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41. 发明授权

US4923784A Photographic elements containing a bleach accelerator precursor 失效
标题翻译：含有漂白促进剂前体的摄影元素
公开(公告)号：US4923784A
公开(公告)日：1990-05-08
申请号：US270926
申请日：1988-11-14
申请人： John W. Harder , Stephen P. Singer
发明人： John W. Harder , Stephen P. Singer
IPC分类号： G03C1/34 , G03C1/43 , G03C7/392 , G03C7/42
CPC分类号： G03C1/346 , G03C1/43 , G03C7/3924 , G03C7/421
摘要： Silver halide photographic elements are described containing, as a bleach accelerator precursor, a silver salt of an acid-containing, non-zwitterionic, organic thiol. The bleach accelerators are operable with a multiplicity of bleach compositions and help in reducing sensitizing dye stain.

42. 发明授权

US06893809B2 Silver halide photographic element containing fogged emulsions for accelerated development 失效
公开(公告)号：US06893809B2
公开(公告)日：2005-05-17
申请号：US10244569
申请日：2002-09-16
申请人： Kenneth J. Reed , James A. Friday , John E. Keevert , Stephen P. Singer , Mary C. Brick
发明人： Kenneth J. Reed , James A. Friday , John E. Keevert , Stephen P. Singer , Mary C. Brick
IPC分类号： G03C1/035 , G03C1/04 , G03C1/43 , G03C7/00 , G03C7/30 , G03C7/305 , G03C7/333 , G03C1/46
CPC分类号： G03C7/30541 , G03C1/0051 , G03C1/04 , G03C7/3022 , G03C7/3029 , G03C7/3041 , G03C7/30594 , G03C7/333 , G03C2007/3032 , G03C2007/3034 , G03C2200/38 , G03C2200/53 , Y10S430/156
摘要： This invention relates to a negative silver halide photographic element comprising a support and a silver halide imaging layer containing a light sensitive silver halide imaging emulsion, said silver halide imaging layer further comprising a separately precipitated non-imaging intentionally fogged fine grain emulsion and an electron transfer agent releasing compound represented by formula (I): CAR1-(L)n-ETA (I) wherein: CAR1 is a carrier moiety which is capable of releasing -(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable electron transfer agent, and (optionally) a development accelerator releasing compound represented by the formula (II): CAR2—(SAM)-NX1—NX2X3 (II) wherein: CAR2 is a carrier moiety which is capable of releasing —(SAM)-NX1—NX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and —NX1—NX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl, or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.

43. 发明授权

US06790602B2 Method of making a silver halide photographic material having enhanced light absorption and low fog 失效
标题翻译：制备具有增强的光吸收和低雾的卤化银照相材料的方法
公开(公告)号：US06790602B2
公开(公告)日：2004-09-14
申请号：US10346745
申请日：2003-01-17
申请人： David R. Foster , Stephen P. Singer , William J. Harrison , Alan R. Pitt
发明人： David R. Foster , Stephen P. Singer , William J. Harrison , Alan R. Pitt
IPC分类号： G03C1005
CPC分类号： G03C1/38 , G03C1/005 , G03C1/29 , G03C7/39216 , G03C7/39236 , G03C2001/0854
摘要： This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
摘要翻译：本发明涉及一种使卤化银乳剂光谱增感的方法，包括以下顺序的以下步骤：a）提供包含具有与卤化银颗粒相邻的内染料层的片状卤化银颗粒的卤化银乳剂，所述染料层至少包含能够使卤化银光谱增感的一种染料（染料1），b）向该乳液中加入至少一种能够提供与该内部染料层相邻的第二染料层的染料（染料2），以及c）向该乳液中添加非阳离子表面活性剂或用于氧化显影剂的清除剂或两者的组合，以形成包含与其相关联的两个染料层的卤化银颗粒的卤化银乳剂，其中染料层通过非共价键或通过原位结合; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。

