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41. 发明申请

US20150129038A1 Photovoltaic Cell Containing Novel Photoactive Polymer 审中-公开
标题翻译：含有新型光敏聚合物的光伏电池
公开(公告)号：US20150129038A1
公开(公告)日：2015-05-14
申请号：US14601693
申请日：2015-01-21
申请人： Merck Patent GmbH
发明人： Li WEN , David P. WALLER , Paul BYRNE , Nicolas DROLET , Gilles Herve Regis DENNLER , Kap-Soo CHEON
IPC分类号： H01L51/00 , C08G75/32 , C08G75/02
CPC分类号： H01L51/0036 , B82Y10/00 , C08G61/12 , C08G61/123 , C08G61/126 , C08G75/0209 , C08G75/32 , C08G2261/1426 , C08G2261/1428 , C08G2261/146 , C08G2261/312 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , C08G2261/3247 , C08G2261/414 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/1458 , C09K2211/1483 , C09K2211/1491 , H01L51/0043 , H01L51/0047 , H01L51/0094 , H01L51/424 , H01L51/4273 , H01L2251/552 , Y02E10/549 , Y02P70/521
摘要： Novel photoactive polymers, as well as related photovoltaic cells, articles, systems, and methods, are disclosed.
摘要翻译：公开了新型光活性聚合物，以及相关的光伏电池，制品，系统和方法。

42. 发明申请

US20150065664A1 GRANULAR POLYARYLENE SULFIDE AND PROCESS FOR MANUFACTURING THE SAME 有权
标题翻译：颗粒状聚氨酯硫化物及其制造方法
公开(公告)号：US20150065664A1
公开(公告)日：2015-03-05
申请号：US14378854
申请日：2013-03-29
申请人： Kureha Corporation
发明人： Akihiro Konno , Ken-Ichi Takaki , Yui Yoshida , Yasuhiro Suzuki
IPC分类号： C08G75/14
CPC分类号： C08G75/14 , C08G75/0209 , C08G75/0231 , C08G75/0268
摘要： A granular polyarylene sulfide; (i) the granular polyarylene sulfide containing an —S— substituent at the terminal, the substituent being formed by cleavage of a disulfide compound; (ii) the granular polyarylene sulfide being an oversize fraction after sifting with a sieve having a mesh size of at least 38 μm; (iii) the granular polyarylene sulfide having a halogen content of at most 1,500 ppm; and (iv) the granular polyarylene sulfide being a granular polyarylene sulfide having a melt viscosity of 3 to 100 Pa·s when measured under conditions at a temperature of 310° C. and a shear rate of 1,200 sec−1. The granular polyarylene sulfide is well balanced in melt viscosity, halogen content, nitrogen content, thermal stability, and yield.
摘要翻译：颗粒状聚芳硫醚; （i）末端含有-S-取代基的粒状聚芳硫醚，该取代基是通过二硫化物化合物的裂解形成的; （ii）颗粒状聚芳硫醚是筛网筛网尺寸至少为38μm的过大部分; （iii）卤素含量为1500ppm以下的粒状聚芳硫醚; 和（iv）在温度310℃，剪切速度1200秒-1的条件下测定时，熔融粘度为3〜100Pa·s的粒状聚芳硫醚的粒状聚芳硫醚。粒状聚芳硫醚在熔体粘度，卤素含量，氮含量，热稳定性和产率方面均衡。

43. 发明申请

US20130281651A1 HIGH REFRACTIVE INDEX POLYMERS 审中-公开
标题翻译：高折射率聚合物
公开(公告)号：US20130281651A1
公开(公告)日：2013-10-24
申请号：US13918232
申请日：2013-06-14
申请人： Florida State University Research Foundation, Inc.
发明人： Albert Stiegman
IPC分类号： C08G77/00 , C08G79/00 , C08G75/04
CPC分类号： C08G77/60 , C08G73/0638 , C08G73/0655 , C08G75/0209 , C08G75/025 , C08G75/045 , C08G77/00 , C08G79/00 , C08L79/04 , C08L83/16
摘要： A polymer and a method of forming a polymer are provided. The polymer has the general structure (I): wherein M is a main group element, a transition metal element, or an organic moiety; X is a main group element selected from S, P, As, Se, Te, and Sb; R1 is a direct bond between M and the ethylene group depicted between M and X or a hydrocarbyl linking moiety having between 1 and about 9 carbon atoms; R2 is a hydrocarbyl moiety; R3 is an organic linking group; Y has a value of 0, 1, 2, 3, or 4; Z has a value of 0, 1, 2, 3, or 4; YY has a value of 0, 1 or 2; and Y, YY, and Z are such that the total number of moieties bonded to M is 3, 4, 5, or 6.
摘要翻译：提供聚合物和形成聚合物的方法。聚合物具有通式（I）：其中M是主要元素，过渡金属元素或有机部分; X是选自S，P，As，Se，Te和Sb的主要元素; R 1是在M和X之间描述的M和亚乙基之间的直接键或具有1至约9个碳原子的烃基连接部分; R2是烃基部分; R3是有机连接基团; Y的值为0,1,2,3或4; Z的值为0,1,2,3或4; YY的值为0,1或2; 并且Y，YY和Z使得与M键合的部分的总数为3,4,5或6。

