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41. 发明授权

US4975497A Rubber compositions containing furazan oxides and transition metal salts 失效
标题翻译：含有呋咱氧化物和过渡金属盐的橡胶组合物
公开(公告)号：US4975497A
公开(公告)日：1990-12-04
申请号：US273650
申请日：1988-11-18
申请人： David P. Tate , Daniel F. Graves
发明人： David P. Tate , Daniel F. Graves
IPC分类号： C08K5/35
CPC分类号： C08K5/35
摘要： Modified rubber compositions are described which comprise at least one polymer rubber containing carbon-carbon unsaturation, at least one aromatic furazan oxide, and at least one hydrocarbon-soluble transition metal salt. When a transition metal salt is included in such polymer rubber formulations containing aromatic furazan oxides, the undesirable odors which normally characteristic of such rubber formulations is diminished or eliminated without significantly reducing the other desirable characteristics of the vulcanized rubbers. For example, filled vulcanizates made by vulcanizing mixtures in accordance with the invention exhibit high rebound, and tires which are formulated to include at least a portion of the cured vulcanizates in the tread exhibit reduced rolling resistance. Preferably, the hydrocarbon-soluble transition metal salts are the aliphatic or alicyclic monocarboxylic acid salts or cobalt, iron, nickel or manganese.
摘要翻译：描述了包含至少一种含有碳 - 碳不饱和键的聚合物橡胶，至少一种芳族呋咱氧化物和至少一种烃可溶性过渡金属盐的改性橡胶组合物。当含有芳族呋喃氧化物的聚合物橡胶配方中包含过渡金属盐时，通常这种橡胶配方特征的不希望的气味减少或消除，而不显着降低硫化橡胶的其它所需特性。例如，根据本发明的通过硫化混合物制成的填充硫化橡胶表现出高回弹性，并且被配制成包括至少一部分硫化橡胶在胎面中的轮胎表现出降低的滚动阻力。优选地，烃可溶的过渡金属盐是脂族或脂环族单羧酸盐或钴，铁，镍或锰。

42. 发明授权

US4927887A Modified rubber compositions containing aromatic six-membered heterocyclic nitrogen-containing groups 失效
标题翻译：含有芳香族六元杂环含氮基团的改性橡胶组合物
公开(公告)号：US4927887A
公开(公告)日：1990-05-22
申请号：US234105
申请日：1988-08-19
申请人： David P. Tate , Daniel F. Graves
发明人： David P. Tate , Daniel F. Graves
IPC分类号： B60C1/00 , C08C19/30 , C08C19/42
CPC分类号： B60C1/0016 , C08C19/30 , C08C19/42
摘要： Modified rubber compositions are described which when cured exhibit high rebound and reduced hysteresis. The uncured rubber compositions are prepared by reacting (a) at least one polymer rubber containing an alkali metal and carbon-carbon unsaturation with (b) at least one aromatic six-membered heterocyclic nitrogen-containing compound substituted with a group capable of reacting with the alkali metal of the polymer rubber. Filled vulcanizates made by vulcanizing a composition comprising at least one of the above-described uncured modified rubber compositions and one or more reinforcing fillers also are described. When tire treads are prepared utilizing the filled vulcanizates of the present invention, the tires exhibit improved properties such as reduced running temperature and rolling resistance.
摘要翻译：描述了改进的橡胶组合物，其在固化时表现出高的回弹和减小的滞后。未固化的橡胶组合物通过使（a）至少一种含有碱金属和碳 - 碳不饱和的聚合物橡胶与（b）至少一种被能与其反应的基团取代的芳族六元杂环含氮化合物聚合物橡胶的碱金属。还描述了通过硫化包含至少一种上述未固化的改性橡胶组合物和一种或多种增强填料的组合物制成的填充硫化橡胶。当利用本发明的填充硫化橡胶制备轮胎胎面时，轮胎表现出改善的性能，例如减少的运行温度和滚动阻力。