44. 发明授权

US06350564B1 Color photographic element containing speed improving compound in combination with reflecting material 失效
标题翻译：含有速度改善化合物与反射材料组合的彩色照相元件
公开(公告)号：US06350564B1
公开(公告)日：2002-02-26
申请号：US09690310
申请日：2000-10-17
申请人： Joseph F. Bringley , James A. Friday , Stephen P. Singer , Marcello Vitale
发明人： Joseph F. Bringley , James A. Friday , Stephen P. Singer , Marcello Vitale
IPC分类号： G03C110
CPC分类号： G03C7/39276 , G03C1/8255 , G03C7/3029 , G03C7/30541 , G03C7/30576 , G03C7/39256 , G03C7/3926 , G03C7/39272 , G03C2007/3034
摘要： Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) a light reflecting silver halide material; provided that the heterocycle compound and the light reflecting material are located either (a) in different layers of the element located close enough to each other so that a super-additive speed increase is realized or (b) in the same light sensitive layer. The invention provides improved light sensitivity.
摘要翻译：公开了一种彩色卤化银照相元件，其包括载体：（1）感光卤化银乳剂层;（2）具有至少三个不与氧化显影剂反应的杂原子的氮杂环不含游离硫醇取代基并且具有足够的ClogP以增加与没有化合物的相同元件相比所述元件的照相速度，所述杂环化合物位于所述光敏层中或位于与其相邻的层中; 和（3）光反射卤化银材料;条件是杂环化合物和光反射材料位于元件的不同层中（a）位于彼此足够靠近的位置，从而实现超加速度增加，或（b）在相同的光敏层。本发明提供了改善的光敏度。

45. 发明授权

US06255045B1 Color photographic element containing improved polymeric disulfonamidophenol for scavenging oxidized developer 失效
标题翻译：含有改进的聚合二磺酰胺苯酚用于清除氧化显影剂的彩色照相元件
公开(公告)号：US06255045B1
公开(公告)日：2001-07-03
申请号：US09523841
申请日：2000-03-13
申请人： Tienteh Chen , Stephen P. Singer , Ronald E. Leone
发明人： Tienteh Chen , Stephen P. Singer , Ronald E. Leone
IPC分类号： G03C173
CPC分类号： G03C7/39236 , G03C7/39216
摘要： This invention relates to a photographic element comprising a support, a radiation sensitive silver halide emulsion layer and a water dispersible polymeric disulfonamidophenol that is substantially immobile in the element. The invention provides color photographic elements that exhibit improved stability, color reproduction and robustness in terms of processing variations; particularly variations in red density due to sensitizing dye.
摘要翻译：本发明涉及一种照相元件，其包括支撑体，辐射敏感卤化银乳剂层和基本上不可移动的元件中的水分散性聚合二磺酰胺基苯酚。本发明提供了彩色照相元件，其在加工变化方面表现出改进的稳定性，色彩再现性和鲁棒性; 特别是由于敏化染料导致的红色密度变化。

46. 发明授权

US5821039A Photographic element containing neutral dye-forming resorcinol coupler 失效
标题翻译：含有中性染料形成间苯二酚成色剂的摄影元件
公开(公告)号：US5821039A
公开(公告)日：1998-10-13
申请号：US866786
申请日：1997-05-30
申请人： Ronald E. Leone , Stephen P. Singer
发明人： Ronald E. Leone , Stephen P. Singer
IPC分类号： G03C7/34 , G03C1/00 , G03C7/388 , G03C7/392 , G03C7/32
CPC分类号： G03C7/39216 , G03C7/3885
摘要： A color photographic element which comprises a light sensitive silver halide emulsion layer containing a 5-carbamoyl-1,3-dihydroxybenzene compound having a ClogP of at least 4. The element provides a black and white image using conventional color negative processing.
摘要翻译：一种彩色照相元件，其包含含有至少为4的ClogP的5-氨基甲酰基-1,3-二羟基苯化合物的感光卤化银乳剂层。该元件使用常规的彩色负片处理提供黑白图像。

