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41. 发明申请

US20060210854A1 Fuel battery 审中-公开
标题翻译：燃油电池
公开(公告)号：US20060210854A1
公开(公告)日：2006-09-21
申请号：US10549066
申请日：2004-03-15
申请人： Noboru Taniguchi
发明人： Noboru Taniguchi
IPC分类号： H01M8/04 , H01M8/12
CPC分类号： H01M8/1253 , H01M8/04022 , H01M8/04097 , H01M8/126 , Y02E60/525 , Y02P70/56
摘要： There is provided a fuel cell having excellent portability and transportability and exhibiting superior power generation efficiency for which it is possible to use a liquid or solid fuel, which has higher energy density than a gaseous fuel. A fuel cell includes an electrolyte (1), an anode (2) and a cathode (3) that are disposed so as to sandwich the electrolyte (1), and further includes a fuel supply portion that supplies a fuel to the anode (2), an oxidant supply portion that supplies an oxidant containing oxygen to the cathode (3), and a cell heating portion that heats the fuel cell, and the electrolyte (1) is made of a solid oxide, and the fuel is a liquid or solid at room temperature and normal pressure.
摘要翻译：提供了具有优异的便携性和运输性并且表现出优异的发电效率的燃料电池，其可以使用具有比气体燃料更高的能量密度的液体或固体燃料。燃料电池包括电解液（1），阳极（2）和阴极（3），其被设置为夹住电解质（1），并且还包括燃料供应部分，其将燃料供应到阳极），向阴极（3）供给含氧氧化剂的氧化剂供给部，以及加热燃料电池的电池加热部，电解质（1）由固体氧化物构成，燃料为液体或在室温和常压下固体。

42. 发明申请

US20060083970A1 Solid oxide fuel cell and method for producing same 审中-公开
标题翻译：固体氧化物燃料电池及其制造方法
公开(公告)号：US20060083970A1
公开(公告)日：2006-04-20
申请号：US10526757
申请日：2004-05-13
申请人： Satoshi Shibutani , Yukihiro Okada , Kohji Yuasa , Noboru Taniguchi , Norihisa Mino , Junji Niikura
发明人： Satoshi Shibutani , Yukihiro Okada , Kohji Yuasa , Noboru Taniguchi , Norihisa Mino , Junji Niikura
IPC分类号： H01M8/10 , H01M4/86 , H01M6/00
CPC分类号： H01M4/8875 , H01M4/8605 , H01M4/8636 , H01M4/8652 , H01M4/8882 , H01M4/90 , H01M4/905 , H01M4/921 , H01M2004/8684 , Y10T29/49115
摘要： The present invention provides a solid oxide fuel cell with superior power generation characteristics even at lower temperatures (for example, in a range of 200° C. to 600° C. and preferably in a range of 400° C. to 600° C.) and a method for manufacturing the same. The solid oxide fuel cell is such that the solid oxide fuel cell includes an anode, a cathode, and a first solid oxide held between the anode and the cathode, the anode includes metal particles (2), an anode catalyst (1), and ion conducting bodies (3), the anode catalyst (1) is attached to the surface of the metal particles (2), and the first solid oxide and the ion conducting bodies (3) have either one of an ionic conductivity that is selected from oxide ionic conductivity and hydrogen ionic conductivity.
摘要翻译：本发明提供即使在较低的温度（例如，在200℃至600℃的范围内，优选在400℃至600℃的范围内也具有优异发电特性的固体氧化物燃料电池。）及其制造方法。所述固体氧化物型燃料电池使得所述固体氧化物型燃料电池包括阳极，阴极和保持在所述阳极和所述阴极之间的第一固体氧化物，所述阳极包括金属粒子（2），阳极催化剂（1）和离子导电体（3），阳极催化剂（1）附着在金属颗粒（2）的表面上，第一固体氧化物和离子传导体（3）具有离子导电体氧化物离子导电性和氢离子电导率。