43. 发明授权

US4822845A Rubber compositions modified with heterocyclic di-N-oxides 失效
标题翻译：用杂环二-N-氧化物改性的橡胶组合物
公开(公告)号：US4822845A
公开(公告)日：1989-04-18
申请号：US37486
申请日：1987-04-13
申请人： Daniel F. Graves , Hans-Wilhelm Engels
发明人： Daniel F. Graves , Hans-Wilhelm Engels
IPC分类号： C08K5/34 , C07D241/52 , C08K5/3465 , C08L21/00 , C08K3/04 , C08C4/00
CPC分类号： C07D241/52 , C08K5/3465 , Y10T152/10855
摘要： It now has been found that uncured rubber composition comprising rubbers having an unsaturated carbon chain and at least one carbon black can be improved by including therein, a minor property-improving amount of at least one aromatic heterocyclic di-N-oxide compound of the partial formula ##STR1## wherein the depicted carbon atoms are part of an optionally substituted aromatic ring, and R.sup.1 and R.sup.2 are each independently hydrogen, hydrocarbyl, halohydrocarbyl, hydrocarbyloxy, hydrocarbyl sulfonyl, hydrocarbyl thio, hydrocarbylsulfoxidyl, halogen, amino,--CN--OH--CHO--CH(O hydrocarbyl)2--C(O)R.sup.3--C(O)OR.sup.3--C(N--OH)R.sup.3--C(O)NR.sup.3 R.sup.6--CH.dbd.N--NH--C(O)OR.sup.3--CH.sub.2 OC(O)CH.sub.3--R.sup.4 YR.sup.3--C(O)NHR.sup.4 OH--C(NH)NR.sup.7 R.sup.8,or--C(O)NHN(R.sup.3).sub.2wherein each R.sup.3 is independently hydrogen or a hydrocarbyl group, R.sup.4 is a divalent hydrocarbyl group, R.sup.6 is hydrogen, hydrocarbyl, --R.sup.4 OR.sup.3, or --R.sup.4 COOR.sup.3 ; R.sup.7 is hydrogen or a hydrocarbyl group; R.sup.8 is hydrogen or a hydrocarbyl, an amino, or a hydroxyl group; R.sup.7 and R.sup.8 may be hydrocarbyl groups joined together to form a ring including the nitrogen atom, and Y is O, divalent S, --NH--, --S(O)-- or --S(O).sub.2 or R.sup.1 and R.sup.2 may be joined together to form further ring systems which may be saturated or unsaturated, and further substituted or unsubstituted. When vulcanizates are prepared from such uncured rubber compositions, particularly when the carbon black used therein has an average surface area of at least about 20 m.sup.2 /g, the vulcanizates exhibit reduced low strain hysteresis and exhibit no significant undesirable odor.In another aspect of the invention, a filled vulcanizate made by vulcanizing uncured compositions of the type described above and containing a filler, particularly carbon black, is improved in filler interaction, hysteresis, modulus, compression set and resiliency. Rubber articles and portions thereof made from such vulcanizates such as tires, hoses, belts, springs, treads, sidewalls, and the like can be made utilizing the improved filled vulcanizates of the invention.

44. 发明授权

US4761446A Rubber compositions modified with benzimidazo-linones 失效
标题翻译：用苯并咪唑啉酮改性的橡胶组合物
公开(公告)号：US4761446A
公开(公告)日：1988-08-02
申请号：US37378
申请日：1987-04-13
申请人： Daniel F. Graves , Hans-Wilhelm Engels
发明人： Daniel F. Graves , Hans-Wilhelm Engels
IPC分类号： B29D30/00 , B29K21/00 , C08J5/00 , C08K5/34 , C08K5/3447 , C08L21/00
CPC分类号： C08K5/3447
摘要： It now has been found that the properties of filled rubber compositions comprising rubbers having an unsaturated carbon chain can be improved by including therein, a minor property-improving amount of at least one 1,3-dihydroxy-benzimidazolinone or derivative compound of the formula ##STR1## wherein R is hydrogen, or a halogen, hydroxyl, lower hydrocarbyl, lower hydrocarbyloxy, lower hydrocarbylthio, lower hydrocarbyl nitrile, carboxyl, cyano, nitro, amino, amide or --C(O)--R'" where R'" is an aryl or a lower hydrocarbyl group; each R' independently is H, lower alkyl, acyl, CONR"2 or CONHR" where R" is alkyl or aryl. When vulcanizates are prepared from such uncured rubber compositions, the vulcanizates exhibit reduced low strain hysteresis and a high electrical resistivity.In another aspect of the invention, a filled vulcanizate made by vulcanizing uncured compositions of the type described above and containing a filler, particularly carbon black, is improved in filler interaction, hysteresis, modulus, compression set and resiliency. Rubber articles and portions thereof such as tires, hoses, belts, springs, tread, sidewalls and the like can be made utilizing the improved filled vulcanizates of the invention.

