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41. 发明授权

US08133445B2 Reaction chamber promoting heat exchange between the reagents and the gases that are produced 有权
标题翻译：反应室促进试剂与所生成的气体之间的热交换
公开(公告)号：US08133445B2
公开(公告)日：2012-03-13
申请号：US12573376
申请日：2009-10-05
申请人： Christophe Boyer , Fabrice Giroudiere
发明人： Christophe Boyer , Fabrice Giroudiere
IPC分类号： B01J8/02 , B01J35/02 , B01J19/00 , F28D7/00 , C01B3/02
CPC分类号： B01J8/0257 , B01J8/0278 , B01J8/0285 , B01J8/0292 , B01J8/067 , B01J2208/00203 , B01J2208/00495 , B01J2208/00504 , B01J2208/0053 , B01J2208/00769 , B01J2208/00849 , B01J2208/025 , C01B3/323 , C01B3/384 , C01B2203/0233 , C01B2203/0822 , C01B2203/1229 , F28F13/08 , Y02P20/128 , Y02P20/52
摘要： This invention relates to a chamber in which a chemical reaction is carried out in the presence of catalyst and reagents, comprising at least one catalytic tube (10) into which is placed an internal tube (12) for evacuating the gas that is produced, means for introducing reagents (15) and means for introducing the catalyst (16) that are located in the upper portion of the chamber (1), means for heating the catalytic tube (10) that are arranged in the lower portion of the chamber (1), and in which the catalytic tube (10) comprises, in its upper portion above the catalyst (13), means that promote heat exchange between the reagents and the gas that is produced. The invention also relates to the process that uses this chamber.
摘要翻译：本发明涉及一种在催化剂和试剂的存在下进行化学反应的室，包括至少一个催化管（10），其中放置有用于抽空所产生气体的内管（12）用于引入试剂（15）和用于引入位于室（1）上部的催化剂（16）的装置，用于加热设置在室（1）的下部的催化剂管（10）的装置），并且其中催化管（10）在其上部在催化剂（13）上方包括促进试剂和所产生气体之间的热交换的装置。本发明还涉及使用该室的方法。

42. 发明申请

US20110268631A1 MULTI-TUBE CHEMICAL REACTOR WITH TESSELLATED HEAT TRANSFER FINS 失效
标题翻译：多管式化学反应器，带有热交换器
公开(公告)号：US20110268631A1
公开(公告)日：2011-11-03
申请号：US12975814
申请日：2010-12-22
申请人： Paul E. Jankowski
发明人： Paul E. Jankowski
IPC分类号： B01J8/06 , B23P11/00
CPC分类号： B01J8/067 , B01J8/0292 , B01J19/32 , B01J2208/00221 , B01J2219/1928 , B01J2219/3221 , B01J2219/32213 , B01J2219/32231 , B01J2219/32275 , B01J2219/32296 , B01J2219/32466 , C01B3/384 , C01B2203/0227 , C01B2203/0805 , C01B2203/0833 , C01B2203/1247 , C01B2203/1288 , C01B2203/141 , F28D7/163 , F28F1/04 , F28F1/14 , F28F1/22 , F28F9/0132 , Y10T29/49826
摘要： A chemical reactor is provided that includes:a plurality of tubes having a catalytic reactor substrate therein, each of the tubes having an inlet at one end for receiving a fluid flow and an outlet at an opposing end for discharging fluid flow, and a longitudinal axis parallel to the direction of fluid flow through the tube, the longitudinal axis of each tube being parallel to one another; anda plurality of heat exchange fins disposed on and extending radially from the exterior surface of each tube;the heat exchange fins on each tube independently having a profile along a cross-section perpendicular to the longitudinal axis of each tube, and the tubes being arranged with respect to one another, such that the heat exchange fin profiles together form a tessellated pattern in a plane that is perpendicular to the longitudinal axes of the tubes.
摘要翻译：提供了一种化学反应器，其包括：多个管，其中具有催化反应器基板，每个管在一端具有用于接收流体流的入口和用于排出流体流的相对端处的出口，以及纵向轴线平行于通过管的流体流动的方向，每个管的纵向轴线彼此平行; 以及设置在每个管的外表面上且从每个管的外表面径向延伸的多个热交换翅片; 每个管上的热交换翅片独立地具有垂直于每个管的纵向轴线的横截面的轮廓，并且管相对于彼此布置，使得热交换翅片轮廓一起形成镶嵌图案平面垂直于管的纵向轴线。

