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41. 发明申请

US20050247624A1 Method for the recycling of a lewis acid 失效
标题翻译：路易斯酸回收方法
公开(公告)号：US20050247624A1
公开(公告)日：2005-11-10
申请号：US10520007
申请日：2003-07-04
申请人： Tim Jungkamp , Jens Scheidel , Hermann Luyken , Michael Bartsch , Robert Baumann , Gerd Haderlein
发明人： Tim Jungkamp , Jens Scheidel , Hermann Luyken , Michael Bartsch , Robert Baumann , Gerd Haderlein
IPC分类号： B01J31/18 , B01J27/32 , B01J31/40 , B01J38/00 , C07B61/00 , C07C253/10 , C07C255/04 , C07C255/07 , B01D11/00
CPC分类号： B01J31/24 , B01J27/32 , B01J31/1845 , B01J31/4015 , B01J31/403 , B01J2231/343 , C07C253/10 , Y02P20/584 , C07C255/07
摘要： A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions, to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile
摘要翻译：从在不饱和化合物的氢氰化中获得的反应混合物（I）中回收路易斯酸的方法，该反应混合物在一定压力和温度条件下，在与催化剂体系包含路易斯酸和络合物。该方法包括：a）从混合物（I）中除去配合物，得到混合物（II），b）在混合物（II）中加入水并将混合物（II）置于压力和温度条件下以提供相（III）和相（Ⅳ），c）加入一种不与水形成共沸物的液体稀释剂（Ⅴ），其某些压力条件下的沸点高于水，或c2）与水形成共沸混合物（III），d）在步骤c1）或c2）所述的压力条件下使相（III）和液体稀释剂（V）的混合物进行蒸馏，和e）使混合物（VII）对烯属不饱和化合物进行氢化，得到腈

42. 发明授权

US08679436B2 Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts 失效
标题翻译：从用于生产羟胺或羟铵盐的系统处理废气的方法
公开(公告)号：US08679436B2
公开(公告)日：2014-03-25
申请号：US13876496
申请日：2011-09-27
申请人： Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
发明人： Arnd Garsuch , Alexander Panchenko , Sigmar Bräuninger , Jens Scheidel , Alfred Thome
IPC分类号： B01D53/34 , B01D53/46 , C07C215/00
CPC分类号： B01D53/46 , B01D53/229 , B01D53/326 , B01D69/148 , B01D71/024 , B01D71/32 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2257/108 , B01D2313/345 , C01B3/501 , C01B3/503 , C01B21/1418 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , H01M8/086 , H01M8/1023 , H01M8/1025 , H01M8/106 , H01M8/1246 , Y02E60/525 , Y02P70/56
摘要： Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen, the exhaust gas containing nitrogen monoxide, hydrogen, dinitrogen monoxide, nitrogen and ammonia. At least some of the hydrogen present in the exhaust gas is separated off from the exhaust gas by means of a gas-tight membrane-electrode assembly which comprises at least one selectively proton-conducting membrane, a retentate side, a permeate side, and, on each side of the membrane, at least one electrode catalyst, wherein, on the retentate side of the membrane, at least some of the hydrogen is oxidized to protons at the anode catalyst and the protons, after crossing the membrane, are, on the permeate side, at the cathode catalyst according to (I) reduced to hydrogen and/or (II) reacted with oxygen to form water, the oxygen originating from an oxygen-containing stream which is contacted with the permeate side.
摘要翻译：通过用氢气还原一氧化氮，含有一氧化氮，氢气，一氧化二氮，氮气和氨的废气来处理来自用于生产羟胺或羟铵盐的系统的排气的方法。存在于废气中的至少一部分氢气通过气密膜电极组件与废气分离，所述气 - 气膜 - 电极组件包括至少一个选择性质子传导膜，滞留物侧，渗透侧，在膜的每一侧上，至少一个电极催化剂，其中在膜的截留侧上，至少一些氢被氧化成在阳极催化剂和质子之间的质子，在穿过膜之后，在渗透侧，根据（I）的阴极催化剂还原为氢和/或（II）与氧反应形成水，所述氧来源于与渗透侧接触的含氧流。