45. 发明授权

US4570690A Mixing procedure for obtaining filled rubber vulcanizates containing aromatic furazan oxides 失效
标题翻译：用于获得含有芳族呋喃氧化物的填充橡胶硫化橡胶的混合方法
公开(公告)号：US4570690A
公开(公告)日：1986-02-18
申请号：US653652
申请日：1984-09-21
申请人： Daniel F. Graves
发明人： Daniel F. Graves
IPC分类号： C08K5/34 , C08K5/35 , C08K5/353 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08C4/00 , C08K3/04
CPC分类号： C08K5/35 , C08K5/353
摘要： Filled rubber vulcanizates containing aromatic furazan oxides exhibit many improved properties such as increased filler-rubber interaction and decreased hysteresis. Useful furazan oxides have both carbons of the furazan ring as part of a fused aromatic ring. Typical examples are benzofurazan oxide and its methyl and methoxy analogs. Tires made from the inventive vulcanizates show lower running temperatures and improved rolling resistance. The desirable effects of the aromatic furazan oxides may be improved by mixing the rubber, filler and furazan oxide in a conventional mechanical compounding device at specific temperatures and time periods such as about 200.degree.-400.degree. F. for 2-20 minutes.
摘要翻译：含有芳族呋咱氧化物的填充橡胶硫化橡胶具有许多改进的性能，例如增加的填料 - 橡胶相互作用和减小的滞后。有用的呋咱氧化物具有作为稠合芳环的一部分的呋咱环的碳。典型的实例是苯并呋喃氧化物及其甲基和甲氧基类似物。由本发明的硫化橡胶制成的轮胎显示较低的运行温度和改善的滚动阻力。通过在常规的机械配混装置中将橡胶，填料和呋咱氧化物在特定温度和时间如约200-400°F下混合2-20分钟可以改善芳族呋咱氧化物的期望效果。

46. 发明授权

US4226840A Process for the polymerization of cyclic polyhalophosphazenes using a catalyst composition of boron trihalide and oxygenated phosphorus compounds 失效
标题翻译：使用三卤化硼和氧化磷化合物的催化剂组合物聚合环状多卤代膦腈的方法
公开(公告)号：US4226840A
公开(公告)日：1980-10-07
申请号：US77245
申请日：1979-09-19
申请人： John W. Fieldhouse , Daniel F. Graves
发明人： John W. Fieldhouse , Daniel F. Graves
IPC分类号： B01J27/00 , B01J31/00 , C01B21/098 , C01B25/10
CPC分类号： C01B21/098 , C01B21/0986
摘要： Linear polydihalophosphazene polymers which are substantially free of gel are prepared by thermally polymerizing a cyclic polyhalophosphazene represented by the formula (NPX.sub.2).sub.3, wherein X is fluorine, chlorine or bromine in the presence of a catalyst which comprises the reaction product of a boron trihalide compound with an oxygenated phosphorus compound.In addition to producing substantially gel free polymers, the catalyst composition of the process of the invention permits improved control of molecular weight, lower polymerization temperature, high rates of conversion of (NPCl.sub.2).sub.3 to (NPCl.sub.2).sub.n and provides for more readily processible and derivatizable polymers.
摘要翻译：基本上不含凝胶的线性聚二卤代磷腈聚合物通过在催化剂存在下热聚合由式（NPX2）3表示的环状多卤代膦（NPX2）3，其中X是氟，氯或溴，其包含三卤化硼化合物与氧化磷化合物。除了生产基本上不含凝胶的聚合物之外，本发明方法的催化剂组合物允许改进分子量的控制，较低的聚合温度，（NPCl 2）3转化为（NPCl 2）n的高转化率，并提供更容易加工和可衍生聚合物。

