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    • 43. 发明授权
    • Negative-acting chemically amplified photoresist composition
    • 负性化学放大光致抗蚀剂组合物
    • US06576394B1
    • 2003-06-10
    • US09596098
    • 2000-06-16
    • Pingyong XuPing-Hung LuRalph R. Dammel
    • Pingyong XuPing-Hung LuRalph R. Dammel
    • G03C1492
    • G03F7/038G03F7/0045Y10S430/106Y10S430/122
    • A chemically-amplified, negative-acting, radiation-sensitive photoresist composition that is developable in an alkaline medium, the photoresist comprising: a) a phenolic film-forming polymeric binder resin having ring bonded hydroxyl groups; b) a photoacid generator that forms an acid upon exposure to radiation, in an amount sufficient to initiate crosslinking of the film-forming binder resin; c) a crosslinking agent that forms a carbonium ion upon exposure to the acid from step b) generated by exposure to radiation, and which comprises an etherified aminoplast polymer or oligomer; d) a second crosslinking agent that forms a carbonium ion upon exposure to the acid from step b) generated by exposure to radiation, and which comprises either 1) a hydroxy substituted- or 2) a hydroxy C1-C4 alkyl substituted-C1-C12 alkyl phenol, wherein the total amount of the crosslinking agents from steps c) and d) is an effective crosslinking amount; and e) a photoresist solvent, and a process for producing a microelectronic device utilizing such a photoresist composition.
    • 一种可在碱性介质中显影的化学放大的,负性的,辐射敏感的光致抗蚀剂组合物,光致抗蚀剂包括:a)具有环键羟基的酚醛膜形成聚合物粘合剂树脂; b)形成 暴露于辐射后的酸,其量足以引发成膜粘合剂树脂的交联; c)在暴露于通过暴露于辐射产生的步骤b)的酸暴露于酸后形成碳鎓离子的交联剂,其包含 醚化的氨基塑料聚合物或低聚物; d)第二交联剂,其暴露于通过暴露于辐射产生的步骤b)的酸形成碳鎓离子,并且其包括1)羟基取代的或2)羟基C 1 -C 4 烷基取代的C 1 -C 12烷基苯酚,其中来自步骤c)和d)的交联剂的总量是有效的交联量; ande)光致抗蚀剂溶剂,以及利用这种光致抗蚀剂组合物制造微电子器件的方法。
    • 45. 发明授权
    • Light-absorbing antireflective layers with improved performance due to refractive index optimization
    • 由于折射率优化而具有改进性能的吸光抗反射层
    • US06274295B1
    • 2001-08-14
    • US09264616
    • 1999-03-08
    • Ralph R. DammelRobert A. Norwood
    • Ralph R. DammelRobert A. Norwood
    • G03F700
    • G03F7/091Y10S430/151
    • The invention consists of a light absorbing top antireflective layer that reduces the swing curve amplitude for photoresist materials used in the semiconductor industry. The coating may be water based but is not necessarily so. The advantage of a water-based coating is its ease of use, since it can be applied without intermixing to the softbaked photoresist, and is removed in the development step, so that process complexity is only minimally increased. One problem that has been associated with the existing non-absorbing antireflective coatings is that the optimum swing curve reduction is only achieved at a very low refractive index. The advantages of a dyed coating are a) that the refractive index of the top coat can additionally be lowered by making use of anomalous dispersion effects if the dye is chosen judiciously, and b) that it is possible to achieve the optimum swing curve reduction at a higher refractive index of the top coat. By a combination of these two effects, the present invention demonstrates a reduction of the swing curve close to the theoretical minimum value, which constitutes a substantial improvement over existing antireflective topcoats.
    • 本发明包括一种光吸收顶部抗反射层,其减少半导体工业中使用的光致抗蚀剂材料的摆动曲线幅度。 涂层可以是水性的,但不一定如此。 水性涂​​料的优点是其易于使用,因为它可以在不与软烘烤的光致抗蚀剂混合的情况下进行应用,并且在显影步骤中被去除,使得仅仅最小程度地提高了工艺复杂性。 与现有的非吸收性抗反射涂层相关联的一个问题是仅在非常低的折射率下实现最佳摆动曲线减小。 染色涂层的优点是a)如果染色被明智地选择,则可以通过利用异常色散效应来额外降低顶涂层的折射率,以及b)可以实现最佳的摆动曲线减小 顶部涂层的折射率较高。 通过这两种效果的组合,本发明证明了接近理论最小值的摆动曲线的减小,这相对于现有的抗反射面漆构成了实质的改进。