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    • 47. 发明授权
    • Process for the production of .beta.-lithium aluminate and needle-shaped
product
    • 生产{62-铝酸锂和针状产品的方法
    • US4164557A
    • 1979-08-14
    • US886365
    • 1978-03-14
    • Martin FeldmannEdgar KobersteinKlaus Seibold
    • Martin FeldmannEdgar KobersteinKlaus Seibold
    • C01F7/04H01M2/16H01M8/02C01F7/02
    • H01M8/0295C01F7/043H01M2/1646Y02P70/56
    • A process for the production of .beta.-lithium aluminate LiAlO.sub.2, is disclosed wherein a lithium hydroxide aluminate of the formula: Li.sub.2 O . Al.sub.2 O.sub.3 . nH.sub.2 O is precipitated from aqueous solutions which contain the lithium ions and aluminum in ionogenic or elementary form at a pH value above 7. The concentration of the two metal components is at least 0.1, at most 6 g-atoms per liter, preferably 2 to 5 g-atoms per liter. The precipitation product is washed and dried and then is converted by annealing into .beta.-lithium aluminate, in the temperature range between 200.degree. C. and 800.degree. C., preferably 400.degree. C.-650.degree. C., and especially 450.degree. C.-550.degree. C. The .beta.-LiAlO.sub.2 obtained thereby has a lamellae-shaped or fine crystalline form which is converted into a needle-shaped, crystalline lithium aluminate, is obtained by the process of the invention and is suitable for the construction of electrolyte matrices.
    • 公开了一种制备β-锂铝酸锂LiAlO 2的方法,其中式为Li 2 O的氢氧化锂铝酸盐。 Al2O3。 nH 2 O在含有高于7的pH值的离子发生或元素形式的锂离子和铝的水溶液中沉淀。两种金属组分的浓度为至少0.1,至多6g-原子/升,优选2至5 每升原子。 将沉淀产物洗涤和干燥,然后通过退火转化成β-铝酸锂,温度在200℃至800℃,优选400℃-650℃,特别是450℃ 。-550℃。由此获得的β-LiAlO 2具有通过本发明的方法获得并转化成针状结晶的铝酸锂的薄片状或细晶体形式,并且适用于构建电解质 矩阵。
    • 50. 发明授权
    • Method of working up the solution from the enzymatic resolution of a
racemate of an N-acetyl-DL-amino-carboxylic acid
    • 从N-乙酰基-DL-氨基 - 羧酸的外消旋体的酶拆分处理溶液的方法
    • US4909916A
    • 1990-03-20
    • US285366
    • 1988-12-15
    • Edgar KobersteinThomas Lehmann
    • Edgar KobersteinThomas Lehmann
    • B01D61/44B01D61/54C12P13/04C12P41/00
    • C12P41/007B01D61/445C12P13/04
    • There is described the working up of a solution by electrodialysis originally prepared by the enzymatic resolution of an N-acetyl-DL-aminocarboxylic acid. The electrodialysis device used consists of a plurality of three-chamber packets, each of which comprises a feed and diluent chamber (1), a (basic) concentrate chamber (2) located on its cathode side and an (acidic) concentrate chamber (3) located on its anode side, whereby each three-chamber packet is separated from each of the two adjacent ones by a device (4) in which water is decomposed into OH.sup.- ions and H.sup.+ ions. The added resolution solution is separated by this device into three solutions, the first of which contains the L-amino acid, the second of which contains the cations present in the resolution solution as hydroxides and the third of which contains the anions present in the resolution solution as free acids.
    • 描述了最初通过N-乙酰基-DL-氨基羧酸的酶拆分制备的电渗析来处理溶液。 所使用的电渗析装置包括多个三室包装,每个包装包括进料和稀释室(1),位于其阴极侧的(碱性)浓缩室(2)和(酸性)浓缩室(3) ),其中通过其中水被分解成OH-离子和H +离子的装置(4)将每个三室分组与两个相邻的分组分离。 加入的分辨率溶液由该装置分离成三种溶液,其中第一种溶液含有L-氨基酸,其中第二种溶液含有分解溶液中存在的阳离子为氢氧化物,其中第三种含有决议中存在的阴离子 溶液作为游离酸。