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41. 发明申请

US20110160408A1 ISOSORBIDE-BASED POLYCARBONATES, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 有权
标题翻译：基于异构体的聚碳酸酯，其制备方法和形成的制品
公开(公告)号：US20110160408A1
公开(公告)日：2011-06-30
申请号：US12893457
申请日：2010-09-29
申请人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan-Pleun Lens , Hendrik Theodurus van de Grampel
发明人： Hans de Brouwer , Robert Dirk van de Grampel , Jan Henk Kamps , Jan-Pleun Lens , Hendrik Theodurus van de Grampel
IPC分类号： C08L67/04 , C08L67/00 , C08L83/06
CPC分类号： C08L69/00 , C08G64/0266 , C08G64/1666 , C08G64/186 , C08L83/10 , C08L2205/02 , C08L2666/18
摘要： Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit, and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units, the aliphatic unit different from the isosorbide unit is derived from an aliphatic oligomeric polyester polyol having a molecular weight of 900 to 4000, and the calculated bio-content is greater than or equal to 40 weight percent, based on the total weight of the polycarbonate polymer.
摘要翻译：本文公开了一种聚碳酸酯聚合物，其包含：异山梨醇单元，聚硅氧烷单元和不同于异山梨醇单元的脂肪族单元，其中所述异山梨醇单元，聚硅氧烷单元和脂肪族单元各自为碳酸酯，或碳酸酯和酯单元的组合，与异山梨醇单元不同的脂肪族单元来自分子量为900〜4000的脂族低聚聚酯多元醇，计算出的生物含量大于或等于40重量％，基于聚碳酸酯聚合物的总重量。

42. 发明申请

US20100130700A1 POLYESTERCARBONATE COPOLYMERS WITH HIGH SCRATCH RESISTANCE 有权
标题翻译：具有高耐刮擦性能的聚酯碳酸酯共聚物
公开(公告)号：US20100130700A1
公开(公告)日：2010-05-27
申请号：US12275428
申请日：2008-11-21
申请人： Hans de Brouwer , Robert Dirk van Grampel , James F. Hoover , Adrianus Alphonsus Maria Kusters , Jan-Pleun Lens , Andries Jakobus Petrus van Zyl
发明人： Hans de Brouwer , Robert Dirk van Grampel , James F. Hoover , Adrianus Alphonsus Maria Kusters , Jan-Pleun Lens , Andries Jakobus Petrus van Zyl
IPC分类号： C08G63/78 , C08G63/00
CPC分类号： C08G63/64
摘要： Disclosed are polyestercarbonate copolymers comprising a carbonate unit of Formula (I), an ITR ester unit of Formula (V), and optionally a different carbonate unit of Formula (VI): wherein Ra, Rb, p, q, A, h, j, k, Rc, r, and R1 are as described herein. The polyestercarbonate copolymers have a combination of scratch resistance, good flow, and good weatherability.
摘要翻译：公开了包含式（I）的碳酸酯单元，式（V）的ITR酯单元和任选的式（VI）的不同碳酸酯单元的聚酯碳酸酯共聚物：其中Ra，Rb，p，q，A，h，j ，k，Rc，r和R1如本文所述。聚酯碳酸酯共聚物具有耐擦伤性，良好的流动性和良好的耐候性的组合。

43. 发明授权

US07700696B2 Polycarbonate composition having improved scratch resistance, and articles formed therefrom 有权
标题翻译：具有改进的耐刮擦性的聚碳酸酯组合物和由其形成的制品
公开(公告)号：US07700696B2
公开(公告)日：2010-04-20
申请号：US11427102
申请日：2006-06-28
申请人： Robert Dirk van de Grampel , Jan-Pleun Lens , Dake Shen
发明人： Robert Dirk van de Grampel , Jan-Pleun Lens , Dake Shen
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08L69/005 , C08L2666/18
摘要： A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
摘要翻译：热塑性组合物包含A）25至95重量份的第一聚碳酸酯，其基本上由以下组成：i）25至100摩尔％的包含烷基取代的双酚碳酸酯单元的第一碳酸酯单元，ii）0至75摩尔％的第二碳酸酯单元，其中第一和第二碳酸酯单元不相同，第一和第二碳酸酯单元在第一聚碳酸酯中的摩尔百分比之和为100摩尔％; B）5〜75重量份碳酸酯单元与芳基酯单元的摩尔比为95:5〜10:90的聚酯 - 聚碳酸酯; 和C）0至65重量份的第二聚碳酸酯，其中第一聚碳酸酯和第二聚碳酸酯不相同，并且第一聚碳酸酯，聚酯 - 聚碳酸酯和第二聚碳酸酯的重量份之和为100份重量。