43. 发明授权

US08278474B2 Method for the separation of pentenenitrile isomers 有权
标题翻译：戊烯腈异构体分离方法
公开(公告)号：US08278474B2
公开(公告)日：2012-10-02
申请号：US13047212
申请日：2011-03-14
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
IPC分类号： C07C253/34
CPC分类号： C07C253/34 , C07C255/07
摘要： A process is described for separating mixtures of isomeric pentenenitriles, in which at least one isomer is removed from the mixture, wherein the separation of the substance mixtures of isomeric pentenenitriles is effected distillatively under reduced pressure.
摘要翻译：描述了用于分离异构戊烯腈混合物的方法，其中从混合物中除去至少一种异构体，其中异构戊烯腈的物质混合物的分离在减压下进行蒸馏。

44. 发明授权

US08058466B2 Method for producing 3-pentenenitrile by means of the hydrocyanation of 1,3-butadiene 有权
标题翻译：通过1,3-丁二烯氢氰化生产3-戊烯腈的方法
公开(公告)号：US08058466B2
公开(公告)日：2011-11-15
申请号：US12376731
申请日：2007-08-01
申请人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Hermann Luyken , Peter Pfab , Jens Scheidel , Andrea Haunert , Thomas Genger
发明人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Hermann Luyken , Peter Pfab , Jens Scheidel , Andrea Haunert , Thomas Genger
IPC分类号： C07C253/10
CPC分类号： C07C253/10 , C07C255/07
摘要： An process for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene, in which the process yield with regard to recycled 1,3-butadiene is maximized.
摘要翻译：通过氢化1,3-丁二烯制备3-戊烯腈的方法，其中关于回收的1,3-丁二烯的方法产率最大化。

45. 发明授权

US07705171B2 Process for producing nickel(0)-phosphorus ligand complexes 有权
标题翻译：制备镍（0） - 磷配体络合物的方法
公开(公告)号：US07705171B2
公开(公告)日：2010-04-27
申请号：US12279795
申请日：2007-02-13
申请人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Peter Pfab , Hermann Luyken , Jens Scheidel
发明人： Gerd Haderlein , Tobias Aechtner , Andreas Leitner , Peter Pfab , Hermann Luyken , Jens Scheidel
IPC分类号： C07F15/04
CPC分类号： B01J31/1845 , B01J31/24 , B01J2231/32 , B01J2531/847
摘要： A process for preparing nickel(0)-phosphorus ligand complexes comprising at least one nickel(0) central atom and at least one phosphorus ligand by reacting a nickel(II) compound with a reducing agent in the presence of the ligand to give a reaction mixture, wherein a) the molar reducing agent:nickel(II) compound ratio in the reaction is from 1:1 to 1000:1, calculated as the molar ratio of the redox equivalents, b) the molar phosphorus ligand:nickel(II) compound ratio in the reaction is not more than 30:1, calculated as the molar P atoms:Ni atoms ratio, c) the nickel(0) content in the resulting reaction mixture is not more than 1.3% by weight and d) the resulting reaction mixture is extracted by adding at least one dinitrile and at least one hydrocarbon to form at least two immiscible phases.
摘要翻译：一种通过在配体存在下使镍（II）化合物与还原剂反应而制备包含至少一个镍（O）中心原子和至少一个磷配体的镍（0） - 磷配体络合物的方法，得到反应混合物，其中a）摩尔还原剂：反应中的镍（II）化合物比例为1:1至1000:1，以氧化还原当量的摩尔比计算，b）磷配体：镍（II）反应中的化合物比例不超过30:1，以P原子摩尔数计算：Ni原子比，c）所得反应混合物中的镍（0）含量不超过1.3重量％，d）所得的通过加入至少一种二腈和至少一种烃以形成至少两个不混溶的相来萃取反应混合物。