47. 发明授权

US4207403A Oil-free elastomeric poly(aryloxyphosphazene) copolymer foam 失效
标题翻译：无油弹性聚（芳氧基磷腈）共聚物泡沫
公开(公告)号：US4207403A
公开(公告)日：1980-06-10
申请号：US30598
申请日：1979-04-16
申请人： Tai C. Cheng , John W. Fieldhouse , Arthur E. Oberster , Daniel F. Graves
发明人： Tai C. Cheng , John W. Fieldhouse , Arthur E. Oberster , Daniel F. Graves
IPC分类号： C08G79/02 , C08J9/10 , C08L85/02 , H01B3/30
CPC分类号： C08J9/10 , C08G79/025 , C08L85/02 , H01B3/30 , C08J2385/02 , Y10T428/294
摘要： Poly(aryloxyphosphazene) copolymers are prepared having randomly repeating units represented by the formula: ##STR1## wherein R and R.sup.1 may be the same or different and are selected from the group consisting of monovalent aryl radicals and substituted aryl radicals having the structure: ##STR2## wherein X is a substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, amino and halogen substituted on any sterically permissible position on the phenyl group; and wherein the amount of Cl present in the form of P-Cl bonds is from about 0.4 percent to about 10 percent by weight based upon the total weight of copolymer.The copolymers may contain minor proportions of randomly distributed units in addition to the repeating units described above, these additional units containing reactive sites enabling the properties of the copolymers to be modified by crosslinking and/or curing.The copolymers are elastomeric even in the absence of low molecular weight polyphosphazene oils. The copolymers are curable by a variety of curing agents such as sulfur and peroxides, and can also be cured by radiation and ultraviolet light. The copolymers may be utilized in various applications such as foams and coatings, and are particularly suited for use in wire coating formulations.
摘要翻译：制备具有由下式表示的无规重复单元的聚（芳氧基磷腈）共聚物：其中R和R 1可以相同或不同，并且选自具有以下结构的一价芳基和取代的芳基：其中X是选自烷基，烷氧基，芳基，芳氧基，氨基和在苯基上的任何空间上允许的位置上取代的卤素的取代基; 并且其中以P-Cl键形式存在的Cl的量为基于共聚物总重量的约0.4重量％至约10重量％。除了上述重复单元之外，共聚物可以含有少量的随机分布的单元，这些含有能够通过交联和/或固化来改性共聚物性质的反应性位点的这些附加单元。即使在不存在低分子量聚磷腈油的情况下，共聚物也是弹性体。共聚物可通过各种固化剂如硫和过氧化物固化，并且还可以通过辐射和紫外光固化。共聚物可以用于各种应用中，例如泡沫和涂料，并且特别适用于丝线涂布配方。

48. 发明授权

US4128710A Process for the production of phosphazene polymers 失效
标题翻译：磷腈聚合物的制备方法
公开(公告)号：US4128710A
公开(公告)日：1978-12-05
申请号：US845009
申请日：1977-10-25
申请人： John W. Fieldhouse , Daniel F. Graves , William M. Cole , Mark L. Stayer , Steven L. Fenske
发明人： John W. Fieldhouse , Daniel F. Graves , William M. Cole , Mark L. Stayer , Steven L. Fenske
IPC分类号： C08G79/00 , C08G79/02 , C08G73/00 , C08J3/00
CPC分类号： C08G79/025
摘要： The production of phosphazene polymers represented by the general formula ##STR1## WHEREIN R and R' are organic radicals hereinafter defined, and wherein n is an integer from 20 to upwards of 50,000 wherein one or more kinds of OR or OR' groups is attached to the phosphorus atoms in a substantially linear chain of alternating P and N atoms, the groups when more than one group is present being randomly distributed along the PN backbone, as described in copending United States Patent Application Ser. No. 824,004 filed Aug. 12, 1977, is enhanced by an improved procedure for the separation of the sodium chloride by-product from the derivatized phosphazene polymer. By treating the reaction mixture with carbon dioxide, in the presence of water and preferably with an additional alkali metal salt, agglomeration of the sodium chloride is accomplished, and a clean separation of the NaCl from the polyphosphazene ester is more readily achieved.
摘要翻译： {PG，1}由通式{r1 {tc，1 {rb {ab，44 {m，1 {sb，21 {m，2 {ob，5 {mr，1P {M， 3 {AB，2 OR {MR，3 {AB，6 OR {40 {MR，3 {AD，444 N {M，4 {AB，44 {MR，4 {S，15 {MY，2 {CB，5 {BL，88 {S，6 {HD n {re {PS {PS WHEREIN R和R {40 {0是下文定义的有机基团，其中{1为20至高达50,000的整数，其中一个或多个 OR或OR的种类（40个O基团连接在交替的P和N原子的基本线性链中的磷原子，当存在多于一个基团时的基团沿着PN骨架随机分布，如共同未决United 国家专利申请 1977年8月12日提交的No.824,004通过用于从衍生的磷腈聚合物分离氯化钠副产物的改进方法得到增强。通过用二氧化碳处理反应混合物，在水的存在下，优选用另外的碱金属盐，完成氯化钠的附聚，更容易实现NaCl与聚磷腈酯的清洁分离。