43. 发明授权

US06238535B1 Hydrocarbon sensor 失效
标题翻译：烃传感器
公开(公告)号：US06238535B1
公开(公告)日：2001-05-29
申请号：US09280522
申请日：1999-04-05
申请人： Noboru Taniguchi , Masuo Takigawa
发明人： Noboru Taniguchi , Masuo Takigawa
IPC分类号： G01N27407
CPC分类号： G01N27/4071 , G01N27/4074 , G01N27/417
摘要： The present invention relates to a limiting-current type hydrocarbon sensor comprising a solid-electrolytic layer made of a Ba—Ce-based oxide, and provides a sensor capable of stably detecting hydrocarbon at high sensitivity, regardless of the concentration of oxygen in an atmosphere. A material mainly containing Al is used for at least one of two electrodes on the solid-electrolytic layer made of a Ba—Ce-based oxide to block oxygen at the electrode, i.e. cathode, whereby a hydrocarbon sensor being stable, high in sensitivity, compact, easy to use and low in cost can be provided. Furthermore, the other electrode, anode, of the limiting-current type hydrocarbon sensor is made of a material mainly containing Ag. The limiting-current type hydrocarbon sensor comprises a thin sensor-use solid-electrolytic layer capable of conducting protons and oxide ions, a pair of sensor-use electrodes formed on both sides of the solid-electrolytic layer, one electrode on each side, and a gas diffusion rate determining layer formed on the side of the cathode, one of the pair of electrodes. On the sensor-use solid-electrolytic layer on the side of the anode, a solid ion pump for transferring oxygen, hydrogen or water vapor is provided between the anode and the atmosphere under measurement.
摘要翻译：本发明涉及一种极限电流型烃传感器，其包括由Ba-Ce类氧化物制成的固体电解质层，并提供能够以高灵敏度稳定地检测烃的传感器，而与大气中的氧气浓度无关。主要含有Al的材料用于由Ba-Ce类氧化物制成的固体电解质层上的两个电极中的至少一个，以在电极即阴极处阻挡氧，由此烃传感器稳定，灵敏度高，可以提供紧凑，易于使用和低成本。此外，限流型烃传感器的另一电极，阳极由主要含有Ag的材料制成。极限电流型烃传感器包括能够传导质子和氧化物离子的薄传感器用固体电解质层，形成在固体电解质层两侧的一对传感器用电极，每侧一个电极和形成在阴极侧的气体扩散速率决定层，该对电极之一。在阳极侧的传感器用固体电解质层上，在阳极和测量气氛之间设置用于输送氧，氢或水蒸汽的固体离子泵。

44. 发明授权

US5288562A Solid electrolyte fuel cell 失效
标题翻译：固体电解质燃料电池
公开(公告)号：US5288562A
公开(公告)日：1994-02-22
申请号：US820509
申请日：1992-01-14
申请人： Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
发明人： Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
IPC分类号： H01M8/02 , H01M8/12 , H01M8/24 , H01M8/10
CPC分类号： H01M8/0247 , H01M8/0232 , H01M8/0258 , H01M8/2425 , H01M2008/1293 , H01M2300/0074 , H01M8/0206 , Y02P70/56
摘要： A solid electrolyte fuel cell having a multi-layer structure of flat unit cells composed of a solid electrolyte, a first electrode and a second electrode with metal bipolar plates as gas barriers and collectors preferably made of foam metal or a foam alloy interposed between the adjacent unit cells. A fuel gas and an oxidizing gas are supplied to the fuel cell so that they flow in the directions crossing each other with the solid electrolyte interposed therebetween. The metal bipolar plate is preferably provided with grooves so that the fuel gas and the oxidizing gas can be uniformly distributed over the plate.
摘要翻译：一种固体电解质燃料电池，其具有由固体电解质，第一电极和金属双极板作为气体阻挡层的第二电极构成的平坦单元电池的多层结构，并且优选由发泡金属或泡沫合金制成的集电体，单元格单元格将燃料气体和氧化气体供给到燃料电池，使得它们以固体电解质插入其间彼此交叉的方向流动。金属双极板优选地设置有槽，使得燃料气体和氧化气体可以均匀地分布在板上。