44. 发明授权

US08492502B2 Method for production of polyarylene sulfide resin with excellent luminosity and the polyarylene sulfide resin 有权
标题翻译：具有优异亮度的聚芳硫醚树脂的生产方法和聚芳硫醚树脂
公开(公告)号：US08492502B2
公开(公告)日：2013-07-23
申请号：US12518243
申请日：2008-01-04
申请人： Young-Rok Lee , II-Hoon Cha , Jun-Sang Cho
发明人： Young-Rok Lee , II-Hoon Cha , Jun-Sang Cho
IPC分类号： C08G75/00
CPC分类号： C08G75/0263 , C08G75/0209 , C08G75/0231 , C08G75/0281 , C08L81/02 , C08L81/00
摘要： The present invention relates to a process of producing polyarylene sulfide (PAS) and PAS resin produced therefrom, and more specifically, to a process of preparing polyarylene sulfide with better thermal properties and luminosity than conventional PAS and the PAS resin produced therefrom, including the steps of: a) melting and mixing a composition including solid sulfur, iodinated aryl compounds, and a polymerization terminator; b) polymerizing the molten mixture of step a) for 1 to 30 hours while increasing the temperature and decreasing the pressure from initial reaction conditions of a temperature of 180 to 250° C. and a pressure of 50 to 450 Torr to final reaction conditions of a temperature of 270 to 350° C. and a pressure of 0.001 to 20 Torr; and c) heating the reaction product of step b) at a temperature of 270 to 350° C. for 1 to 25 hours. The process of polyarylene sulfide resin further includes a step of heating the polymerized product at a high temperature following the polymerization step, and uses the polymerization terminator in a suitable amount to control the molecular weight of polyarylene sulfide, thereby producing polyarylene sulfide with excellent thermal properties and luminosity.
摘要翻译：本发明涉及一种生产聚芳硫醚（PAS）和由其制备的PAS树脂的方法，更具体地说，涉及制备具有比常规PAS和由其制备的PAS树脂更好的热性能和发光度的聚芳硫醚的方法，包括步骤 a）熔融和混合包括固体硫，碘化芳基化合物和聚合终止剂的组合物; b）使步骤a）的熔融混合物聚合1至30小时，同时增加温度并将温度从180-250℃的初始反应条件和50至450托的压力降低至最终反应条件温度为270〜350℃，压力为0.001〜20托; 和c）将步骤b）的反应产物在270至350℃的温度下加热1至25小时。聚芳硫醚树脂的方法还包括在聚合步骤之后在高温下加热聚合产物的步骤，并且使用适当量的聚合终止剂来控制聚芳硫醚的分子量，由此制备具有优异热性质的聚芳硫醚和亮度。

45. 发明授权

US07754848B2 Poly (arylene sulfide) and production process thereof 有权
标题翻译：聚（亚芳基硫醚）及其制备方法
公开(公告)号：US07754848B2
公开(公告)日：2010-07-13
申请号：US10584629
申请日：2004-12-20
申请人： Hiroyuki Sato , Koichi Suzuki , Hirohito Kawama
发明人： Hiroyuki Sato , Koichi Suzuki , Hirohito Kawama
IPC分类号： C08F6/10 , C08F6/12 , C08J3/12 , C08J3/14 , C08G75/10 , C08G75/14 , C08G75/16 , C08L81/00
CPC分类号： C08G75/02 , C08G75/0209 , C08G75/0213 , C08G75/0254 , C08G75/0281
摘要： In a process for producing a poly(arylene sulfide) by polymerizing a sulfur source and a dihalo-aromatic compound in the presence of an alkali metal hydroxide in an organic amide solvent, the production process comprises washing a polymer obtained by the polymerization with a hydrophilic organic solvent containing water in a proportion of 1 to 30% by weight, thereby collecting a purified polymer, the content of nitrogen contained in an extract extracted by a mixed solvent containing 40% by weight of acetonitrile and 60% by weight of water from the purified polymer is at most 50 ppm on the basis of the weight of the polymer, and a poly(arylene sulfide), the content of nitrogen contained in an extract extracted by a mixed solvent containing 40% by weight of acetonitrile and 60% by weight of water from the purified polymer is at most 50 ppm on the basis of the weight of the polymer.
摘要翻译：在有机酰胺溶剂中，在碱金属氢氧化物存在下，通过使硫源和二卤代芳族化合物聚合来制造聚（亚芳基硫醚）的方法中，所述制造方法包括用亲水性含水比例为1〜30重量％的有机溶剂，由此收集纯化聚合物，将含有40重量％乙腈和60重量％水的混合溶剂萃取提取的氮含量从纯聚合物基于聚合物的重量为至多50ppm，聚（亚芳基硫醚）包含在通过包含40重量％乙腈和60重量％的混合溶剂萃取的提取物中的氮含量基于聚合物的重量，来自纯化的聚合物的水的至多50ppm。