47. 发明授权

US5599656A Photographic materials having releasable compounds 失效
标题翻译：具有可释放化合物的摄影材料
公开(公告)号：US5599656A
公开(公告)日：1997-02-04
申请号：US563725
申请日：1990-08-06
申请人： Drake M. Michno , Richard P. Szajewski , Stephen P. Singer
发明人： Drake M. Michno , Richard P. Szajewski , Stephen P. Singer
IPC分类号： G03C1/42 , G03C7/305 , G03C7/32
CPC分类号： G03C7/30541 , Y10S430/156 , Y10S430/158
摘要： Photographic elements are disclosed having a first coupler represented by the formula:COUP.sub.1 -T-INHwhereinCOUP.sub.1 is a coupler moiety,T is a timing group bonded to INH through a substituted or unsubstituted methylene group contained in T and bonded to COUP.sub.1 through an O, S, or N atom contained in T,and INH is a development Inhibitor moiety, andwherein the T-INH group is able to undergo electron transfer along a conjugated system therein to cleave INH after T-INH is cleaved from COUP.sub.1, anda second coupler represented by the formula:COUP.sub.2 -(TIME).sub.n -S-R.sub.1 -R.sub.2wherein COUP.sub.2 is a coupler moiety, TIME is a timing group, n is 0 or 1, R.sub.1 is a divalent linking group that does not include a heterocyclic ring attached directly to S, and R.sub.2 is a water solubilizing group.
摘要翻译：公开了具有由下式表示的第一成色剂的摄影元件：COUP1-T-INH，其中COUP1为成色剂部分，T为通过T中含有的取代或未取代的亚甲基与INH键合的时基，并通过O键合至COUP1， S或N原子，INH是显影抑制剂部分，其中T-INH基团能够沿着其共轭体系进行电子转移，以在T-INH从COUP1切割后切割INH，第二 COUP2-（TIME）nS-R1-R2表示的成色剂，COUP2为成色剂部分，TIME为定时基团，n为0或1，R1为不包括直接与 S和R2是水溶性基团。

48. 发明授权

US5478712A Photographic elements protected against color contamination and dye stain 失效
标题翻译：防止颜色污染和染色剂污染的照相元件
公开(公告)号：US5478712A
公开(公告)日：1995-12-26
申请号：US156337
申请日：1993-11-22
申请人： Stephen P. Singer , Susan D. Hill
发明人： Stephen P. Singer , Susan D. Hill
IPC分类号： G03C7/00 , G03C1/18 , G03C7/30 , G03C7/392 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/3029 , G03C1/18 , G03C7/39216 , G03C7/39236
摘要： A ballasted amine is incorporated in a silver halide photographic element which contains a 2,4-disulfonamidophenol which functions as a scavenger for oxidized developing agent. The 2,4-disulfonamidophenol serves to avoid color contamination while the ballasted amine serves to reduce dye stain.
摘要翻译：将镇压胺掺入卤化银照相元件中，其含有作为氧化显影剂的清除剂的2,4-二磺酰胺基苯酚。 2,4-二磺酰胺苯酚用于避免颜色污染，而镇流胺用于减少染料染色。