43. 发明申请

US20110250102A1 REACTOR 有权
标题翻译：反应堆
公开(公告)号：US20110250102A1
公开(公告)日：2011-10-13
申请号：US13074912
申请日：2011-03-29
申请人： Kenji Sakai
发明人： Kenji Sakai
IPC分类号： B01J8/06
CPC分类号： B01J8/0214 , B01J8/003 , B01J8/0292 , B01J2208/00132 , B01J2208/00752 , B01J2208/00761 , B01J2208/0084
摘要： There is provided a radial flow reactor having a multi-pass structure in which loading and unloading of granular packing are easy and which does not impair the reaction performance. The reactor includes, in an upright tubular reactor vessel: a packing region for housing a continuous packed bed of granular packing; and an outer and an inner passages disposed outside and inside the packing region, respectively, allowing a fluid to flow in the axial direction. The reactor is configured so that the fluid can pass between the packing region and the outer passage and between the packing region and the inner passage. The reactor further includes at least one of an outer partition structure and an inner partition structure. The outer partition structure includes: an outer partition plate partitioning the packing region in the axial direction with a gap allowing the granular packing to pass therethrough between the inner border of the packing region and the outer partition plate; and a blocking section for preventing the fluid from flowing through the outer passage in the axial direction. The inner partition structure includes: an inner partition plate partitioning the packing region in the axial direction with a gap allowing the granular packing to pass therethrough between the outer border of the packing region and the inner partition plate; and a blocking section for preventing the fluid from flowing through the inner passage in the axial direction.
摘要翻译：提供了一种具有多通道结构的径向流动反应器，其中颗粒填料的装载和卸载容易并且不损害反应性能。反应器包括在直立的管式反应器容器中：用于容纳颗粒状填料的连续填充床的填充区域; 以及分别设置在填充区域的外部和内部的外部和内部通道，允许流体沿轴向流动。反应器构造成使得流体可以在填充区域和外部通道之间以及填充区域和内部通道之间通过。反应器还包括外分隔结构和内分隔结构中的至少一个。外分隔结构包括：外隔板，其在轴向方向上分隔填料区域，间隙允许颗粒填料在填料区域的内边界与外隔板之间通过; 以及用于防止流体在轴向上流过外部通道的阻挡部。内分隔结构包括：内隔板，其在轴向方向上分隔填料区域，间隙允许颗粒填料在填料区域的外边界与内隔板之间通过; 以及用于防止流体在轴向上流过内部通道的阻挡部。

44. 发明授权

US07476297B2 Device and method for carrying out heterogeneously-catalysed reactive distillations in particular for the production of pseudoionone 失效
标题翻译：用于进行非均相催化反应蒸馏的装置和方法，特别是用于生产假性离子
公开(公告)号：US07476297B2
公开(公告)日：2009-01-13
申请号：US10497520
申请日：2002-12-05
申请人： Gerd Kaibel , Christian Miller , Walter Dobler , Thomas Dirnsteiner , Marcus Sigl , Helmut Jansen , Björn Kaibel
发明人： Gerd Kaibel , Christian Miller , Walter Dobler , Thomas Dirnsteiner , Marcus Sigl , Helmut Jansen , Björn Kaibel
IPC分类号： B01D3/32 , B01J8/02 , B01J19/32
CPC分类号： C07C45/74 , B01D3/009 , B01J8/003 , B01J8/0292 , B01J8/12 , B01J19/249 , B01J19/32 , B01J21/04 , B01J23/10 , B01J35/026 , B01J2219/2453 , B01J2219/2459 , B01J2219/2471 , B01J2219/2481 , B01J2219/2497 , B01J2219/3221 , B01J2219/32217 , B01J2219/32227 , B01J2219/32237 , B01J2219/32258 , B01J2219/32262 , B01J2219/32408 , B01J2219/32466 , B01J2219/326 , C07C45/72 , Y02P20/127 , Y10S203/06 , C07C49/203
摘要： A column is described for carrying out reactive distillations in the presence of a heterogeneous particulate catalyst having an ordered packing or random packings which form intermediate spaces in the column interior, the quotient of the hydraulic diameter for the gas flow through the ordered packing or the random packings and the equivalent diameter of the catalyst particles being in the range from 2 to 20, preferably in the range from 5 to 10, in such a manner that the catalyst particles are introduced into the intermediate spaces, distributed and discharged loose under the action of gravity.
摘要翻译：描述了一种柱，用于在具有在柱内部形成中间空间的有序填料或无规填料的非均相颗粒催化剂存在下进行反应性蒸馏，通过有序填料的气流的液压直径或随机的填料和催化剂颗粒的当量直径在2至20范围内，优选在5至10范围内，使得催化剂颗粒被引入中间空间，在重力。