46. 发明申请

US20100022743A1 POLYARYLENE SULFIDE RESIN WITH EXCELLENT LUMINOSITY AND PREPARATION METHOD THEREOF 有权
标题翻译：具有优异荧光性的聚亚烷基硫酸酯树脂及其制备方法
公开(公告)号：US20100022743A1
公开(公告)日：2010-01-28
申请号：US12518369
申请日：2008-01-04
申请人： Young-Rok Lee , Ii-Hoon Cha , Yong-Jun Shin , Jun-Sang Cho
发明人： Young-Rok Lee , Ii-Hoon Cha , Yong-Jun Shin , Jun-Sang Cho
IPC分类号： C08G75/14
CPC分类号： C08G75/14 , C08G75/0209 , C08G75/0231 , C08G75/0263 , C08L81/02 , C08L2666/22 , C08L81/00
摘要： The present invention relates to a polyarylene sulfide that is prepared from a composition including 100 parts by weight of solid sulfur, 500 to 10,000 parts by weight of iodinated aryl compounds, and 0.03 to 30 parts by weight of a sulfur-containing polymerization terminator with respect to 100 parts by weight of the solid sulfur, and has a melting temperature (Tm) of 255 to 285° C., and luminosity of 40 or higher as defined by the CIE Lab color model, and a process of preparing the same. The PAS resin is prepared from a composition including a sulfur-containing polymerization terminator and thus has excellent thermal properties and luminosity.
摘要翻译：本发明涉及一种聚芳硫醚，其由包含100重量份固体硫，500至10,000重量份碘化芳基化合物和0.03至30重量份含硫聚合终止剂的组合物制备，相对于至100重量份固体硫，并且具有255至285℃的熔融温度（Tm）和由CIE Lab颜色模型所定义的40或更高的亮度及其制备方法。 PAS树脂由包含含硫聚合终止剂的组合物制备，因此具有优异的热性能和亮度。

47. 发明授权

US6149840A Electrically conductive polymeric materials and use thereof 失效
标题翻译：导电聚合材料及其用途
公开(公告)号：US6149840A
公开(公告)日：2000-11-21
申请号：US838296
申请日：1997-09-29
申请人： Ali Afzali Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
发明人： Ali Afzali Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
IPC分类号： C08L33/00 , C08G61/02 , C08G61/12 , C08G75/02 , C08L33/04 , C08L53/02 , C08L65/00 , C08L69/00 , C08L79/00 , C08L79/02 , C08L79/04 , C08L81/02 , C08L81/04 , C08L101/00 , C08L101/12 , H01B1/00 , H01B1/12 , C08G73/06
CPC分类号： H01B1/128 , C08G61/02 , C08G61/123 , C08G75/0209 , C08G75/0295 , C08L101/12 , C08L65/00 , C08L69/00 , C08L79/02 , C08L79/04 , C08L81/02 , H01B1/00 , H01B1/124 , C08L53/02 , C08L81/04
摘要： A polymer blend composition, capable of being made electrically conductive by application of heat having an electrically conductive upon doping polymer in undoped form; the undoped polymer is selected from the group consisting of substituted and unsubstituted polyparaphenylenevinylenes, polyanilines, polyazines, polythiophenes, poly-p-phenylene sulfides, polyfuranes, polyselenophenes, polyacetylenes filtered from soluble precursors and combinations and blends thereof, compounded and blended at a molecular scale with a dielectric polymer; wherein the dielectric polymer is selected from the group consisting of interpolymers of acrylonitrile-butadiene-styrene, acetal acrylic liquid crystal polymers, polybutylene terephthalate, polycarbonate, polyester, polyetherimide, polyethersulfone, polyethylene, polyethylene terephthalate, polyphenylene oxide, polyphenylene sulfide, polypropylene, polystyrene, polyurethane, polyvinychloride, styrene-acrylonitrile copolymer, fluoropolymers, nylon polyesters, and thermoplastic elastomers, and a thermally deblockable dopant selected from the group consisting of triflates, tosylates and borates, the electrically conductive upon doping polymer having enhanced solubility in undoped form with said dielectric polymer to form a compatible molecularly mixed blend in solution; doping of the polymer occurs only after exposure to heat.
摘要翻译：一种聚合物共混组合物，其能够通过施加具有未掺杂形式的具有导电性的掺杂聚合物的热而导电; 未掺杂的聚合物选自取代和未取代的聚对亚苯基亚乙烯基，聚苯胺，聚嗪，聚噻吩，聚对苯硫醚，聚呋喃，聚硒吩，可溶性前体过滤的聚乙炔及其组合和共混物，以分子量配混和共混与介电聚合物; 所述介电聚合物选自丙烯腈 - 丁二烯 - 苯乙烯，缩醛丙烯酸类液晶聚合物，聚对苯二甲酸丁二醇酯，聚碳酸酯，聚酯，聚醚酰亚胺，聚醚砜，聚乙烯，聚对苯二甲酸乙二醇酯，聚苯醚，聚苯硫醚，聚丙烯，聚苯乙烯聚氨酯，聚氯乙烯，苯乙烯 - 丙烯腈共聚物，含氟聚合物，尼龙聚酯和热塑性弹性体，以及选自三氟甲磺酸酯，甲苯磺酸酯和硼酸酯的热可去结合的掺杂剂，所述导电的一次性掺杂聚合物具有增强的未掺杂形式的溶解度，电介质聚合物在溶液中形成相容的分子混合共混物; 聚合物的掺杂仅在暴露于热之后才发生。