44. 发明授权

US07557175B2 Poly(carbonate-co-urea) copolymers and melt transesterification method of preparing these copolymers 失效
标题翻译：聚（碳酸酯 - 共 - 尿素）共聚物和制备这些共聚物的熔融酯交换法
公开(公告)号：US07557175B2
公开(公告)日：2009-07-07
申请号：US11743781
申请日：2007-05-03
申请人： Jan Henk Kamps , Edward Kung , Jan-Pleun Lens
发明人： Jan Henk Kamps , Edward Kung , Jan-Pleun Lens
IPC分类号： C08G63/02 , C08G63/00
CPC分类号： C08G64/0241 , C08G64/12 , C08G64/1641
摘要： Disclosed herein is a poly(carbonate-co-urea-co-ester) copolymer comprising incorporated urea compound, dihydroxy compound and diacid compound residues. Also disclosed herein is a poly(carbonate-co-urea) copolymer comprising incorporated urea compound and dihydroxy compound residues.
摘要翻译：本文公开了包含掺入的脲化合物，二羟基化合物和二酸化合物残基的聚（碳酸酯 - 共 - 脲 - 共 - 酯）共聚物。本文还公开了包含掺入的脲化合物和二羟基化合物残基的聚（碳酸酯 - 共 - 尿素）共聚物。

45. 发明申请

US20090062438A1 COPOLYESTERCARBONATE COMPOSITIONS 审中-公开
标题翻译：共聚碳酸酯组合物
公开(公告)号：US20090062438A1
公开(公告)日：2009-03-05
申请号：US11847707
申请日：2007-08-30
申请人： Robert Dirk van de Grampel , Theodorus Lambertus Hoeks , Jan-Pleun Lens , Dake Shen , Rajendra Kashinath Singh
发明人： Robert Dirk van de Grampel , Theodorus Lambertus Hoeks , Jan-Pleun Lens , Dake Shen , Rajendra Kashinath Singh
IPC分类号： C08G63/60 , C08K5/09 , C08K5/36
CPC分类号： C08L69/005 , C08K5/42 , C08K5/5393 , C08K5/549 , C08L83/04 , C08L83/00
摘要： A fire-resistant copolyestercarbonate composition is provided comprising a salt-based flame retardant; and a copolyestercarbonate comprising a polycarbonate unit and a polyester unit, the polyester unit derived from the reaction of isophthalic acid, terephthalic acid, and resorcinol, the copolyestercarbonate containing from about 10 mole percent to 99.9 mole percent of the polyester unit. The composition also has improved scratch resistance and may be transparent.
摘要翻译：提供一种耐火共聚酯碳酸酯组合物，其包含盐基阻燃剂; 和包含聚碳酸酯单元和聚酯单元的共聚酯碳酸酯，所述聚酯单元衍生自间苯二甲酸，对苯二甲酸和间苯二酚的反应，所述共聚酯碳酸酯含有约10mol％至99.9mol％的聚酯单元。该组合物还具有改善的耐擦伤性并且可以是透明的。

