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41. 发明授权

US5101032A Cycloalkylidene dyes 失效
标题翻译： CYCLOALKYLIDENE DYES
公开(公告)号：US5101032A
公开(公告)日：1992-03-31
申请号：US600815
申请日：1990-10-22
申请人： Hans-Dieter Martin , Bernhard Albert , Knut Kessel
发明人： Hans-Dieter Martin , Bernhard Albert , Knut Kessel
IPC分类号： C09B17/00 , C09B19/00 , C09B23/00 , C09B23/10 , G03F7/031 , G03G5/06
CPC分类号： C09B23/105 , G03F7/031 , G03G5/0668 , G03G5/067
摘要： Cycloalkylidene dyes have the formula ##STR1## where m is 0 or 1,L is a chemical bond or C.sub.1 -C.sub.2 -alkylene, which may be substituted,R.sup.1 is hydrogen, C.sub.1 -C.sub.20 -alkyl, which may be phenyl-substituted, substituted or unsubstituted phenyl, naphthyl or C.sub.3 -C.sub.7 -cycloalkyl,Y is oxygen or two hydrogens,X.sup.1 is oxygen andX.sup.2 is C.sub.1 -C.sub.8 -alkanoyloxy, substituted or unsubstituted benzoyloxy, C.sub.1 -C.sub.6 -trialkylsilyloxy or a radical of the formula OR.sup.1 or NR.sup.2 R.sup.3, where R.sup.1 is as defined above and R.sup.2 and R.sup.3 are identical or different and each is independently of the other C.sub.1 -C.sub.20 -alkyl, which may be phenyl-substituted, substituted or unsubstituted phenyl, naphthyl, or C.sub.3 -C.sub.7 -cycloalkyl or R.sup.2 and R.sup.3 together with the nitrogen atom joining them are saturated heterocyclyl, or else one of R.sup.2 and R.sup.3 is hydrogen, or X.sup.1 and X.sup.2 together are a radical of the formula ##STR2## where Z is oxygen, sulfur or NR.sup.2, where R.sup.2 is as defined above, andQ is a carbocyclic or heterocyclic ring in which the substituents N and Z occupy adjacent positions.
摘要翻译：环亚烷基染料具有式“IMAGE”，其中m为0或1，L为化学键或可被取代的C 1 -C 2亚烷基，R 1为氢，C 1 -C 20 - 烷基，其可为苯基取代的或未取代的苯基，萘基或C 3 -C 7 - 环烷基，Y为氧或两个氢，X 1为氧，X 2为C 1 -C 8 - 烷酰氧基，取代或未取代的苯甲酰氧基，C 1 -C 6 - 三烷基甲硅烷氧基或式OR 1或NR 2 R 3基团其中R 1如上所定义，R 2和R 3相同或不同，并且各自独立地为C 1 -C 20 - 烷基，其可以是苯基取代的，取代或未取代的苯基，萘基或C 3 -C 7 - 环烷基或R 2 和R 3与连接它们的氮原子一起是饱和杂环基，或者R 2和R 3中的一个是氢，或者X 1和X 2一起是下式的基团，其中Z是氧，硫或NR 2，其中R2是并且Q是其中取代基N和Z占据相邻的碳环或杂环 nt职位。

42. 发明授权

US4999026A Transferring dyes for thermal printing: tri-cyano-vinyl aniline dyes 失效
标题翻译：用于热敏印刷的转移染料：三氰基乙烯基苯胺染料
公开(公告)号：US4999026A
公开(公告)日：1991-03-12
申请号：US384095
申请日：1989-07-24
申请人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
发明人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C09B23/14 , C09B29/03 , C09B29/033 , C09D5/26 , D06P5/13
CPC分类号： B41M5/385 , B41M5/3854 , B41M5/388 , Y10S8/922
摘要： Dyes are transferred from a carrier by sublimation/vaporization to plastic-coated papers by a process in which the dyes used are of the general formula (I) ##STR1## where A is D--N.dbd.N-- or ##STR2## R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkoxy, alkylthio or halogen and R.sup.1 and R together may furthermore form a 5-membered or 6-membered heterocyclic ring, and R and R' independently of one another are each hydrogen, phenyl which is unsubstituted or substituted by methyl or methoxy, or C.sub.5 - or C.sub.6 -cycloalkyl or C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.2 -C.sub.5 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 -or C.sub.3 -alkoxycarbonyloxy, hydroxyl, cyano, halogen, phenyl or C.sub.5 - or C.sub.6 -cycloalkyl, or ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring where D is a radical of a diazo component of the thiophene, thiazole, isothiazole or 1,2,4-thiadiazole series and R.sup.3 is hydrogen or CN.In the process, the dyes (I) give strong dyeings which have good light fastness and are resistant to chemical substances.
摘要翻译：染料通过升华/蒸发从载体转移到塑料涂布的纸上，其中使用的染料具有通式（I）的化合物（I），其中A是DN = N-或R1和 R 2各自为氢，烷基，烷氧基，烷硫基或卤素，R 1和R可以另外形成5元或6元杂环，R和R'彼此独立地为氢，未取代或取代的苯基 C 1 -C 4 - 烷氧羰基，C 2 -C 5 - 烷酰氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - C 4-烷氧基-C 2 - 或C 3 - 烷氧基羰基氧基，羟基，氰基，卤素，苯基或C 5 - 或C 6 - 环烷基，或者是5元或6元饱和杂环，其中D是重氮基团噻吩，噻唑，异噻唑或1,2,4-噻二唑系列的组分，R 3为氢或CN。在此过程中，染料（I）产生强烈的染色，耐光性好，耐化学物质。

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