49. 发明授权

US5455150A Color photographic negative elements with enhanced printer compatibility 失效
标题翻译：彩色照相底片，增强打印机兼容性
公开(公告)号：US5455150A
公开(公告)日：1995-10-03
申请号：US75068
申请日：1993-06-10
申请人： Jared B. Mooberry , Paul B. Merkel , Stephen P. Singer
发明人： Jared B. Mooberry , Paul B. Merkel , Stephen P. Singer
IPC分类号： G03C7/00 , G03C1/83 , G03C7/18 , G03C7/392 , G03C1/46
CPC分类号： G03C7/18 , G03C1/83
摘要： A silver halide photographic negative has a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a coupler which reacts with oxidized color developer to form a magenta dye. The coupler in the green sensitive layer produces a magenta dye which has relatively low density in the 560-590 nm range as compared with magenta dyes produced by pyrazolotriazole type couplers or 1-phenyl-3-acylamino-5-pyrazolone couplers. The element additionally has an inert dye present, preferably positioned below the green sensitive layer containing the foregoing coupler. The inert dye has a peak absorption between 560-590 nm so that the negative has a ratio of density at 580 nm to density at 550 nm, both as measured at neutral midscale exposure, which is greater than exhibited by the element absent the inert dye.
摘要翻译：卤化银照相底片具有含有与氧化显色剂反应形成青色染料的成色剂的红色敏感层，含有与氧化显色剂反应形成黄色染料的成色剂的蓝色敏感层和含有与氧化的彩色显影剂反应形成品红色染料的成色剂。绿色敏感层中的成色剂产生品红色染料，与由吡唑并三唑型成色剂或1-苯基-3-酰基氨基-5-吡唑啉酮成色剂产生的品红色染料相比，在560-590nm范围内具有相对较低的密度。元素另外具有存在的惰性染料，优选位于含有前述成色剂的绿色敏感层下方。惰性染料在560-590nm之间具有峰值吸收，使得阴性在580nm处的密度与550nm处的密度之比（无论是在惰性染料中没有表现出的中性中值曝光）。

50. 发明授权

US5298368A Photographic coupler compositions and methods for reducing continued coupling 失效
标题翻译：摄影耦合器组合物和减少连续耦合的方法
公开(公告)号：US5298368A
公开(公告)日：1994-03-29
申请号：US689436
申请日：1991-04-23
申请人： Paul B. Merkel , Edward Schofield , Stephen P. Singer
发明人： Paul B. Merkel , Edward Schofield , Stephen P. Singer
IPC分类号： G03C7/384 , G03C7/30 , G03C7/388 , G03C7/392 , G03C1/34 , G03C7/42
CPC分类号： G03C7/3003 , G03C7/3012 , G03C7/3885
摘要： Photographic coupler compositions comprise (a) a pyrazolone magenta dye-forming coupler compound, and (b) a sulfoxide compound in an amount sufficient to reduce continued coupling of the coupler compound during the bleach step of a color photographic process. The sulfoxide compound is of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of straight and branched chain alkyl groups, alkenyl groups and alkylene groups; straight and branched chain alkyl groups, alkenyl groups and alkylene groups containing at least one substituent selected from the group consisting of alkoxy, aryloxy, aryl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido and carbamoyl groups and halogen atoms; a phenyl group; and a phenyl group containing at least one substituent selected from the group consisting of alkyl, alkoxy, aryloxy, aryl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido and carbamoyl groups and halogen atoms. Additionally, R.sub.1 and R.sub.2 combined contain at least 12 carbon atoms. Preferably, the coupler composition is substantially free of phenol compounds when R.sub.1 and R.sub.2 are other than unsubstituted alkyl, alkenyl or alkylene groups.
摘要翻译：摄影成色剂组合物包含（a）形成吡唑啉酮品红色染料的成色剂化合物，和（b）足够量的亚砜化合物，其量可以在彩色照相法漂白步骤期间减少偶合剂化合物的持续偶联。亚砜化合物具有式（*化学结构*），其中R 1和R 2分别选自直链和支链烷基，烯基和亚烷基; 直链和支链烷基，烯基和含有至少一个选自烷氧基，芳氧基，芳基，烷氧基羰基，芳氧基羰基，酰氧基，碳酰氨基和氨基甲酰基和卤素原子的取代基的亚烷基; 苯基; 和含有至少一个选自烷基，烷氧基，芳氧基，芳基，烷氧基羰基，芳氧基羰基，酰氧基，碳酰氨基和氨基甲酰基和卤素原子的取代基的苯基。另外，R 1和R 2组合含有至少12个碳原子。当R 1和R 2不是未取代的烷基，烯基或亚烷基时，优选地，所述成色剂组合物基本上不含酚化合物。

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