49. 发明授权

US08754169B2 Method of preparing rubber comprising polymeric compositions and isoprene comprising interpolymers 失效
标题翻译：制备包含聚合物组合物和包含互聚物的异戊二烯的橡胶的方法
公开(公告)号：US08754169B2
公开(公告)日：2014-06-17
申请号：US13616809
申请日：2012-09-14
申请人： Mark N. Dedecker , James E. Hall , Daniel F. Graves
发明人： Mark N. Dedecker , James E. Hall , Daniel F. Graves
IPC分类号： C08F287/00 , C08L55/02 , C08L9/06
CPC分类号： C08F287/00
摘要： A method for forming a rubber-modified polymeric composition includes polymerizing vinyl aromatic monomer within a mixture including the vinyl aromatic monomer and an interpolymer having at least one block of polyisoprene, at lest one block of polystyrene, and at lest one block of polybutadiene to thereby form the rubber-modified polymeric composition, where the interpolymer includes an internal block of polyisoprene.
摘要翻译：形成橡胶改性聚合物组合物的方法包括在包含乙烯基芳族单体和互聚物的混合物中聚合乙烯基芳族单体，所述互聚物具有至少一个聚异戊二烯嵌段，至少一个聚苯乙烯嵌段，至少一个聚丁二烯嵌段形成橡胶改性的聚合物组合物，其中互聚物包括聚异戊二烯的内部嵌段。

50. 发明授权

US06362283B1 Block copolymers interpolymerized with in situ polystyrene and process for preparation thereof 失效
标题翻译：用原位聚苯乙烯共聚的嵌段共聚物及其制备方法
公开(公告)号：US06362283B1
公开(公告)日：2002-03-26
申请号：US09676239
申请日：2000-09-29
申请人： Mark H. Wollum , Daniel F. Graves
发明人： Mark H. Wollum , Daniel F. Graves
IPC分类号： C08F25506
CPC分类号： C08F297/04 , C08L53/02 , C08L2666/04
摘要： A process for interpolymerizing a vinyl aromatic hydrocarbon polymer and a block polymer is disclosed. The process includes the following steps: (a) forming a block polymer precursor of at least one polymeric block containing conjugated diene monomer contributed units in the presence of an anionic initiator and in an inert diluent, the block polymer precursor having living ends; and (b) thereafter adding to the block polymer precursor a charge of a vinyl aromatic hydrocarbon monomer and an additional charge of an anionic initiator to simultaneously form (1) a block polymer having a terminal block formed from the charge of vinyl aromatic hydrocarbon monomer attached to the block polymer precursor and (2) a poly(vinyl aromatic hydrocarbon) polymer interpolymerized with the block polymer. The practice of this process produces a vinyl aromatic hydrocarbon block terminated block polymer, such as SBS, interpolymerized with a polymer formed from vinyl aromatic hydrocarbon monomer, such as polystyrene. The resultant interpolymer has a high Gardner Impact Strength and good processability.
摘要翻译：公开了一种使乙烯基芳族烃聚合物和嵌段聚合物共聚的方法。该方法包括以下步骤：（a）在阴离子引发剂存在下，在惰性稀释剂中形成含有共轭二烯单体的至少一个聚合物嵌段的嵌段聚合物前体，所述嵌段聚合物前体具有活性末端; 和（b）然后向嵌段聚合物前体中加入乙烯基芳族烃单体和另外的阴离子引发剂的电荷，以同时形成（1）具有由连接的乙烯基芳族烃单体的电荷形成的末端嵌段的嵌段聚合物嵌段聚合物前体和（2）与嵌段聚合物共聚的聚（乙烯基芳族烃）聚合物。该方法的实践产生与由乙烯基芳族烃单体如聚苯乙烯形成的聚合物共聚的乙烯基芳族烃嵌段封端的聚合物，例如SBS。所得到的互聚物具有较高的加德纳冲击强度和良好的加工性能。

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