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    • 44. 发明申请
    • MIM CAPACITOR FORMATION METHOD AND STRUCTURE
    • MIM电容器形成方法和结构
    • US20130285201A1
    • 2013-10-31
    • US13458947
    • 2012-04-27
    • Zhihong ZhangXu ChengTodd C. RoggenbauerJiang-Kai Zuo
    • Zhihong ZhangXu ChengTodd C. RoggenbauerJiang-Kai Zuo
    • H01L29/02H01L21/02
    • H01L28/92H01L29/92
    • Metal-insulator metal (MIM) capacitors are formed by providing a substrate having a first surface, forming thereon a first electrode having conductive and insulating regions wherein the conductive regions desirably have an area density DA less than 100%. A first dielectric is formed over the first electrode. A cavity is formed in the first dielectric, having a sidewall extending to the first electrode and exposing thereon some of the first electrode conductive and insulating regions. An electrically conductive barrier layer is formed covering the sidewall and the some of the first electrode conductive and insulating regions. A capacitor dielectric layer is formed in the cavity covering the barrier layer. A counter electrode is formed in the cavity covering the capacitor dielectric layer. External connections are formed to a portion of the first electrode laterally outside the cavity and to the counter electrode within the cavity.
    • 通过提供具有第一表面的基板形成金属绝缘体金属(MIM)电容器,在其上形成具有导电和绝缘区域的第一电极,其中导电区域希望具有小于100%的面密度DA。 第一电介质形成在第一电极上。 在第一电介质中形成空腔,其具有延伸到第一电极并在其上暴露第一电极导电和绝缘区域的一些的侧壁。 形成覆盖侧壁和一些第一电极导电绝缘区域的导电阻挡层。 在覆盖阻挡层的空腔中形成电容器电介质层。 在覆盖电容器介电层的空腔中形成对电极。 外部连接形成在腔的横向外侧的第一电极的一部分和腔内的对电极。
    • 46. 发明申请
    • Method to deposit an impermeable film on porous low-k dielectric film
    • 在多孔低k电介质膜上沉积不渗透膜的方法
    • US20050084619A1
    • 2005-04-21
    • US10963192
    • 2004-10-12
    • Zhihong ZhangTai NguyenTue Nguyen
    • Zhihong ZhangTai NguyenTue Nguyen
    • H01L21/285H01L21/316H01L21/318H01L21/768C23C16/00B05D3/04
    • H01L21/76838H01L21/02203H01L21/28556H01L21/28568H01L21/3105
    • A method for improving the adhesion of an impermeable film on a porous low-k dielectric film in an interconnect structure is disclosed. The method provides an in-situ annealing step before the deposition of the impermeable film to release the volatile trapped molecules such as water, alcohol, HCl, and HF vapor, inside the pores of the porous low-k dielectric film. The method also provides an in-situ deposition step of the impermeable film right after the deposition of the porous low dielectric film without exposure to an atmosphere containing trappable molecules. The method further provides an in-situ deposition step of the impermeable film right after the removal a portion of the porous low-k dielectric film without exposure to an atmosphere containing trappable molecules. By the removal of all trapped molecules inside the porous low-k dielectric film, the adhesion between the deposited impermeable film and the low-k dielectric film is improved. This method is applicable to many porous low-k dielectric films such as porous hydrosilsesquioxane or porous methyl silsesquioxane, porous silica structures such as aerogel, low temperature deposited silicon carbon films, low temperature deposited Si—O—C films, and methyl doped porous silica.
    • 公开了一种用于改善互连结构中的多孔低k电介质膜上的不渗透膜的粘附性的方法。 该方法提供在沉积不渗透膜以在多孔低k电介质膜的孔隙内释放挥发性捕获分子如水,醇,HCl和HF蒸气的原位退火步骤。 该方法还提供了在不暴露于含有可捕获分子的气氛之后立即沉积多孔低介电膜之后的不渗透膜的原位沉积步骤。 该方法进一步提供了在不暴露于含有可捕获分子的气氛之后移除多孔低k电介质膜的一部分之后的不渗透膜的原位沉积步骤。 通过去除多孔低k电介质膜内的所有被捕获的分子,提高了沉积的不可渗透膜和低k电介质膜之间的粘附性。 该方法适用于多孔低k介电膜,例如多孔氢硅倍半氧烷或多孔甲基硅倍半氧烷,多孔二氧化硅结构如气凝胶,低温沉积硅碳膜,低温沉积Si-O-C膜和甲基掺杂多孔二氧化硅。