46. 发明申请

US20090281356A1 METHOD FOR PRODUCING ORGANIC PHOSPHOROUS COMPOUNDS CONTAINING HALOGENE 有权
标题翻译：用于生产含有卤素的有机磷化合物的方法
公开(公告)号：US20090281356A1
公开(公告)日：2009-11-12
申请号：US12373336
申请日：2007-07-03
申请人： Robert Baumann , Tobias Aechtner , Wolfgang Siegel , Hermann Luyken , Peter Pfab , Jens Scheidel , Andreas Leitner , Andreas Glass
发明人： Robert Baumann , Tobias Aechtner , Wolfgang Siegel , Hermann Luyken , Peter Pfab , Jens Scheidel , Andreas Leitner , Andreas Glass
IPC分类号： C07F9/48
CPC分类号： C07F9/4891 , C07F9/4875
摘要： Method of producing compounds of the general formula XPR2(OR1) I a where X is chlorine, bromine or iodine and R1 is an organic radical, by reacting compounds of the general formula X2PR2 II, in which X has the meaning given above and R2 is an organic radical, with compounds of the general formula R1OH III, in which R1 has the meaning given above, to give a mixture IV, in that a) the postreaction is carried out at a temperature of from 50 to 240° C. and a pressure of from 0.001 to 0.9 bar, b) from the mixture IV the compounds I a are separated off from the compounds PR2(OR1)2 I b and, if appropriate, the compounds II and c) compounds I b and, if appropriate, unreacted compounds II are returned to the synthesis stage.
摘要翻译：通过使通式X 2 PR 2 II的化合物（其中X具有上面给出的含义，R 2）是通过使通式XPR2（OR1）Ia的化合物的制备方法，其中X是氯，溴或碘，R 1是有机基团具有通式R 1 OH III的化合物的化合物，其中R 1具有上述含义，得到混合物IV，其中a）反应在50-240℃的温度和压力为0.001至0.9巴，b）从混合物IV中，化合物I a与化合物PR2（OR1）2 I b分离，如果合适，分离出化合物II和c）化合物I b，如果合适，未反应的化合物II返回到合成阶段。

47. 发明授权

US07541486B2 Method for producing 3-pentenenitrile 有权
标题翻译： 3-戊烯腈的制备方法
公开(公告)号：US07541486B2
公开(公告)日：2009-06-02
申请号：US10586007
申请日：2005-01-27
申请人： Jens Scheidel , Tim Jungkamp , Michael Bartsch , Gerd Haderlein , Robert Baumann , Hermann Luyken
发明人： Jens Scheidel , Tim Jungkamp , Michael Bartsch , Gerd Haderlein , Robert Baumann , Hermann Luyken
IPC分类号： C07C255/00 , C07C253/00
CPC分类号： C07C253/10 , C07C253/34 , C07C255/07
摘要： A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) reacting 1,3-butadiene with hydrogen cyanide over at least one catalyst to obtain a stream 1 which comprises 3-pentenenitrile, 2-methyl-3-butenenitrile, the at least one catalyst and 1,3-butadiene, (b) distilling stream 1 in a column to obtain a high-1,3-butadiene stream 2 as the top product and a low-1,3-butadiene stream 3 as the bottom product which comprises 3-pentenenitrile, the at least one catalyst and 2-methyl-3-butenenitrile, (c) distilling stream 3 in a column to obtain a stream 4 as the top product which comprises 1,3-butadiene, a stream 5 which comprises 3-pentenenitrile and 2-methyl-3-butenenitrile at a side draw of the column, and a stream 6 as the bottom product which comprises the at least one catalyst, (d) distilling stream 5 to obtain a stream 7 as the top product which comprises 2-methyl-3-butenenitrile, and a stream 8 as the bottom product which comprises 3-pentenenitrile.
摘要翻译：描述了一种制备3-戊烯腈的方法，其特征在于以下工艺步骤：（a）使1,3-丁二烯与氰化氢在至少一种催化剂上反应，得到流1，其包含3-戊烯腈，2-甲基-3 丁烯腈，至少一种催化剂和1,3-丁二烯，（b）在塔中蒸馏物流1，得到作为顶部产物的高-1,3-丁二烯流2和低-1,3-丁二烯流 3作为底部产物，其包含3-戊烯腈，至少一种催化剂和2-甲基-3-丁烯腈，（c）在塔中蒸馏流3以获得作为顶部产物的料流4，其包含1,3-丁二烯，在塔的侧馏分中包含3-戊烯腈和2-甲基-3-丁烯腈的料流5和作为底部产物的料流6，其包含至少一种催化剂，（d）蒸馏流5以获得流7作为顶部产物，其包含2-甲基-3-丁烯腈，以及作为底部产物的料流8，其包含3-戊烯腈

