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    • 48. 发明授权
    • Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates
    • 可光聚合乙烯基醚基单体制剂和可包含某些新型螺二碳酸酯的可聚合组合物
    • US06458865B2
    • 2002-10-01
    • US09232500
    • 1999-01-15
    • Cecil C. ChappelowCharles S. PinzinoJ. David EickJoel D. Oxman
    • Cecil C. ChappelowCharles S. PinzinoJ. David EickJoel D. Oxman
    • C08F250
    • C07D493/10C08F2/50C08F16/12Y10S522/908
    • Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.
    • 提供了可光聚合的组合物,其是乙烯基醚,包含碘鎓盐,可见光增感剂和电子给体化合物的光引发剂体系的反应产物。 这些单体/低聚组合物还可以包括环氧化物,多元醇,螺原碳酸酯。 本发明的一个实施方案是由乙烯基醚,螺状碳酸酯和光引发剂体系组成的可聚合组合物。 本发明的另一个实施方案是由乙烯基醚,环氧化物,多元醇和光引发剂体系组成的可聚合组合物。 本发明的另一个实施方案是由乙烯基醚,环氧化物,多元醇,螺状碳酸酯和光引发剂体系组成的可聚合组合物。此外,本发明的另一个实施方案是某些新的螺状原碳酸酯化合物。 这些新型螺状原碳酸酯化合物中的每一种都包括至少一个环氧基作为取代基。