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41. 发明申请

US20050119445A1 Polyamino acids and method for producing the same 审中-公开
标题翻译：聚氨基酸及其制备方法
公开(公告)号：US20050119445A1
公开(公告)日：2005-06-02
申请号：US10504902
申请日：2003-02-14
申请人： Thomas Geller , Arne Gerlach , Anton Vidal-Ferran , Hans-Christian Militzer , Reinhard Langer
发明人： Thomas Geller , Arne Gerlach , Anton Vidal-Ferran , Hans-Christian Militzer , Reinhard Langer
IPC分类号： C07D301/12 , C08G69/10 , C08G69/08
CPC分类号： C07D301/12 , C08G69/10
摘要： The invention relates to polyamino acids, to a method for producing the same and to their use as catalysts for enantioselective epoxidation of α,β-unsaturated enons and α,β-unsaturated sulfones.
摘要翻译：本发明涉及聚氨基酸，其制备方法及其作为α，β-不饱和烯酮和α，β-不饱和砜的对映选择性环氧化催化剂的用途。

42. 发明授权

US06429344B1 Process for the preparation of d,I-menthol 有权
标题翻译：制备d，l-薄荷醇的方法
公开(公告)号：US06429344B1
公开(公告)日：2002-08-06
申请号：US09439770
申请日：1999-11-15
申请人： Reinhard Langer , Gerd-Michael Petruck
发明人： Reinhard Langer , Gerd-Michael Petruck
IPC分类号： C07C2700
CPC分类号： C07C29/20 , C07B2200/07 , C07C2601/14 , C07C35/12
摘要： The invention relates to a process for the preparation of d,l-menthol by catalytic hydrogenation of compounds which have the carbon skeleton of menthane containing at least one double bond and are 3-substituted by oxygen and/or of menthone or isomenthone or mixtures of such compounds using hydrogen at temperatures of 100 to 200° C. and at hydrogen partial pressures between 2 and 50 bar and/or by rearrangement of menthol stereoisomers in the presence of hydrogen at temperatures of 0 to 140° C. and at hydrogen partial pressures between 0.1 and 20 bar in the presence of noble-metal-containing catalysts.
摘要翻译：本发明涉及一种通过催化氢化制备d，l-薄荷醇的方法，所述化合物具有含有至少一个双键的薄荷烷的碳骨架，并被氧和/或薄荷酮或异酮酮或3- 这种化合物在100至200℃的温度和2至50巴的氢分压下和/或通过在0〜140℃的温度和氢气分压下在氢气存在下重新配置薄荷醇立体异构体，在含贵金属的催化剂存在下，介于0.1和20巴之间。

43. 发明授权

US06242649B1 Continuous method for producing aromatic amines 有权
标题翻译：连续生产芳香胺的方法
公开(公告)号：US06242649B1
公开(公告)日：2001-06-05
申请号：US09529143
申请日：2000-04-07
申请人： Heiko Beckhaus , Reinhard Langer
发明人： Heiko Beckhaus , Reinhard Langer
IPC分类号： C07C20900
CPC分类号： C07C209/36 , C07C211/50
摘要： A continuous process for the preparation of aromatic di- and/or polyamines by catalytic hydrogenation of the corresponding aromatic di- and/or polynitro compounds with hydrogen, characterized in that, in a reactor with a catalytic fixed bed or trickle bed at a pressure between 5 and 100 bar and a reaction temperature of from 100 to 220° C. a) the aromatic di- and/or polynitro compounds, optionally in the presence of a solvent, are introduced into a product stream comprising essentially recycled hydrogenated product, water and hydrogen, and b) a part of the product stream is removed continuously from the reactor system.
摘要翻译：用于通过相应的芳族二 - 和/或多硝基化合物与氢气的催化氢化制备芳族二 - 和/或多胺的连续方法，其特征在于在具有催化固定床或滴流床的反应器中， 5和100巴，反应温度为100至220°Ca.）芳族二 - 和/或多硝基化合物（任选在溶剂存在下）引入包含基本上循环的氢化产物，水和氢的产物流中，和b）产物流的一部分从反应器系统连续地除去。