48. 发明授权

US5331064A Polybenzazole compositions containing pendant poly(aromatic sulfide) moieties 失效
标题翻译：含有聚（芳族硫化物）部分的聚苯并恶唑组合物
公开(公告)号：US5331064A
公开(公告)日：1994-07-19
申请号：US501646
申请日：1990-03-29
申请人： Ying H. So , Thomas A. DeVilbiss, III
发明人： Ying H. So , Thomas A. DeVilbiss, III
IPC分类号： C08G73/22 , C08G75/02 , C08F283/00
CPC分类号： C08G75/0209 , C08G73/22 , C08G75/0245 , C08G75/0272
摘要： Graft copolymers of polybenzazole and poly(phenylene sulfide) are synthesized by the reaction of terephthalic acid and 4,6-diaminoresorcinol with 2-(polyphenylene sulfide)terephthalic acid. The resulting graft copolymer can be cross-linked by heating to provide a cross-linked product having improved thermal stability, acid resistance, and compressive strength.
摘要翻译：通过对苯二甲酸和4,6-二氨基间苯二酚与2-（聚苯硫醚）对苯二甲酸的反应合成聚吲哚和聚（苯硫醚）的接枝共聚物。所得到的接枝共聚物可以通过加热交联以提供具有改进的热稳定性，耐酸性和抗压强度的交联产物。

49. 发明授权

US5155207A Arylene sulfide polymers and articles of manufacture 失效
标题翻译：亚芳基硫化物聚合物和制品
公开(公告)号：US5155207A
公开(公告)日：1992-10-13
申请号：US485396
申请日：1990-02-23
申请人： Guy Senatore , Liang Yeon F.
发明人： Guy Senatore , Liang Yeon F.
IPC分类号： C08G75/02
CPC分类号： C08G75/0254 , C08G75/0209 , C08G75/0231 , Y10T428/31533
摘要： Films and fibers are prepared from arylene sulfide resins comprising first recurring units consisting of aromatic structures having the form: ##STR1## and second recurring units including units selected from aromatic structures having the form: ##STR2##
摘要翻译：由芳族硫醚树脂制成的薄膜和纤维由包含以下形式的芳族结构构成的第一重复单元制成：第二重复单元包括选自以下形式的芳族结构单元：

50. 发明授权

US5051495A Production and/or handling of aryl polyethers and thioethers polymers 失效
标题翻译：芳基聚醚和硫醚聚合物的生产和/或处理
公开(公告)号：US5051495A
公开(公告)日：1991-09-24
申请号：US195610
申请日：1988-05-18
申请人： Philip Staniland , Arthur H. Gilbert , Ian R. M. Henderson
发明人： Philip Staniland , Arthur H. Gilbert , Ian R. M. Henderson
IPC分类号： C08G65/46 , C08G75/02
CPC分类号： C08G75/0209 , C08G65/46
摘要： In making polyarylethersulphones or polyaryletherketones or their thioanalogues by reaction of phenols with aromatic halogen compounds, raw polycondensation product is freed of alkali halide by adjusting its composition and/or temperature so that it dissolves at least 0.5% w/w of water and holds the polymer in solution, and then contacting it in liquid form with hot water, preferably under pressure.

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