48. 发明授权

US07528275B2 Method for the production of adipodinitrile by hydrocyanation of 1,3-butadiene 有权
标题翻译：通过1,3-丁二烯氢氰化生产己二腈的方法
公开(公告)号：US07528275B2
公开(公告)日：2009-05-05
申请号：US10586450
申请日：2005-01-26
申请人： Michael Bartsch , Robert Baumann , Gerd Haderlein , Miguel Angel Flores , Tim Jungkamp , Hermann Luyken , Jens Scheidel , Wolfgang Siegel
发明人： Michael Bartsch , Robert Baumann , Gerd Haderlein , Miguel Angel Flores , Tim Jungkamp , Hermann Luyken , Jens Scheidel , Wolfgang Siegel
IPC分类号： C07C253/08
CPC分类号： C07C253/10 , C07C255/09
摘要： A process is described for preparing adiponitrile by hydrocyanating 1,3-butadiene over a catalyst, by, in a first process step, hydrocyanating 1,3-butadiene to 3-pentenenitrile over at least one nickel(0) catalyst, and, in a second process step, hydrocyanating 3-pentenenitrile to adiponitrile over at least one nickel(0) catalyst with addition of at least one Lewis acid, wherein at least one of the at least one nickel(0) catalysts used in the particular process steps is transferred into the other process step.
摘要翻译：描述了通过在催化剂上氢化1,3-丁二烯来制备己二腈的方法，通过在第一工艺步骤中，在至少一种镍（O）催化剂上氢化1,3-丁二烯至3-戊烯腈，并且在在至少一种镍（O）催化剂中加入至少一种路易斯酸，将3-戊烯腈氢化成己二腈，其中在特定工艺步骤中使用的至少一种镍（0）催化剂中的至少一种被转移进入其他流程步骤。

49. 发明授权

US07504529B2 Method for hydrocyanation 有权
标题翻译：加氢氰化法
公开(公告)号：US07504529B2
公开(公告)日：2009-03-17
申请号：US10587027
申请日：2005-01-26
申请人： Tim Jungkamp , Hans-Martin Polka , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
发明人： Tim Jungkamp , Hans-Martin Polka , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
IPC分类号： C07C253/08
CPC分类号： C07C253/34 , C07C255/07 , C07C255/04
摘要： A process is described for removing hydrogen cyanide from mixtures comprising pentenenitrile, wherein the removal is effected by an azeotropic distillation of hydrogen cyanide with 1,3-butadiene.
摘要翻译：描述了从包含戊烯腈的混合物中除去氰化氢的方法，其中通过氰化氢与1,3-丁二烯的共沸蒸馏来进行除去。

50. 发明申请

US20080242883A1 Method for the Hydrocyanation of Butadiene 有权
标题翻译：丁二烯氢化方法
公开(公告)号：US20080242883A1
公开(公告)日：2008-10-02
申请号：US10587026
申请日：2005-01-27
申请人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
发明人： Tim Jungkamp , Robert Baumann , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel
IPC分类号： C07C255/01
CPC分类号： C07C253/10 , C07C255/07
摘要： A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein the reaction is carried out in a loop reactor having external pumped circulation and jet nozzle for driving the internal circulation.
摘要翻译：描述了一种通过在至少一种催化剂存在下氢氰化1,3-丁二烯来制备3-戊烯腈的方法，其中反应在具有外部泵送循环的环流反应器和用于驱动内部循环的喷嘴中进行。

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