44. 发明授权

US08203006B2 Process for producing vinylene carbonate 失效
标题翻译：碳酸亚乙烯酯的制备方法
公开(公告)号：US08203006B2
公开(公告)日：2012-06-19
申请号：US11920040
申请日：2006-05-04
申请人： Reinhard Langer , Anke Beckmann , Andreas Schulze Tilling , Paul Wagner , Leslaw Mleczko , Sigurd Buchholz
发明人： Reinhard Langer , Anke Beckmann , Andreas Schulze Tilling , Paul Wagner , Leslaw Mleczko , Sigurd Buchholz
IPC分类号： C07D317/40
CPC分类号： C07D317/40
摘要： The present invention relates to the industrial production of vinylene carbonate (VC) by eliminating hydrogen chloride from chloroethylene glycol carbonate (CGC) or solid catalysts in the gas phase, the reaction being carried out over a catalyst bed agitated by thorough mixing.
摘要翻译：本发明涉及通过在气相中从氯乙烯二醇碳酸酯（CGC）或固体催化剂中除去氯化氢来进行工业生产碳酸亚乙烯酯（VC），该反应在通过充分混合搅拌的催化剂床上进行。

45. 发明授权

US07094923B2 Method for producing substituted nitro benzoic acids by oxidation of corresponding nitro toluenes, nitro benzyl alcohols, esters and/or ethers 失效
标题翻译：通过氧化相应的硝基甲苯，硝基苄醇，酯和/或醚来制备取代的硝基苯甲酸的方法
公开(公告)号：US07094923B2
公开(公告)日：2006-08-22
申请号：US11083746
申请日：2005-03-17
申请人： Reinhard Langer , Lars Rodefeld , Karl Heinz Neumann
发明人： Reinhard Langer , Lars Rodefeld , Karl Heinz Neumann
IPC分类号： C07C309/00 , C07C51/16 , C07C51/255 , C07C51/23 , C07C51/15
CPC分类号： C07C303/22 , C07C201/12 , C07C309/58 , C07C205/57 , C07C205/58 , C07C205/61
摘要： The present invention relates to the preparation of nitrobenzoic acids by oxidizing particular nitrotoluenes, nitrobenzyl alcohols, esters and/or ethers in the presence of nitric acid at elevated temperature and elevated pressure. It has been found that the particular nitrotoluenes, nitrobenzyl alcohols, esters and/or ethers may be oxidized particularly reliably and in high yields using nitric acid to the benzoic acid derivatives when they are metered into the nitric acid.
摘要翻译：本发明涉及通过在高温和高压下在硝酸存在下氧化特定的硝基甲苯，硝基苄醇，酯和/或醚来制备硝基苯甲酸。已经发现，当特定的硝基甲苯，硝基苄基醇，酯和/或醚可以特别可靠地被氧化并且当它们被计量到硝酸中时，使用硝酸对苯甲酸衍生物是高产率的。

46. 发明申请

US20060149083A1 Method for the decarboxylation of dicarboxylic acids 失效
标题翻译：二羧酸脱羧的方法
公开(公告)号：US20060149083A1
公开(公告)日：2006-07-06
申请号：US10538995
申请日：2003-12-04
申请人： Sigurd Buchholz , Alexander Klausener , Reinhard Langer , Leslaw Mleczko , Gunter Leverkusen
发明人： Sigurd Buchholz , Alexander Klausener , Reinhard Langer , Leslaw Mleczko , Gunter Leverkusen
IPC分类号： C07D495/02
CPC分类号： C07D495/04 , C07D333/38 , Y02P20/582
摘要： The invention relates to a method for the thermal decarboxylation of dicarboxylic acids, in particular to 3,4-ethylene dioxythiophene-2,5-dicarboxylic acid as an educt. According to said method the educt is used in solid form and/or the reaction is carried out in the presence of a plurality of fluidised bed bodies. No solvents are used in the reaction and the decarboxylation product that is formed during the reaction is carried away from the reaction zone in gaseous form.
摘要翻译：本发明涉及一种二羧酸热脱羧的方法，特别涉及作为溶出物的3,4-亚乙基二氧噻吩-2,5-二羧酸的热脱羧方法。根据所述方法，溶出物以固体形式使用和/或反应在多个流化床体的存在下进行。在反应中没有使用溶剂，并且在反应期间形成的脱羧产物以气态形式从反应区带走。