46. 发明授权

US07425603B2 Polymers, polymer compositions, and method of preparation 有权
标题翻译：聚合物，聚合物组合物和制备方法
公开(公告)号：US07425603B2
公开(公告)日：2008-09-16
申请号：US11288995
申请日：2005-11-29
申请人： T. Tilak Raj , Radhakrishna Arakali Srinivasarao , Jan-Pleun Lens , Subrahmanya Bhat K. , Umesh Hasyagar , Subash Scindia
发明人： T. Tilak Raj , Radhakrishna Arakali Srinivasarao , Jan-Pleun Lens , Subrahmanya Bhat K. , Umesh Hasyagar , Subash Scindia
IPC分类号： C08G64/00
CPC分类号： C08G63/64 , C08G59/26 , C08G63/6856 , C08G64/12
摘要： A polymer comprising structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; wherein each occurrence of “n”, “m”, and “p” independently has a value of 0, 1, 2, 3, or 4; and wherein the polymer is substantially linear.
摘要翻译：包含衍生自式（I）的多环二羟基化合物（其中R 1，R 2和R 3）的结构单元的聚合物各自独立地选自氰基官能团，卤素，具有1至10个碳的脂族官能团，具有3至10个碳的脂环族官能团和具有6至10个碳的芳族官能团; 其中每次出现的“n”，“m”和“p”独立地具有0,1,2,3或4的值; 并且其中所述聚合物基本上是线性的。

47. 发明申请

US20080081884A1 POLYCARBONATE-POLYSILOXANE COPOLYMER COMPOSITIONS AND ARTICLES FORMED THEREFROM 有权
标题翻译：聚碳酸酯 - 聚硅氧烷共聚物组合物及其形成的制品
公开(公告)号：US20080081884A1
公开(公告)日：2008-04-03
申请号：US11537056
申请日：2006-09-29
申请人： Katherine Glasgow , Jan-Pleun Lens , Brian Mullen , Vandita Pai-Paranjape
发明人： Katherine Glasgow , Jan-Pleun Lens , Brian Mullen , Vandita Pai-Paranjape
IPC分类号： C08F283/02
CPC分类号： C08G77/448 , C08L83/10
摘要： A thermoplastic composition comprises a copolycarbonate comprising 25 to 100 mole percent of a first carbonate unit derived from a dihydroxy aromatic compound having the formula wherein Ra′ and Rb′ are C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4, and r and s are 1 to 4; and 0 to 75 mole percent of a second carbonate unit, wherein the first carbonate unit and second carbonate unit are not identical; a polysiloxane-polycarbonate copolymer comprising 0.15 to 30 weight percent of a polysiloxane block comprising siloxane units of the formula wherein E is on average of 4 to 60 units, and 70 to 99.85 weight percent of a third carbonate unit, wherein an article having a thickness of 3.2 mm and molded from the thermoplastic composition has a Dynatup total energy of greater than 50 Joules, as measured at a constant speed of 3.3 to 3.6 m/sec at 23° C. according to ASTM D3763-02. A method of making and articles prepared therefrom are also disclosed.
摘要翻译：热塑性组合物包含共聚碳酸酯，其包含25至100摩尔％的衍生自具有下式的二羟基芳族化合物的第一碳酸酯单元，其中R a a'和R b'均为C C 1-12烷基，T是C 5-16亚烷基，C 5-16亚烷基，C 1-5 亚烷基，C 1-5亚烷基，C 6-13亚芳基，C 7-12芳基亚烷基，C 1 -C 6亚烷基， C 7-12芳基亚烷基，C 7-12烷基亚芳基或C 7-12亚芳基烷基，r和s各自独立地为1至4个，r和s为1〜4; 和0至75摩尔％的第二碳酸酯单元，其中所述第一碳酸酯单元和第二碳酸酯单元不相同; 聚硅氧烷 - 聚碳酸酯共聚物，其包含0.15至30重量％的包含下式的硅氧烷单元的聚硅氧烷嵌段，其中E平均为4至60个单元，和70至99.85重量％的第三个碳酸酯单元，其中具有厚度根据ASTM D3763-02，由热塑性组合物模塑的Dynatup总能量大于50焦耳，其在23℃下以3.3至3.6m /秒的恒定速度测量。还公开了一种制备方法和由其制备的制品。

