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    • 49. 发明申请
    • Column for carrying out an isotope exchange between a liquid substance and a gaseous substance
    • 用于在液体物质和气态物质之间进行同位素交换的色谱柱
    • US20020079259A1
    • 2002-06-27
    • US10054194
    • 2001-11-13
    • Sulzer Chemtech AG
    • Christian EngelerHans RuckstuhlRichard Zmasek
    • B01D015/00
    • B01D59/32B01D3/20C01B5/02
    • The column is provided for carrying out an isotope exchange (EM) between a liquid substance (L) and a gaseous substance (G) using a catalytic reaction (EK). In this reaction the isotope exchange between molecules of the vaporized liquid substance (V) and molecules of the gaseous substance (G) takes place through a heterogeneous catalysis. The column comprises a plurality of modules (M) which are arranged vertically one above the other and which are in each case subdivided into two regions K and A which are serially connected by a connection region (C). The catalytic reaction can be carried out in the region K on a first packing (2). A substance exchange (E1, E2) between a liquid and a gaseous phase which contains vapor can be carried out in the region A by means of a second packing (3) for compensating substance concentrations. During the operation of the column a transport of the gaseous substance (G, V) which contains vapor is driven through the modules as a result of pressure gradients. In this the transport direction is changed at least once in the connection region, and indeed from a downward direction to an upward direction, whereas the liquid substance (L) is forwarded downwardly through the modules through the action of gravity alone.
    • 提供该柱用于使用催化反应(EK)在液体物质(L)和气态物质(G)之间进行同位素交换(EM)。 在该反应中,蒸发的液体物质(V)的分子与气态物质(G)的分子之间的同位素交换通过非均相催化进行。 该列包括多个模块(M),它们彼此垂直地布置,并且在每种情况下被细分成由连接区域(C)串联连接的两个区域K和A. 催化反应可以在第一包装(2)上的区域K中进行。 在液体和含有蒸汽的气相之间的物质交换(E1,E2)可以通过用于补偿物质浓度的第二填料(3)在区域A中进行。 在塔的操作期间,由于压力梯度,包含蒸汽的气态物质(G,V)的输送通过模块被驱动。 在这种情况下,输送方向在连接区域中改变至少一次,实际上从向下方向改变到向上方向,而液体物质(L)通过独立的重力作用向下穿过模块。
    • 50. 发明授权
    • Process for preparing a chemical compound enriched in isotope content
    • 制备富含同位素含量的化合物的方法
    • US4343685A
    • 1982-08-10
    • US238711
    • 1981-02-25
    • Edward D. Michaels
    • Edward D. Michaels
    • B01D59/32C25B1/02C25B1/22
    • B01D59/32
    • A process to prepare a chemical enriched in isotope content which includes:(a) A chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound;(b) the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material;(c) the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region;(d) the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products.
    • 一种制备富含同位素含量的化学物质的方法,其包括:(a)产生同位素富集的第一化合物和同位素贫化的第二化合物的第一和第二化合物之间的化学交换反应; (b)将一部分第一化合物作为产物除去并除去作为废料的第二化合物的一部分; (c)在化学交换反应区的产物末端将第一化合物的剩余物转化为第二化合物进行回流; (d)在化学交换区的废料端将第二化合物的剩余部分转化为第一化合物回流; 以及通过一次转化反应生成的另外的化学品对其它转化反应的循环,以便在其中消耗。 转化反应之一是氧化反应,其产生的能量用于驱动另一种转化反应,减少。 还原反应在固体聚合物电解质电解反应器中进行。 整个过程是节能的,没有浪费副产品。