45. 发明授权

US5244753A Solid electrolyte fuel cell and method for manufacture of same 失效
标题翻译：固体电解质燃料电池及其制造方法
公开(公告)号：US5244753A
公开(公告)日：1993-09-14
申请号：US942373
申请日：1992-09-09
申请人： Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
发明人： Noboru Taniguchi , Junji Niikura , Kazuhito Hatoh , Takaharu Gamo
IPC分类号： H01M8/12
CPC分类号： H01M8/1213 , H01M8/1246 , Y02E60/525 , Y02P70/56
摘要： This invention provides a solid electrolyte fuel cell operable with high efficiency even in the temperature range of about 850.degree. to 650.degree. C., The invention is characterized by the use of a novel perovskite double oxide of the composition A.sub.X B.sub.Y O.sub.3-.alpha.. The fabrication of the electrolyte, air electrode and fuel electrode layers by tape casting has contributed to marked improvement in processability and productivity.
摘要翻译：本发明提供即使在约850℃至650℃的温度范围内也可高效运行的固体电解质燃料电池。本发明的特征在于使用组合物AXBYO3-α的新型钙钛矿双氧化物。通过带状铸造制造电解质，空气电极和燃料电极层有助于加工性和生产率的显着提高。

46. 发明授权

US4997729A Anode for high temperature fuel cell 失效
标题翻译：高温燃料电池阳极
公开(公告)号：US4997729A
公开(公告)日：1991-03-05
申请号：US290189
申请日：1988-12-27
申请人： Kazuhito Hatoh , Junji Niikura , Hisaaki Gyoten , Noboru Taniguchi , Takaharu Gamo , Yoshio Moriwaki , Tsutomu Iwaki
发明人： Kazuhito Hatoh , Junji Niikura , Hisaaki Gyoten , Noboru Taniguchi , Takaharu Gamo , Yoshio Moriwaki , Tsutomu Iwaki
IPC分类号： H01M4/86 , H01M8/14
CPC分类号： H01M4/9041 , H01M4/8621 , H01M8/142 , H01M2004/8684 , H01M2008/147 , H01M2300/0051 , Y02E60/526 , Y10S420/90
摘要： An anode for high temperature fuel cell containing metal hydrides or hydrogen absorbing alloys at least in part of the anode material of high temperature fuel cell operating while consuming a gas containing hydrogen, or a gas substantially containing hydrogen, as the fuel. In particular, at least in part of the anode for molten carbonate fuel cell, either metal hydrides or hydrogen absorbing alloys is used, and the performance of the anode is enhanced, and it contributes to extension of the life of the anode.
摘要翻译：一种用于高温燃料电池的阳极，其含有至少部分高温燃料电池的负极材料中的金属氢化物或吸氢合金，同时消耗含氢的气体或基本上含有氢的气体作为燃料。特别地，至少部分用于熔融碳酸盐燃料电池的阳极，使用金属氢化物或吸氢合金，并且提高阳极的性能，并且有助于延长阳极的寿命。

47. 发明授权

US07141327B2 Solid electrolyte fuel cell and manufacturing method thereof 有权
标题翻译：固体电解质燃料电池及其制造方法
公开(公告)号：US07141327B2
公开(公告)日：2006-11-28
申请号：US10453535
申请日：2003-06-04
申请人： Noboru Taniguchi
发明人： Noboru Taniguchi
IPC分类号： H01M8/12 , C04B35/64
CPC分类号： H01M4/92 , H01M4/8605 , H01M8/1213 , H01M8/1253 , H01M8/126 , Y02E60/525 , Y02P70/56
摘要： A solid electrolyte fuel cell including a protonic oxide conductor having a composition represented by Ba(Zr1−xCex)1−yMyAlzO3−α (M: one or more kinds of elements selected from a group of tri-valent rare earth elements and In, 1≧x≧0, 0.3>y>0, 0.04>z≧0, and 1.5>α>0); and an electrode that is mainly made of platinum and has catalysis properties; wherein an electrolyte has a film thickness of 300 μm or less, and a method of manufacturing the same are disclosed. The solid electrolyte fuel cell can obtain a cell output even at low temperatures equal to 500 degrees centigrade or less.
摘要翻译：一种固体电解质燃料电池，包括具有由Ba（Zr 1-x Ce 1-x N）1-y M表示的组成的质子氧化物导体，（M：选自三价稀土元素和In中的一种或多种元素， 1> = x> = 0,0.3> y> 0,0.04> z> = 0和1.5>α> 0）; 和主要由铂制成并具有催化性能的电极; 其中电解质的膜厚为300μm以下，并且公开了其制造方法。固体电解质燃料电池即使在等于或等于500摄氏度的低温也能获得电池输出。

48. 发明授权

US06638406B2 Hydrocarbon sensor and method for producing the same 失效
公开(公告)号：US06638406B2
公开(公告)日：2003-10-28
申请号：US09976196
申请日：2001-10-11
申请人： Noboru Taniguchi
发明人： Noboru Taniguchi
IPC分类号： G01N27407
CPC分类号： G01N27/4074 , G01N33/0047
摘要： A hydrocarbon sensor of the present invention includes a substrate made of a solid electrolyte that conducts protons, and a pair of electrodes formed on the substrate, and at least one electrode of the pair of electrodes contains Au and Al. Assuming that a content of an Al simple substance in one of the pair of electrodes is “a” mol %, and a content of aluminum oxide therein is “b” mol %, “a” and “b” satisfy a relationship: a+2b≦7.

