to the machine (MD-stretching) with a factor of at least 2 at a temperature of at least Tg of the copolyamide; d) Stretching the film obtained after MD stretching in a direction transversal to the machine (TD-stretching) with a factor of at least 2 at a temperature of at least Tg+10° C. of the copolyamide; e) Cooling the obtained film after TD-stretching; f) Heat setting the film obtained after cooling, at a temperature of between Tm−70° C. and Tm of the copolyamide; in which Tg and Tm of the copolyamide are determined as described by ASTM D3418-03. The invention also relates to a biaxially oriented film and food packaging obtainable by this process.
    • 45. 发明申请
    • POLYAMIDE RESIN COMPOSITION REINFORCED WITH GLASS FIBER
    • 聚酰胺树脂组合物加玻璃纤维
    • US20160053091A1
    • 2016-02-25
    • US14781366
    • 2014-04-08
    • TOYOBO CO., LTD.
    • Tomohide NAKAGAWATatsuya OIKazunari TANAKA
    • C08K7/14C08J5/04
    • C08K7/14C08J5/043C08J2377/06C08J2377/10C08J2477/06C08J2477/10C08K3/04C08L77/02C08L77/06
    • The present invention provides a polyamide resin composition reinforced with glass fiber which can produce a molded product having high anti-vibration property or, in other words, having very high resonance frequency and having, upon necessity, excellent weather-resisting color fastness. A polyamide resin composition reinforced with glass fiber, comprising a polyamide resin (A) constituted from aliphatic polyamide (a1) and aromatic component-containing polyamide (a2), and glass fibers (B) having a cross-sectional area of 1.5 to 5.0×10−6 cm2, wherein ratio by weight of the polyamide resin (A) to the glass fibers (B) [(A):(B)] is from 20:80 to 35:65 and ratio by weight of the aliphatic polyamide (a1) to the aromatic component-containing polyamide (a2) [(a1):(a2)] is from 5:95 to 95:5. The polyamide resin composition reinforced with glass fibers of the present invention can further comprise carbon black (C) in an amount of at most 5% by weight.
    • 本发明提供一种用玻璃纤维增​​强的聚酰胺树脂组合物,其可以制造具有高抗振性能的成型产品,或换句话说,具有非常高的共振频率,并且在必要时具有优异的耐候性色牢度。 由玻璃纤维增​​强的聚酰胺树脂组合物,包含由脂肪族聚酰胺(a1)和含芳香族成分的聚酰胺(a2)构成的聚酰胺树脂(A)和横截面积为1.5〜5.0×的玻璃纤维(B) 10-6cm 2,其中聚酰胺树脂(A)与玻璃纤维(B)[(A):B)]的重量比为20:80至35:65,脂族聚酰胺( a1)至含芳香族成分的聚酰胺(a2)[(a1):(a2)]为5:95〜95:5。 用本发明的玻璃纤维增​​强的聚酰胺树脂组合物还可以含有至多5重量%的碳黑(C)。