48. 发明授权

US07321069B2 Process for preparing bisphenols 有权
标题翻译：制备双酚的方法
公开(公告)号：US07321069B2
公开(公告)日：2008-01-22
申请号：US11015183
申请日：2004-12-17
申请人： Gurram Kishan , Ramesh Krishnamurti , Kapila Debjani , Arakali Radhakrishna Srinivasarao , Jan-Pleun Lens
发明人： Gurram Kishan , Ramesh Krishnamurti , Kapila Debjani , Arakali Radhakrishna Srinivasarao , Jan-Pleun Lens
IPC分类号： C07C39/12
CPC分类号： C07C37/20 , B01J21/066 , B01J21/08 , B01J27/188 , C07C37/14 , C07C2601/14 , C07C39/17
摘要： A process for preparing aromatic bisphenols, wherein the method comprises reacting an aromatic hydroxy compound with an alkylating agent having a functionality of two in the presence of a catalyst system. The catalyst system used for the process is selected from the group consisting of a heteropolyacid compound, a clay, a functionalized metal oxide catalyst and combinations of the foregoing.
摘要翻译：一种制备芳族双酚的方法，其中所述方法包括在催化剂体系的存在下使芳族羟基化合物与官能度为2的烷基化剂反应。用于该方法的催化剂体系选自杂多酸化合物，粘土，官能化金属氧化物催化剂和上述组合。

49. 发明申请

US20070123713A1 Polycyclic dihydroxy compound and methods for preparation 审中-公开
标题翻译：多环二羟基化合物及其制备方法
公开(公告)号：US20070123713A1
公开(公告)日：2007-05-31
申请号：US11289070
申请日：2005-11-29
申请人： T. Raj , A.S. Radhakrishna , Jan-Pleun Lens , Subrahmanya K. , Umesh Hasyagar
发明人： T. Raj , A.S. Radhakrishna , Jan-Pleun Lens , Subrahmanya K. , Umesh Hasyagar
IPC分类号： C07D209/48
CPC分类号： C07D493/04 , C07D209/48
摘要： A process of forming a polycyclic dihydroxy compound is described. The polycyclic dihydroxy compound has Formula (I) wherein R1, R2 and R3 are independently at each occurrence selected from the group consisting of a cyano functionality, a halogen, an aliphatic functionality having 1 to 10 carbons, a cycloaliphatic functionality having 3 to 10 carbons, and an aromatic functionality having 6 to 10 carbons; and wherein each occurrence of “n”, “m”, and “p” independently has a value of 0, 1, 2, 3, or 4. Also described are polycyclic dihydroxy compounds of Formula (I) in which the phthalimide group is meta to the triaryl-substituted carbon.
摘要翻译：描述了形成多环二羟基化合物的方法。多环二羟基化合物具有式（I），其中R 1，R 2和R 3各自独立地选自以下各项：氰基官能团，卤素，具有1至10个碳的脂族官能团，具有3至10个碳的脂环族官能团和具有6至10个碳的芳族官能团; 并且其中每次出现的“n”，“m”和“p”独立地具有0,1,2,3或4的值。还描述了式（I）的多环二羟基化合物，其中邻苯二甲酰亚胺基是对于三芳基取代的碳。

50. 发明授权

US07208620B1 Polycyclic dihydroxy compounds and methods for preparation 有权
标题翻译：多环二羟基化合物及其制备方法
公开(公告)号：US07208620B1
公开(公告)日：2007-04-24
申请号：US11261720
申请日：2005-10-28
申请人： Jan Henk Kamps , Jan-Pleun Lens , A. S. Radhakrishna , T. Tilak Raj , Ravindra Vikram Singh
发明人： Jan Henk Kamps , Jan-Pleun Lens , A. S. Radhakrishna , T. Tilak Raj , Ravindra Vikram Singh
IPC分类号： C07C69/76 , C07C67/00
CPC分类号： C07C45/69 , C07C45/74 , C07C67/343 , C07C67/347 , C07C69/757 , C07C2601/14 , C07C49/223
摘要： A dihydroxy aromatic compound having a Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4.
摘要翻译：具有式（I）的二羟基芳族化合物，其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团，具有2个具有4至10个碳的脂环族酯官能团和具有4至10个碳原子的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团至10个碳; 并且每次出现时，每个R 3和R 4可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团具有3至10个碳，“n”是0至4的整数，“m”是0至4的整数。

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