45. 发明申请

US20060110302A1 Method and device for supporting catalyst gauzes in an ammonia oxidation burner 有权
标题翻译：用于在氨氧化燃烧器中支撑催化剂纱布的方法和装置
公开(公告)号：US20060110302A1
公开(公告)日：2006-05-25
申请号：US10519072
申请日：2002-09-20
申请人： Halvor Oien , Leif Gronstad , Oystein Nirisen , Per Karlsen , Magne Slaen
发明人： Halvor Oien , Leif Gronstad , Oystein Nirisen , Per Karlsen , Magne Slaen
IPC分类号： B01J8/44 , B01J8/02 , B01J35/02
CPC分类号： B01J8/0292 , B01J8/008 , B01J35/06 , B01J2208/00884 , B01J2219/0277 , C01B21/265 , C01B21/28
摘要： The invention comprise a support system for catalyst gauzes in an ammonia oxidation burner and a method of reducing movement of particulate ceramic material due to thermal dilatation. The catalyst gauzes (1) and possibly support screens (2) are being supported by ceramic fillings contained in a burner basket with metal walls and a perforated bottom plate. A “wave breaker” (9, 11) is fixed to the metal wall (4) and/or the outer part/periphery of the bottom plate (5).
摘要翻译：本发明包括用于氨氧化燃烧器中的催化剂纱布的支撑体系，以及减少由于热膨胀导致的颗粒状陶瓷材料的移动的方法。催化剂纱布（1）和可能的支撑筛网（2）由包含在具有金属壁和多孔底板的燃烧器篮中的陶瓷填料支撑。 “波浪断路器”（9,11）固定到金属壁（4）和/或底板（5）的外部/周边。

46. 发明授权

US06921518B2 Chemical reactor 失效
标题翻译：化学反应器
公开(公告)号：US06921518B2
公开(公告)日：2005-07-26
申请号：US09769583
申请日：2001-01-25
申请人： Anthony Johnston
发明人： Anthony Johnston
IPC分类号： B01J8/02 , B01J8/04 , B01J19/00 , C01C1/04 , F28D1/00
CPC分类号： B01J8/0438 , B01J8/0221 , B01J8/0235 , B01J8/0285 , B01J8/0292 , B01J8/0496 , B01J19/0013 , B01J2208/0015 , B01J2208/00212 , B01J2208/00221 , B01J2219/00085 , B01J2219/182 , B01J2219/1943 , C01C1/0417 , F28D9/0037 , F28F3/048 , F28F2260/00 , Y02P20/52
摘要： A reactor of the staged adiabatic reactor type, comprises at least one heat exchanger panel, preferably a printed circuit heat exchange (PCHE) panel, interposes between adiabatic beds of catalyst, wherein the facial area of the panels and the superficial facial area of the corresponding catalyst are substantially similar, and the panels include means defining discrete passages for handling of reactants and heat transfer media, wherein the means defining passages for heat transfer media provide for at least two differing flow path directions for the heat transfer media through the heat exchanger panel whereby the occurrence of temperature bias or differentials is reduced.
摘要翻译：分级绝热反应器型的反应器包括至少一个热交换器面板，优选印刷电路热交换（PCHE）面板，介于催化剂的绝热床之间，其中面板的面部区域和相应的表面面积区域催化剂基本上类似，并且面板包括限定用于处理反应物和传热介质的离散通道的装置，其中限定用于传热介质的通道的装置为传热介质提供至少两个不同的流动路径方向，所述传热介质通过热交换器面板从而降低了温度偏差或微分的发生。