47. 发明授权

US06900349B2 Method for producing substituted nitro benzoic acids by oxidation of corresponding nitro toluenes, nitrol benzyl alcohols, esters and/or ethers 失效
标题翻译：通过氧化相应的硝基甲苯，硝基苄醇，酯和/或醚来制备取代的硝基苯甲酸的方法
公开(公告)号：US06900349B2
公开(公告)日：2005-05-31
申请号：US10257062
申请日：2001-03-30
申请人： Reinhard Langer , Lars Rodefeld , Karl Heinz Neumann
发明人： Reinhard Langer , Lars Rodefeld , Karl Heinz Neumann
IPC分类号： C07C201/12 , C07C205/57 , C07C205/58 , C07C303/22 , C07C309/58 , C07C309/00 , C07C51/15 , C07C51/16 , C07C51/23 , C07C51/255
CPC分类号： C07C303/22 , C07C201/12 , C07C309/58 , C07C205/57 , C07C205/58 , C07C205/61
摘要： The present invention relates to the preparation of nitrobenzoic acids by oxidizing particular nitrotoluenes, nitrobenzyl alcohols, esters and/or ethers in the presence of nitric acid at elevated temperature and elevated pressure. It has been found that the particular nitrotoluenes, nitrobenzyl alcohols, esters and/or ethers may be oxidized particularly reliably and in high yields using nitric acid to the benzoic acid derivatives when they are metered into the nitric acid.
摘要翻译：本发明涉及通过在高温和高压下在硝酸存在下氧化特定的硝基甲苯，硝基苄醇，酯和/或醚来制备硝基苯甲酸。已经发现，当特定的硝基甲苯，硝基苄基醇，酯和/或醚可以特别可靠地被氧化并且当它们被计量到硝酸中时，使用硝酸对苯甲酸衍生物是高产率的。

48. 发明授权

US06710217B1 Method for producing 4-chlorobiphenyl and 4-chlorobiphenyl-specific specifications 失效
标题翻译：制备4-氯联苯和4-氯联苯的具体规格的方法
公开(公告)号：US06710217B1
公开(公告)日：2004-03-23
申请号：US10009536
申请日：2001-11-13
申请人： Reinhard Langer , Alexander Klausener , Paul Wagner , Lothar Puppe
发明人： Reinhard Langer , Alexander Klausener , Paul Wagner , Lothar Puppe
IPC分类号： C07C1700
CPC分类号： C07C25/18 , B01J27/10 , B01J29/60 , C07C17/12 , C07C17/383
摘要： The invention relates to a process for preparing 4-chlorobiphenyl by (a) reacting biphenyl and chlorine in the presence of one or more ring-chlorination catalysts, and (b) subjecting the reaction mixture obtained in step (a) to fractional distillation to obtain 4-chlorobiphenyl.
摘要翻译：本发明涉及一种通过（a）在一种或多种环氯化催化剂存在下使联苯和氯反应制备4-氯联苯的方法，和（b）将步骤（a）中获得的反应混合物进行分馏，得到 4-氯联苯。

49. 发明授权

US6077975A Process for preparing dicycloaliphatic amines 失效
标题翻译：二环脂族胺的制备方法
公开(公告)号：US6077975A
公开(公告)日：2000-06-20
申请号：US407592
申请日：1999-09-28
申请人： Reinhard Langer , Gerd-Michael Petruck
发明人： Reinhard Langer , Gerd-Michael Petruck
IPC分类号： B01J27/188 , B01J23/652 , B01J23/656 , C07B61/00 , C07C209/60 , C07C209/72 , C07C211/35 , C07C209/00
CPC分类号： C07C209/72 , B01J23/652 , B01J23/6562 , B01J23/6567
摘要： A low-pressure process for the hydrogenation of aromatic amines to give the corresponding symmetrical dicycloaliphatic amines in the presence of rhodium catalysts which are unmodified or modified by Ir, Ru, Os, Pd and/or Pt or mixtures of these metals, on supports modified by oxides of Cr, Mo, W, Mn and/or Re or mixtures of these oxides.
摘要翻译：在铑催化剂存在下，通过Ir，Ru，Os，Pd和/或Pt或这些金属的混合物将这些金属未改性或修饰的铑催化剂存在下，芳族胺氢化得到相应的对称二环脂族胺的低压法， Cr，Mo，W，Mn和/或Re的氧化物或这些氧化物的混合物。

50. 发明授权

US6054619A Process for preparing cycloaliphatic amines 失效
标题翻译：脂环族胺的制备方法
公开(公告)号：US6054619A
公开(公告)日：2000-04-25
申请号：US332327
申请日：1999-06-14
申请人： Reinhard Langer , Gerd-Michael Petruck
发明人： Reinhard Langer , Gerd-Michael Petruck
IPC分类号： B01J23/46 , B01J23/652 , B01J23/656 , B01J27/055 , C07C209/72 , C07C211/35 , C07C209/00 , B01J23/00
CPC分类号： C07C209/72 , B01J23/464 , B01J23/652 , B01J23/6522 , B01J23/656 , B01J23/6562 , B01J27/055
摘要： The present invention relates to a low-pressure process for hydrogenating aromatic amines to give the corresponding cycloaliphatic amines in the presence of rhodium catalysts.
摘要翻译：本发明涉及在铑催化剂存在下使芳族胺氢化得到相应的脂环族胺的低压方法。

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