49. 发明授权

US06528195B1 Mixed ionic conductor and device using the same 有权
标题翻译：混合离子导体和使用其的装置
公开(公告)号：US06528195B1
公开(公告)日：2003-03-04
申请号：US09506122
申请日：2000-02-17
申请人： Noboru Taniguchi
发明人： Noboru Taniguchi
IPC分类号： H01M810
CPC分类号： G01N27/4074 , C04B35/48 , C04B35/50 , C04B35/62615 , C04B35/6262 , C04B35/6264 , C04B35/6268 , C04B2235/32 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3231 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/327 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , C04B2235/3286 , C04B2235/3289 , C04B2235/3291 , C04B2235/3293 , C04B2235/3294 , C04B2235/3296 , C04B2235/3298 , C04B2235/6567 , C04B2235/768 , C04B2235/96 , H01M8/1246 , H01M8/1253 , H01M8/126 , H01M2008/1293 , H01M2300/0074 , Y02E60/525 , Y02P70/56
摘要： A mixed ionic conductor with an ion conductive oxide has a perovskite structure of the formula BadZr1−x−yCexMy3O3−&ggr; wherein M3 is at least one element selected from the group consisting of Sm, Eu, Gd, Tb, Yb, Y, Sc, and In; with 0.98≦d≦1; 0.01≦x
摘要翻译：具有离子导电氧化物的混合离子导体具有式BadZr1-x-yCexMy3O3-gamma的钙钛矿结构，其中，M3是选自由Sm，Eu，Gd，Tb，Yb，Y，Sc，和In 其中0.98 <= d <= 1; 0.01 <= x <0.5; 0.01 <= y <= 0.3; （2 + y-2d）/ 2 <=γ<1.5。这种混合离子导体不仅具有用于诸如燃料电池的电化学装置所必需的导电性，而且具有优异的耐湿性。

50. 发明授权

US06342267B2 Hydrocarbon sensor and method of producing the same 有权
标题翻译：烃传感器及其制造方法
公开(公告)号：US06342267B2
公开(公告)日：2002-01-29
申请号：US09804229
申请日：2001-03-13
申请人： Noboru Taniguchi
发明人： Noboru Taniguchi
IPC分类号： G01N27407
CPC分类号： G01N33/0047 , G01N27/4074
摘要： A limiting-current-type hydrocarbon sensor comprising a solid electrolyte formed of a barium-cerium-based oxide, capable of detecting hydrocarbon stably and accurately regardless of whether no oxygen is present or a high concentration of oxygen is present. The cathode on the surface of the solid electrolyte is formed of an alloyed layer including Au and Al. In particular, an alloyed layer including an Al—Au intermediate phase is suited for the alloyed layer of the cathode. The alloyed layer comprises a first layer including an Al—Au intermediate phase and making contact with the surface of the solid electrolyte and a second layer including a metal Al phase and covering the first layer. The Al phase of the alloyed layer blocks oxygen, and the Al—Au intermediate phase smoothens hydrogen association and reduces the resistance of the electrode. The hydrocarbon sensor can thus detect hydrocarbon accurately even when oxygen is included in an atmosphere.
摘要翻译：包含由钡 - 铈系氧化物形成的固体电解质的极限电流型烃传感器，无论是否存在氧气或高浓度的氧气都能够稳定且准确地检测碳氢化合物。固体电解质表面的阴极由包含Au和Al的合金层形成。特别地，包含Al-Au中间相的合金层适用于阴极的合金化层。合金层包括包含Al-Au中间相并与固体电解质的表面接触的第一层和包含金属Al相的第二层并覆盖第一层。合金层的Al相阻挡氧，Al-Au中间相平滑氢缔合并降低电极的电阻。因此，即使在气氛中包含氧气的话，烃传感器也能够精确地检测烃。

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