47. 发明申请

US20050086864A1 LOW PRESSURE DROP REFORMING EXCHANGER 有权
标题翻译：低压减压换向阀
公开(公告)号：US20050086864A1
公开(公告)日：2005-04-28
申请号：US10905460
申请日：2005-01-05
申请人： Robert Burlingame , Thomas Czuppon , Larry Hackemesser
发明人： Robert Burlingame , Thomas Czuppon , Larry Hackemesser
IPC分类号： B01J8/00 , B01J8/02 , B01J8/06 , B01J19/30 , B01J23/755 , B01J35/02 , C01B3/38
CPC分类号： B01J8/0292 , B01J8/008 , B01J8/067 , B01J19/30 , B01J23/755 , B01J35/026 , B01J2208/00221 , B01J2208/00309 , B01J2208/00495 , B01J2208/0053 , B01J2219/30223 , B01J2219/30242 , B01J2219/32296 , C01B3/382 , C01B3/384 , C01B2203/0844 , C01B2203/141 , C01B2203/142 , C01B2203/82 , Y02P20/52
摘要： Disclosed are a syngas production process and a reforming exchanger 100. The process involves passing a first portion of hydrocarbon feed mixed with steam and oxidant through an autothermal catalytic steam reforming zone to form a first reformed gas of reduced hydrocarbon content, passing a second portion of the hydrocarbon feed mixed with steam through an endothermic catalytic steam reforming zone to form a second reformed gas of reduced hydrocarbon content, and mixing the first and second reformed gases and passing the resulting gas mixture through a heat exchange zone for cooling the gas mixture and thereby supplying heat to the endothermic catalytic steam reforming zone. The endothermic catalytic steam reforming zone and the heat exchange zone are respectively disposed tube side and shell side within a shell-and-tube reforming exchanger 100. The reforming exchanger 100 comprises a plurality of tubes 118 packed with low pressure drop catalyst-bearing monolithic structures 200 wherein an inside diameter of the tubes 118 is less than 4 times a maximum edge dimension of the catalyst structures 200.
摘要翻译：公开了合成气生产方法和重整换热器100。该方法包括使与蒸汽和氧化剂混合的烃进料的第一部分通过自热催化蒸汽重整区，以形成具有降低的烃含量的第一重整气体，使与蒸汽混合的烃进料的第二部分通过吸热催化蒸汽重整形成还原烃含量的第二重整气体，并混合第一和第二重整气体，并使得到的气体混合物通过热交换区，用于冷却气体混合物，从而向吸热催化蒸汽重整区供热。吸热催化蒸汽重整区和热交换区分别设置在管 - 管重整交换器100内的管侧和壳侧。重整交换器100包括填充有低压降催化剂承载整体结构200的多个管118，其中管118的内径小于催化剂结构200的最大边缘尺寸的4倍。

48. 发明申请

US20040228780A1 Dehydrogenation process 失效
公开(公告)号：US20040228780A1
公开(公告)日：2004-11-18
申请号：US10874887
申请日：2004-06-23
发明人： James R. Butler , James T. Merrill , Adrian M. Jacobsen
IPC分类号： B01J008/00
CPC分类号： C07C5/333 , B01F5/06 , B01J8/0292 , B01J8/0453 , B01J8/065 , B01J2208/00061 , B01J2208/00212 , B01J2208/00548 , B01J2208/0084 , B01J2208/00849 , Y10S585/922 , Y10S585/923 , Y10S585/924 , C07C15/44 , C07C15/46
摘要： Process for the catalytic dehydrogenation of a C2 or C3 alkyl aromatic in which a feedstock containing the alkyl aromatic and steam is supplied into the inlet of a tubular reactor containing a dehydrogenation catalyst. Within the reactor, the feedstock flows through at least a portion of the reactor along a spiral flow path extending longitudinally of the reactor. The resulting vinyl aromatic product is then recovered from a downstream or outlet section of the reactor. The spiral flow path through which the feedstock is passed is located at least adjacent the inlet side of the reactor and at least a portion of the spiral flow path contains a particulate dehydrogenation catalyst. The spiral flow path may extend throughout a major portion of the elongated tubular reactor and may contain a particulate dehydrogenation catalyst in a substantial portion there. The feedstock containing the alkyl aromatic and steam is supplied into a plurality of tubular reactors located within the interior of a dehydrogenation reactor vessel and is arranged in a parallel relationship in which the tubular reactors are spaced laterally from one another and from the interior wall of the reaction vessel.

49. 发明申请

US20040197246A1 Fuel processing reactor with internal heat exchange for low pressure gas stream 审中-公开
标题翻译：具有低压气流内部热交换的燃料处理反应器
公开(公告)号：US20040197246A1
公开(公告)日：2004-10-07
申请号：US10407312
申请日：2003-04-04
申请人： Texaco Inc.
发明人： James F. Stevens , Curtis L. Krause , Paul Francis Martin , Vijay Anant Deshpande
IPC分类号： B01J008/02
CPC分类号： C01B3/16 , B01J8/025 , B01J8/0271 , B01J8/0285 , B01J8/0292 , B01J8/0453 , B01J8/0496 , B01J2208/00141 , C01B3/38 , C01B3/386 , C01B2203/0233 , C01B2203/0261 , C01B2203/0288 , C01B2203/0883 , C01B2203/1011 , H01M8/0618 , H01M8/0668 , Y02P70/56 , Y10T29/49391
摘要： A compact fuel processing reactor. The reactor includes a housing having an inlet for receiving a process gas and an outlet for a directing a product gas out of the housing. A catalyst bed that includes discrete particles of a refractory material is located within the housing for contacting the process gas. A coiled tubing heat exchanger is at least partially disposed within the catalyst bed for cooling the catalyst bed. The coiled tubing can comprise a smooth continuous outer surface in intimate contact with the discrete particles. The circulating cooling medium comprises water in liquid, gas or a mixture of liquid and gas phases. The discrete particles in the catalyst bed are in intimate contact with at least a portion of the coiled tubing to promote heat transfer from the catalyst bed to the coiled tubing. The heat exchanger has less than about 25, preferably less than about 20, more preferably less than about 15, and still more preferably less than about 10 square meters of heat exchanging surface area per cubic meter of catalyst bed. The catalyst bed can be a water gas shift, desulfurization or reforming bed. The reactor can include one or more additional catalyst beds arranged in series such that the housing enclosed a shift catalyst bed as well as a desulphurization bed and/or a reforming bed. Methods of cooling a catalyst bed within a compact reactor and methods of manufacturing a compact reactor are also provided.
摘要翻译：紧凑的燃料处理反应堆。反应器包括具有用于接收处理气体的入口和用于将产物气体引导出壳体的出口的壳体。包括耐火材料的离散颗粒的催化剂床位于壳体内用于接触工艺气体。连续油管热交换器至少部分地布置在催化剂床内以冷却催化剂床。连续油管可以包括与离散颗粒紧密接触的光滑的连续外表面。循环冷却介质包括液体中的水，气体或液相和气相的混合物。催化剂床中的离散颗粒与至少一部分连续油管紧密接触以促进从催化剂床到连续油管的热传递。热交换器的每立方米催化剂床的热交换表面积小于约25，优选小于约20，更优选小于约15，还更优选小于约10平方米。催化剂床可以是水煤气变换，脱硫或重整床。反应器可以包括串联布置的一个或多个另外的催化剂床，使得壳体包围换档催化剂床以及脱硫床和/或重整床。还提供了在紧凑型反应器内冷却催化剂床的方法和制造紧凑型反应器的方法。

50. 发明授权

US06781024B2 Dehydrogenation process 失效
标题翻译：脱氢工艺
公开(公告)号：US06781024B2
公开(公告)日：2004-08-24
申请号：US10074173
申请日：2002-02-12
申请人： James R. Butler , James T. Merrill , Adrian M. Jacobsen
发明人： James R. Butler , James T. Merrill , Adrian M. Jacobsen
IPC分类号： C07G5367
CPC分类号： C07C5/333 , B01F5/06 , B01J8/0292 , B01J8/0453 , B01J8/065 , B01J2208/00061 , B01J2208/00212 , B01J2208/00548 , B01J2208/0084 , B01J2208/00849 , Y10S585/922 , Y10S585/923 , Y10S585/924 , C07C15/44 , C07C15/46
摘要： Process for the catalytic dehydrogenation of a C2 or C3 alkyl aromatic in which a feedstock containing the alkyl aromatic and steam is supplied into the inlet of a tubular reactor containing a dehydrogenation catalyst. Within the reactor, the feedstock flows through at least a portion of the reactor along a spiral flow path extending longitudinally of the reactor. The resulting vinyl aromatic product is then recovered from a downstream or outlet section of the reactor. The spiral flow path through which the feedstock is passed is located at least adjacent the inlet side of the reactor and at least a portion of the spiral flow path contains a particulate dehydrogenation catalyst. The spiral flow path may extend throughout a major portion of the elongated tubular reactor and may contain a particulate dehydrogenation catalyst in a substantial portion there. The feedstock containing the alkyl aromatic and steam is supplied into a plurality of tubular reactors located within the interior of a dehydrogenation reactor vessel and is arranged in a parallel relationship in which the tubular reactors are spaced laterally from one another and from the interior wall of the reaction vessel.
摘要翻译：将含有烷基芳族和蒸汽的原料供给到含有脱氢催化剂的管式反应器的入口中的C2或C3烷基芳族化合物的催化脱氢方法。在反应器内，原料沿着反应器纵向延伸的螺旋流动路径流过反应器的至少一部分。然后从反应器的下游或出口部分回收得到的乙烯基芳族化合物。原料通过的螺旋流动路径至少位于反应器的入口侧，螺旋流路的至少一部分含有颗粒脱氢催化剂。螺旋流动路径可以延伸穿过细长管式反应器的主要部分，并且可以在其中大部分含有颗粒状脱氢催化剂。将含有烷基芳族化合物和蒸汽的原料供给到位于脱氢反应器容器内部的多个管式反应器中并且以平行关系排列，其中管式反应器彼此横向间隔开，反应容器

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